Electrical Transport — Electrical Semiconductivity of Stacked Layer Coordination Polymers of Rhodium(I)

Measurement evidence

Electrical Transport

Electrical Semiconductivity of Stacked Layer Coordination Polymers of Rhodium(I) · Feinstein-Jaffe I., Efraty A. · Macromolecules · 1986 · 2076-2077

7 measurement groups · 18 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Two-electrode ac conductivity, 1 kHz

[Rh(1,3-diisocyanobenzene)2+Cl-]n compressed-powder pellet · Pellet

Room temperature approximately 25 deg C; compressed-powder pellet.

Temperature
298
Geometry
Two-electrode pellet holder; pellet thickness 0.20 mm.
Context
pristine_framework
Measurement source
2076 · Experimental Section · Table I
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Measured conductivity/conductance8.0 x 10^-8 ohm^-1Table
Rounded Reported
2076 · Results and Discussion · Table I
Pellet thickness0.20 mmvariation +/-0.05 mmTable
Exact Reported
2076 · Results and Discussion · Table I
Specific conductivity4.00 x 10^-6 ohm^-1 cm^-10.000004 S cm^-1Table
Exact Reported
2076 · Results and Discussion · Table I

Two-electrode ac conductivity, 1 kHz

[Rh(1,4-diisocyanobenzene)2+Cl-]n compressed-powder pellet · Pellet

Room temperature approximately 25 deg C; compressed-powder pellet.

Temperature
298
Geometry
Two-electrode pellet holder; pellet thickness 0.20 mm.
Context
pristine_framework
Measurement source
2076 · Experimental Section · Table I
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Measured conductivity/conductance3.3 x 10^-6 ohm^-1Table
Rounded Reported
2076 · Results and Discussion · Table I
Pellet thickness0.20 mmvariation +/-0.05 mmTable
Exact Reported
2076 · Results and Discussion · Table I
Specific conductivityMarked as a best value within this paper1.65 x 10^-4 ohm^-1 cm^-10.000165 S cm^-1Table
Exact Reported
2076 · Results and Discussion · Table I

Two-electrode ac conductivity, 1 kHz

[Rh(1,5-diisocyanonaphthalene)2+Cl-]n compressed-powder pellet · Pellet

Room temperature approximately 25 deg C; compressed-powder pellet.

Temperature
298
Geometry
Two-electrode pellet holder; pellet thickness 0.35 mm.
Context
pristine_framework
Measurement source
2076 · Experimental Section · Table I
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Measured conductivity/conductance1.1 x 10^-7 ohm^-1Table
Rounded Reported
2076 · Results and Discussion · Table I
Pellet thickness0.35 mmvariation +/-0.05 mmTable
Exact Reported
2076 · Results and Discussion · Table I
Specific conductivity3.14 x 10^-6 ohm^-1 cm^-10.00000314 S cm^-1Table
Exact Reported
2076 · Results and Discussion · Table I

Two-electrode ac conductivity, 1 kHz

[Rh(4,4'-diisocyanobiphenyl)2+Cl-]n compressed-powder pellet · Pellet

Room temperature approximately 25 deg C; compressed-powder pellet.

Temperature
298
Geometry
Two-electrode pellet holder; pellet thickness 0.50 mm.
Context
pristine_framework
Measurement source
2076 · Experimental Section · Table I
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Measured conductivity/conductance6.1 x 10^-7 ohm^-1Table
Rounded Reported
2076 · Results and Discussion · Table I
Pellet thickness0.50 mmvariation +/-0.05 mmTable
Exact Reported
2076 · Results and Discussion · Table I
Specific conductivity1.22 x 10^-5 ohm^-1 cm^-10.0000122 S cm^-1Table
Exact Reported
2076 · Results and Discussion · Table I

Two-electrode ac conductivity, 1 kHz

[Rh(4,4'-diisocyanodiphenylmethane)2+Cl-]n compressed-powder pellet · Pellet

Room temperature approximately 25 deg C; compressed-powder pellet.

Temperature
298
Geometry
Two-electrode pellet holder; pellet thickness 0.20 mm.
Context
pristine_framework
Measurement source
2076 · Experimental Section · Table I
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Measured conductivity/conductance4.0 x 10^-7 ohm^-1Table
Rounded Reported
2076 · Results and Discussion · Table I
Pellet thickness0.20 mmvariation +/-0.05 mmTable
Exact Reported
2076 · Results and Discussion · Table I
Specific conductivity2.00 x 10^-5 ohm^-1 cm^-10.00002 S cm^-1Table
Exact Reported
2076 · Results and Discussion · Table I

Temperature-dependent ac resistivity

[Rh(1,4-diisocyanobenzene)2+Cl-]n compressed-powder pellet · Pellet

ln resistivity versus 1000/T measured from 25-150 deg C.

Temperature
298-423
Geometry
Compressed-powder pellet; ac conductivity/resistivity.
Context
pristine_framework
Measurement source
2076-2077 · Results and Discussion · Figure 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Band-gap energy0.47 eVText
Exact Reported
2076 · Results and Discussion · Figure 2
ln resistivity versus 1000/T behaviournearly linear plotsText
Qualitative
2076 · Results and Discussion · Figure 2

Temperature-dependent ac resistivity

[Rh(4,4'-diisocyanobiphenyl)2+Cl-]n compressed-powder pellet · Pellet

ln resistivity versus 1000/T measured from 25-150 deg C.

Temperature
298-423
Geometry
Compressed-powder pellet; ac conductivity/resistivity.
Context
pristine_framework
Measurement source
2076-2077 · Results and Discussion · Figure 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Band-gap energy0.25 eVText
Exact Reported
2076 · Results and Discussion · Figure 2