Porosity — CO2-Sensitive Porous Magnet: Antiferromagnet Creation from a Paramagnetic Charge-Transfer Layered Metal-Organic Framework

Measurement evidence

Porosity

CO2-Sensitive Porous Magnet: Antiferromagnet Creation from a Paramagnetic Charge-Transfer Layered Metal-Organic Framework · Zhang J., Kosaka W., Liu Q. et al. · Journal of the American Chemical Society · 2023 · 26179-26189

1 measurement group · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Single-component volumetric gas sorption isotherms and isobars

Gas sorption and porosity

Activated crystals of compound 1 · Single Crystal

N2, CO2, and O2 sorption; CO2 isotherms/isobars from 195-300 K and 1-100 kPa; sample degassed at 353 K for 12 h.

Temperature: 77, 90, 120, 195-300
Atmosphere: N2, O2, CO2
Geometry: BELSORP Max volumetric adsorption apparatus connected to cryostat
Context: pristine framework before and during guest adsorption
Measurement source: p009 · Gas Adsorption Measurements · Figure 1; Figures S1-S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake at 99 kPa and 195 KMarked as a best value within this paper	56.51 mL (STP) g-1 for 4.92 molecules per formula unit	4.92 molecules per formula unit	—	Text Exact Reported	p003 · CO2 Sorption Properties and Related Phase Diagram · Figure 1a
CO2 uptake at GO-e	35.94 mL (STP) g-1, approximately 3 mol per formula unit	3 mol CO2 per formula unit	approximately for molar equivalent	Text Rounded Reported	p003 · CO2 Sorption Properties and Related Phase Diagram · Figure 1a
CO2 ending gate-opening pressure at 195 K	10.31 kPa	—	—	Text Exact Reported	p003 · CO2 Sorption Properties and Related Phase Diagram · Figure S3
CO2 initial gate-opening pressure at 195 K	0.63 kPa	—	—	Text Exact Reported	p003 · CO2 Sorption Properties and Related Phase Diagram · Figure 1a; Figure S3
CO2 adsorption/desorption hysteresis width	approximately 400 Pa	0.4 kPa	approximately	Text Approximate	p003 · CO2 Sorption Properties and Related Phase Diagram · Figure S2a
N2 sorption character	nonporous nature for N2 at both 77 and 120 K	—	—	Text Qualitative	p003 · CO2 Sorption Properties and Related Phase Diagram · Figure S1
O2 uptake at 90/120 K and 99 kPa	about 2 mol mol-1 O2	2 O2 per formula unit	about	Text Approximate	S37 · Magnetic property under O2 atmosphere · Figure S1
Transition enthalpy from isotherms, GC-e	-41.5 kJ mol-1	—	—	Text Exact Reported	S9 · Temperature dependence of the gated sorption pressure · Figure S4
Transition enthalpy from isotherms, GC-i	-40.1 kJ mol-1	—	—	Text Exact Reported	S9 · Temperature dependence of the gated sorption pressure · Figure S4
Transition enthalpy from isotherms, GO-e	-11.9 kJ mol-1	—	—	Text Exact Reported	S9 · Temperature dependence of the gated sorption pressure · Figure S4
Transition enthalpy from isotherms, GO-i	-30.2 kJ mol-1	—	—	Text Exact Reported	S9 · Temperature dependence of the gated sorption pressure · Figure S4