cMOF Evidence Base

Synthesis evidence

Monovalent K, Cs, Tl, and Ag nitrosodicyanomethanides: Completely different 3D networks with useful properties of luminescent materials and nonelectric sensors for gases†

Glover G., Gerasimchuk N., Biagioni R. et al. · Inorganic Chemistry · 2009 · 2371-2382

4 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Vague recipeSource: Main

Route 1: Other

p005 / journal page 2375 · Synthesis

Metal precursorsAgNO3
Linker precursors{ONC(CN)2}- anion from reaction mixture
Solventsnot specified
Work-upObtained as pure bright deep-yellow microcrystalline powder after precipitation.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceAgNO3Not specifiedp005 / journal page 2375 · Synthesis
Linker{ONC(CN)2}- anion from reaction mixtureNot specifiedp005 / journal page 2375 · Synthesis
Partial recipeSource: Main

Route 2: Other

p005 / journal page 2375 · Synthesis

Metal precursorsAg{ONC(CN)2}; CsCl
Linker precursorsnitrosodicyanomethanide supplied as Ag{ONC(CN)2}
Solventswater inferred from typical metathesis procedure, but volume not specified for Cs
Atmospherenot specified
Temperature4 for single-crystal growth from aqueous solution
Work-upYellow-orange crystals isolated; single crystals obtained from aqueous solutions upon slow evaporation at 4 deg C.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceAg{ONC(CN)2}0.662 g, 3.28 mMp005 / journal page 2375 · Synthesis
Metal SourceCsCl0.552 g, 3.28 mMp005 / journal page 2375 · Synthesis
Partial recipeSource: Main

Route 3: Other

p005 / journal page 2375 · Synthesis

Metal precursorsAg{ONC(CN)2}; KBr
Linker precursorsnitrosodicyanomethanide supplied as Ag{ONC(CN)2}
Solventswater inferred from typical metathesis procedure, but volume not specified for K
Atmospherenot specified
Work-upBright yellow crystals isolated; detailed filtration/crystallisation conditions not separately stated for K.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceAg{ONC(CN)2}1.00 g, 5 mMp005 / journal page 2375 · Synthesis
Metal SourceKBr0.59 g, 5.0 mMp005 / journal page 2375 · Synthesis
Complete recipeSource: Main

Route 4: Other

p004 / journal page 2374 · Synthesis

Metal precursorsAg{ONC(CN)2}; TlCl
Linker precursorsnitrosodicyanomethanide supplied as Ag{ONC(CN)2}
Solventswater, 10 mL plus 2 mL wash
Atmospherestirred in the dark; otherwise atmosphere not specified
Temperature4 for crystallisation; room temperature during metathesis not numerically specified
Time0.333 h stirring after TlCl addition; 336 h crystallisation
Work-upFiltered to remove AgCl, washed with 2 mL water, clear yellow filtrate left at 4 deg C for crystallisation for 2 weeks.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceAg(CCO) / Ag{ONC(CN)2}0.135 g, 0.67 mMp004 / journal page 2374 · Synthesis
Metal SourceTlCl0.161 g, 0.67 mMp004 / journal page 2374 · Synthesis
Solventwater10 mL suspension; 2 mL washp004 / journal page 2374 · Synthesis