Lin Z., Lin J., Yu S.-W. et al. · Inorganic Chemistry Communications · 2026 · 116638
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Ni-AEs retain H2 production under seawater and sunlight conditions, but the SI condition labels are internally inconsistent.
Caveat: Main text/Fig. 2d and SI Tables S7/S8 disagree on seawater versus sunlight labelling. | Schema-normalised claim_type from 'application_performance' to 'application_relevance'; the original controlled-label wording is retained here.
3 · Results · Linked to 4 structured results
Ni-Ca gives higher photocatalytic H2 evolution than Ni-Sr under the standard, seawater and sunlight assignments, consistent with its improved electron/proton transport and hydrophilicity.
Caveat: Main text/Fig. 2d and SI Tables S7/S8 disagree on the seawater versus sunlight labels; the extraction follows the main-text/figure assignment. | Schema-normalised claim_type from 'application_performance' to 'application_relevance'; the original controlled-label wording is retained here.
5 · Results · Linked to 8 structured results
Both Ni-Ca and Ni-Sr are pristine heterometallic MOFs with directly measured electronic and proton transport properties.
Caveat: Schema-normalised claim_type from 'scope_relevance' to 'application_relevance'; the original controlled-label wording is retained here.
1 · Abstract · Linked to 4 structured results
Ni-AEs are structurally stable during photocatalytic recycling, with activity remaining near 90% after four cycles.
Caveat: Recycling and pH-stability support includes figure/caption evidence; no raw diffraction data are supplied.
5 · 3. Result and discussion · Fig. 2f; Figs. S9-S11 referenced · Linked to 3 structured results
Ni-Ca crystallises as a triclinic P-1 interlaced 3D framework assembled from NiS and CaO clusters.
Caveat: Schema-normalised claim_type from 'structure' to 'phase_assignment'; the original controlled-label wording is retained here.
2 · Results · Linked to 3 structured results
Ni-Sr is treated as an isostructural Sr analogue based on PXRD similarity and metal-ratio evidence.
Caveat: No separate full SCXRD table for Ni-Sr was present in the local documents. | Schema-normalised claim_type from 'structure' to 'phase_assignment'; the original controlled-label wording is retained here.
3 · Results · Linked to 2 structured results
Redox-active NiS clusters mimic hydrogenase active centres, while CaO/SrO clusters and hydrogen-bonding chains create a hydrophilic microenvironment that supports electron/proton transport and hydrogen evolution.
Caveat: The microenvironment mechanism is supported by structure, hydrogen bonding and transport/application correlations rather than a direct operando mechanistic measurement.
3 · 3. Result and discussion · Fig. 1; Fig. 2 · Linked to 8 structured results
Mott-Schottky plots identify Ni-AEs as n-type semiconductors with similar conduction-band potentials.
5 · Results · Linked to 4 structured results
PL quenching and EPR evidence support faster photo-induced electron transfer for Ni-Ca than Ni-Sr.
Caveat: PL constants are read from plotted Stern-Volmer equations; EPR comparison is partly qualitative. | Schema-normalised claim_type from 'photophysics_mechanism' to 'transport_mechanism'; the original controlled-label wording is retained here.
5 · Results · Linked to 4 structured results
Replacing Sr2+ with Ca2+ improves carrier mobility, electronic conductivity, proton conductivity, and hydrophilicity.
5 · Results · Linked to 8 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Ni-Ca heterometallic MOF (Ni-Ca) | Not specified['redox-active NiS clusters', 'redox-inactive CaO clusters'] | unknown · Unknown | 1 · Abstract |
| Ni-Sr heterometallic MOF (Ni-Sr) | Not specified['redox-active NiS clusters', 'redox-inactive SrO clusters'] | unknown · Unknown | 2 · Synthesis |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Ni-Ca dark brown crystals / powderresearch_0697__mat__ni_ca_mof | Powder · Target Sample · Mixed Metal | target_sample | 2 · Synthesis |
| Ni-Ca DFT modelresearch_0697__mat__ni_ca_mof | Model · Model System · Model | model_system | 8 · S8 Density Functional Theory |
| Ni-Ca coated electrochemical electroderesearch_0697__mat__ni_ca_mof | Electrode · Composite Sample · Composite | composite_sample | S5 Electrochemical Tests |
| Ni-Ca pressed pelletresearch_0697__mat__ni_ca_mof | Pellet · Target Sample · Mixed Metal | target_sample | 7 · S7 Proton and Electrical Conductivity Tests |
| Ni-Sr brown crystals / powderresearch_0697__mat__ni_sr_mof | Powder · Target Sample · Mixed Metal | target_sample | 2 · Synthesis |
| Ni-Sr DFT modelresearch_0697__mat__ni_sr_mof | Model · Model System · Model | model_system | 4 |
| Ni-Sr coated electrochemical electroderesearch_0697__mat__ni_sr_mof | Electrode · Composite Sample · Composite | composite_sample | S5 Electrochemical Tests |
| Ni-Sr pressed pelletresearch_0697__mat__ni_sr_mof | Pellet · Target Sample · Mixed Metal | target_sample | 7 · S7 Proton and Electrical Conductivity Tests |