cMOF Evidence Base

Synthesis evidence

Morphology-driven electrochemical attributes of Cu-MOF: a high-performance anodic material for battery supercapacitor hybrids

Shakeel N., Khan J., Al-Kahtani A.A. · RSC Advances · 2024 · 33941-33951

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Drop Cast

p003 / journal page 33943 · 2.1 Electrode characterization/fabrication

Metal precursorsQ1 hydrothermal Cu-MOF active material
Linker precursorspyridine-4-carboxylic acid in Q1 Cu-MOF
SolventsN-methyl-2-pyrrolidone (NMP)
Additivesacetylene black; PVDF binder
Atmospherenot reported
Temperature60
Time6 drying; 6 slurry stirring
Substrate orientationnickel foam, 1 cm2 coated area
Work-upslurry stirred 6 h, coated on cleaned nickel foam, dried at 60 C for 6 h
Activationdrying at 60 C before electrochemical analysis
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherQ1 synthesized Cu-MOF80 wt% of electrode mixturep003 / journal page 33943 · 2.1 Electrode characterization/fabrication
Additiveacetylene black10 wt%p003 / journal page 33943 · 2.1 Electrode characterization/fabrication
AdditivePVDF binder10 wt%p003 / journal page 33943 · 2.1 Electrode characterization/fabrication
SolventN-methyl-2-pyrrolidone (NMP)Not specifiedp003 / journal page 33943 · 2.1 Electrode characterization/fabrication
Partial recipeSource: Main

Route 2: Hydrothermal

p002-p003 / journal pages 33942-33943 · 2 Materials and methods · Fig. 1

Metal precursorscopper chloride (CuCl2), 0.1 M solution in 10 mL methanol
Linker precursorspyridine-4-carboxylic acid, 0.1 M solution in deionized water
Solventsmethanol; deionized water
Atmospherenot reported
Temperature180
Time12
Work-uppurified after hydrothermal reaction to remove contaminants; dried by vacuum drying or low heating
Activationdrying; no separate activation reported
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcecopper chloride (CuCl2)0.1 M; in 10 mL methanolp002-p003 / journal pages 33942-33943 · 2 Materials and methods · Fig. 1
Linkerpyridine-4-carboxylic acid0.1 Mp002-p003 / journal pages 33942-33943 · 2 Materials and methods · Fig. 1
Solventmethanol10 mL for CuCl2 solutionp002-p003 / journal pages 33942-33943 · 2 Materials and methods · Fig. 1
Solventdeionized waterNot specifiedp002-p003 / journal pages 33942-33943 · 2 Materials and methods · Fig. 1
Vague recipeSource: Main

Route 3: Other

p008 / journal page 33948 · 5 Battery-supercapacitor hybrid configuration · Fig. 7(a)

Metal precursorsQ2 Cu-MOF electrode
Linker precursorspyridine-4-carboxylic acid in Q2 Cu-MOF
Additivesactivated carbon; polymeric separator
Atmospherenot reported
Work-upQ2 battery electrode and activated-carbon capacitive electrode assembled with thin porous polymeric separator
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherQ2 Cu-MOF electrodeNot specifiedp008 / journal page 33948 · 5 Battery-supercapacitor hybrid configuration · Fig. 7(a)
Additiveactivated carbonNot specifiedp008 / journal page 33948 · 5 Battery-supercapacitor hybrid configuration · Fig. 7(a)
Otherpolymeric separatorNot specifiedp008 / journal page 33948 · 5 Battery-supercapacitor hybrid configuration · Fig. 7(a)
Partial recipeSource: Main

Route 4: Drop Cast

p003 / journal page 33943 · 2.1 Electrode characterization/fabrication

Metal precursorsQ2 sonochemical Cu-MOF active material
Linker precursorspyridine-4-carboxylic acid in Q2 Cu-MOF
SolventsN-methyl-2-pyrrolidone (NMP)
Additivesacetylene black; PVDF binder
Atmospherenot reported
Temperature60
Time6 drying; 6 slurry stirring
Substrate orientationnickel foam, 1 cm2 coated area
Work-upslurry stirred 6 h, coated on cleaned nickel foam, dried at 60 C for 6 h
Activationdrying at 60 C before electrochemical analysis
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherQ2 synthesized Cu-MOF80 wt% of electrode mixturep003 / journal page 33943 · 2.1 Electrode characterization/fabrication
Additiveacetylene black10 wt%p003 / journal page 33943 · 2.1 Electrode characterization/fabrication
AdditivePVDF binder10 wt%p003 / journal page 33943 · 2.1 Electrode characterization/fabrication
SolventN-methyl-2-pyrrolidone (NMP)Not specifiedp003 / journal page 33943 · 2.1 Electrode characterization/fabrication
Partial recipeSource: Main

Route 5: Other

p003 / journal page 33943 · 2 Materials and methods · Fig. 1

Metal precursorsCuCl2, 0.50 mol
Linker precursorspyridine-4-carboxylic acid, 0.50 mol
Solventsdeionized water
Atmospherenot reported
Temperature30
Time0.75
Work-upcentrifuged, repeatedly washed with ethanol and DI water, dried overnight at 80 C
Activationovernight drying at 80 C; no separate activation reported
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCuCl20.50 molp003 / journal page 33943 · 2 Materials and methods · Fig. 1
Linkerpyridine-4-carboxylic acid0.50 molp003 / journal page 33943 · 2 Materials and methods · Fig. 1
Solventdeionized water100 mLp003 / journal page 33943 · 2 Materials and methods · Fig. 1
Solventethanolwash solventp003 / journal page 33943 · 2 Materials and methods · Fig. 1