Microscopy Morphology — MOF matrix isolation: Cooperative conformational mobility enables reliable single crystal transformations

5 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

MnMOF-1-DEE after attempted Rh metalation · Single Crystal

EDX measured Mn:Rh ratio/Rh occupancy after attempted post-synthetic Rh metalation.

Context: guest-loaded
Measurement source: p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Rh occupancy standard error	2.5	—	—	SI Table Exact Reported	p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1
Rh occupancy	3	—	2.5%	SI Table Exact Reported	p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1

MnMOF-1-THF after attempted Rh metalation · Single Crystal

EDX measured Mn:Rh ratio/Rh occupancy after attempted post-synthetic Rh metalation.

Context: guest-loaded
Measurement source: p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Rh occupancy standard error	1.5	—	—	SI Table Exact Reported	p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1
Rh occupancy	5	—	1.5%	SI Table Exact Reported	p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1

Rh-metalated MnMOF-1 from acetone · Single Crystal

EDX measured Mn:Rh ratio/Rh occupancy after attempted post-synthetic Rh metalation.

Context: guest-loaded
Measurement source: p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Rh occupancy standard error	4.7	—	—	SI Table Exact Reported	p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1
Rh occupancyMarked as a best value within this paper	210	—	4.7%	SI Table Exact Reported	p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1

Rh-metalated MnMOF-1 from DCM · Single Crystal

EDX measured Mn:Rh ratio/Rh occupancy after attempted post-synthetic Rh metalation.

Context: guest-loaded
Measurement source: p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Rh occupancy standard error	4.3	—	—	SI Table Exact Reported	p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1
Rh occupancyMarked as a best value within this paper	198	—	4.3%	SI Table Exact Reported	p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1

Rh-metalated MnMOF-1 from p-xylene · Single Crystal

EDX measured Mn:Rh ratio/Rh occupancy after attempted post-synthetic Rh metalation.

Context: guest-loaded
Measurement source: p020 / SI page 20 · SI 6.0 Energy Dispersive X-ray Analysis (EDX) · Table S6.1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EDX Rh/Mn outcome	Rh:Mn = 2:3	—	—	Text Rounded Reported	p008 / journal page 91 · Post-synthetic metalation of MnMOF-1 with [Rh(CO)2Cl]2 · ESI Table S6.1