Porosity — Generation of Environmentally Persistent Free Radicals on Metal-Organic Frameworks

3 measurement groups · 33 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption-desorption, BET/NLDFT

Gas sorption and porosity

MCP-dosed MIL-100(Al) · Powder

MCP/CT-dosed MIL-100(Al), before and after Soxhlet purification; activated under vacuum at 150 C before sorption.

Temperature: 77
Atmosphere: N2
Context: guest-loaded Al framework
Measurement source: S18 · Supporting figures and tables · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area, CT-dosed MIL-100(Al)	168 m2 g-1	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
BET surface area, purified CT-dosed MIL-100(Al)Marked as a best value within this paper	1502 m2 g-1	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
BET surface area, MCP-dosed MIL-100(Al)	275 m2 g-1	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
BET surface area, purified MCP-dosed MIL-100(Al)Marked as a best value within this paper	1497 m2 g-1	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
Pore diameter, CT-dosed MIL-100(Al)	1.40 nm	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
Pore diameter, purified CT-dosed MIL-100(Al)	1.05 nm	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
Pore diameter, MCP-dosed MIL-100(Al)	1.16 nm	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
Pore diameter, purified MCP-dosed MIL-100(Al)	1.04 nm	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
Total pore volume, CT-dosed MIL-100(Al)	0.31 cm3 g-1	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
Total pore volume, purified CT-dosed MIL-100(Al)	0.93 cm3 g-1	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
Total pore volume, MCP-dosed MIL-100(Al)	0.40 cm3 g-1	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2
Total pore volume, purified MCP-dosed MIL-100(Al)	0.82 cm3 g-1	—	—	SI Table Exact Reported	S18 · Supporting figures and tables · Table S2

N2 adsorption-desorption, BET/NLDFT

Gas sorption and porosity

MCP-dosed MIL-100(Fe) · Powder

MCP/CT-dosed MIL-100(Fe) and MIL-100(Cr); activated at 150 C under vacuum for 12 h.

Temperature: 77
Atmosphere: N2
Context: guest-loaded Fe/Cr framework comparison
Measurement source: S35 · Supporting figures and tables · Table S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area, CT-dosed MIL-100(Cr)	1537 m2 g-1	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
BET surface area, MCP-dosed MIL-100(Cr)	1764 m2 g-1	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
BET surface area, CT-dosed MIL-100(Fe)	322 m2 g-1	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
BET surface area, MCP-dosed MIL-100(Fe)	931 m2 g-1	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
Pore diameter, CT-dosed MIL-100(Cr)	1.20 nm	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
Pore diameter, MCP-dosed MIL-100(Cr)	1.16 nm	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
Pore diameter, CT-dosed MIL-100(Fe)	1.76 nm	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
Pore diameter, MCP-dosed MIL-100(Fe)	1.10 nm	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
Total pore volume, CT-dosed MIL-100(Cr)	1.11 cm3 g-1	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
Total pore volume, MCP-dosed MIL-100(Cr)	1.75 cm3 g-1	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
Total pore volume, CT-dosed MIL-100(Fe)	0.83 cm3 g-1	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4
Total pore volume, MCP-dosed MIL-100(Fe)	0.65 cm3 g-1	—	—	SI Table Exact Reported	S35 · Supporting figures and tables · Table S4

N2 adsorption-desorption, BET/NLDFT

Gas sorption and porosity

MIL-100(Al) powder · Powder

Samples activated under vacuum at 150 C for 12 h; N2 sorption at 77 K over P/P0 0.001-1.

Temperature: 77
Atmosphere: N2
Context: pristine framework family
Measurement source: 3267 · Other Measurements · Table S1; Figure S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area, MIL-100(Al)Marked as a best value within this paper	1837 m2 g-1	—	—	SI Table Exact Reported	S7 · Supporting figures and tables · Table S1
BET surface area, MIL-100(Cr)Marked as a best value within this paper	1818 m2 g-1	—	—	SI Table Exact Reported	S7 · Supporting figures and tables · Table S1
BET surface area, MIL-100(Fe)Marked as a best value within this paper	1506 m2 g-1	—	—	SI Table Exact Reported	S7 · Supporting figures and tables · Table S1
Pore diameter, MIL-100(Al)	1.04 nm	—	—	SI Table Exact Reported	S7 · Supporting figures and tables · Table S1
Pore diameter, MIL-100(Cr)	1.00 nm	—	—	SI Table Exact Reported	S7 · Supporting figures and tables · Table S1
Pore diameter, MIL-100(Fe)	1.08 nm	—	—	SI Table Exact Reported	S7 · Supporting figures and tables · Table S1
Total pore volume, MIL-100(Al)	0.91 cm3 g-1	—	—	SI Table Exact Reported	S7 · Supporting figures and tables · Table S1
Total pore volume, MIL-100(Cr)	0.94 cm3 g-1	—	—	SI Table Exact Reported	S7 · Supporting figures and tables · Table S1
Total pore volume, MIL-100(Fe)	0.85 cm3 g-1	—	—	SI Table Exact Reported	S7 · Supporting figures and tables · Table S1