Electrical Transport — Spin crossover in Fe(triazole)-Pt nanoparticle self-assembly structured at the sub-5 nm scale

Measurement evidence

Electrical Transport

Spin crossover in Fe(triazole)-Pt nanoparticle self-assembly structured at the sub-5 nm scale · Usmani S., Mikolasek M., Gillet A. et al. · Nanoscale · 2020 · 8180-8187

4 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

I-V measurement

Pristine PtNP deposit on electrode · Electrode

Pristine PtNP deposit measured at 300 K.

Temperature
300
Geometry
electrode deposit
Context
pristine PtNP electrical control
Measurement source
p005 · Supplementary information · Fig. S4a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Pristine PtNP I-V responselinear I-V at 300 KVisual Estimate
Qualitative
p005 · Supplementary information · Fig. S4a
Pristine PtNP current near +2 Vapproximately +750 nA at +2 Vvisual estimate from axisFigure Axis
Approximate
p005 · Supplementary information · Fig. S4a

I-V measurement

PtNPs-FeL3 self-assembly drop-cast on interdigitated electrodes · Electrode

PtNPs-FeL3 self-assembly measured at 300 K; non-linearity used as Coulomb blockade signature.

Temperature
300
Geometry
drop-cast self-assembly on electrode
Context
PtNPs-FeL3 hybrid self-assembly device
Measurement source
p005 · Supplementary information · Fig. S4b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Self-assembly I-V non-linearityMarked as a best value within this papernon-linear I-V, signature of Coulomb blockadeCaption
Qualitative
p005 · Supplementary information · Fig. S4b
Self-assembly current near +2.5 Vapproximately +58 nA at +2.5 Vvisual estimate from axisFigure Axis
Approximate
p005 · Supplementary information · Fig. S4b

Current-temperature transport measurement

PtNPs-FeL3 self-assembly drop-cast on interdigitated electrodes · Electrode

Electrode biased at 0.1 V with temperature sweep rate of 3 K min^-1.

Temperature
approximately 25-300
Geometry
drop-cast self-assembly on electrode
Context
PtNPs-FeL3 hybrid self-assembly device
Measurement source
p007 · Supplementary information · Fig. S6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Bias voltage for hysteresis-like current-temperature cycle0.1 VCaption
Exact Reported
p007 · Supplementary information · Fig. S6
Approximate current near 300 K in hysteresis plotapproximately 150 nA near 300 Kvisual estimate from axisFigure Axis
Approximate
p007 · Supplementary information · Fig. S6
Sweep rate for hysteresis-like current-temperature cycle3 K min^-1Caption
Exact Reported
p007 · Supplementary information · Fig. S6

Current-temperature transport measurement

PtNPs-FeL3 self-assembly drop-cast on interdigitated electrodes · Electrode

Drop-cast SA on interdigitated electrodes; nitrogen-cooled cryostat; Keithley 6430 subfemtoamperemeter; temperature swept at 1 K min^-1 unless otherwise stated.

Temperature
roughly 25-300
Atmosphere
nitrogen-cooled cryostat
Geometry
interdigitated comb electrodes, 20 fingers, 30 nm high, 200 um long, 5 um gap
Context
PtNPs-FeL3 hybrid self-assembly device
Measurement source
p005-p007, journal pp. 8184-8186 · Magnetic and charge transport measurements; Charge transport measurements · Fig. 4b; ESI Fig. S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Transport current rangefew nA to few hundred nAText
Range
p005, journal p. 8184 · Magnetic and charge transport measurements · ESI Fig. S5
Current-temperature slope breakMarked as a best value within this paperaround 280 KCaption
Approximate
p004, journal p. 8183 · Magnetic and charge transport measurements · Fig. 4b
Hybrid assembly resistance rangeMarked as a best value within this paper10-10^3 MohmText
Range
p005, journal p. 8184 · Magnetic and charge transport measurements · ESI Fig. S5
Slope breaks on independent electrodesaround 270 KCaption
Approximate
p006 · Supplementary information · Fig. S5
Electrodes showing slope breakfour out of six measured electrodes0.667 fraction of measured electrodesText
Exact Reported
p007, journal p. 8186 · Charge transport measurements
Transport voltage rangefew tenths of a volt up to 2 VText
Range
p005, journal p. 8184 · Magnetic and charge transport measurements · ESI Fig. S5