Zhao C.-E., Wang S., Chen S. et al. · Chemical Science · 2025 · 9276-9283
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The CuNi-HHTP MSC retains substantial capacitance over cycling and bending tests and can power a red LED with three devices in series.
Caveat: LED demonstration runtime is reported as a lower bound.
p006 / 9281 · Results and discussion · Fig. 5f-h and Fig. S8 · Linked to 5 structured results
Laser-scribed interdigital CuNi-HHTP MSCs improve transparency and areal capacitance relative to sandwich-type FTSCs.
Caveat: Device values include composite architecture effects and should not be treated as pristine-framework intrinsic transport alone.
p005 / 9280 · Results and discussion · Fig. 5 and Fig. S7 · Linked to 5 structured results
No additional local document was needed for first-hand extraction; the main article states that additional experimental data are included in the ESI, which was available and read.
p007 / 9282 · Data availability
Ni incorporation in CuNi-HHTP creates dual metal sites and nanorod morphology that improve electron/ion transport relative to single-metal controls.
Caveat: Sheet resistance values for single-metal controls were only estimated from Fig. 3a, but conductivities were reported exactly.
p004 / 9279 · Results and discussion · Fig. 3a-b · Linked to 5 structured results
DFT calculations support different K+ adsorption energetics on Cu-HHTP and Cu/Ni sites in CuNi-HHTP and are used to rationalise ion-transport kinetics.
Caveat: The main text states Ni incorporation is favourable for K+ adsorption although the reported Cu-HHTP value is more negative than the CuNi-HHTP site values.
p005 / 9280 · Results and discussion · Fig. 4e · Linked to 3 structured results
CuNi-HHTP charge storage involves Faradaic K+ insertion/extraction with conversion between C=O and C-O bonding.
Caveat: Mechanism is inferred from ex situ XPS/FT-IR trends and DFT adsorption calculations.
p004-p005 / 9279-9280 · Results and discussion · Fig. 4 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu-HHTPBrowse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu-HHTPCu · HHTP | 2D · PristineSingle-metal layered HHTP c-MOF; PXRD peaks indexed to layered structures. | p003 / 9278 · Results and discussion · Fig. 2 |
| CuNi-HHTPBrowse family: Cu/Ni–HHTP family | Cu/Ni-HHTP framework; HHTP = 2,3,6,7,10,11-hexahydroxytriphenyleneCu and Ni metal sites · HHTP | 2D · Pristine2D honeycomb c-MOF with slipped-parallel ab stacking and 1D channels; theoretical pore size about 1.8 nm. | p002 / 9277 · Results and discussion · Fig. 1 |
| Ni-HHTPBrowse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni-HHTPNi · HHTP | 2D · PristineSingle-metal layered HHTP c-MOF control with rod-like morphology. | p003 / 9278 · Results and discussion · Fig. 2 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Cu-HHTPresearch_0768__mat__mat_cu_hhtp | Powder · Pristine Control · Pristine Framework | As-synthesised single-metal control. | S2 · Experimental Procedures |
| Cu-HHTP computational modelresearch_0768__mat__mat_cu_hhtp | Model · Model System · Model | DFT model derived from Cu-HHTP crystal structure. | S4 · DFT Calculations |
| CuNi-HHTP (1:3)research_0768__mat__mat_cuni_hhtp | Powder · Pristine Control · Mixed Metal | As-synthesised atomic-ratio variant. | S2 · Experimental Procedures · Fig. S3 |
| CuNi-HHTP (3:1)research_0768__mat__mat_cuni_hhtp | Powder · Pristine Control · Mixed Metal | As-synthesised atomic-ratio variant. | S2 · Experimental Procedures · Fig. S3 |
| CuNi-HHTP thin film electrode on ITO-PETresearch_0768__mat__mat_cuni_hhtp | Thin Film · Target Sample · Mixed Metal | Sprayed CuNi-HHTP layer; loading mass 0.75 mg cm^-2.ITO-PET, O2 plasma treated | S3 · Devices fabrication |
| Sandwich-type flexible transparent CuNi-HHTP supercapacitorresearch_0768__mat__mat_cuni_hhtp | Electrode · Pristine Control · Composite | Two CuNi-HHTP thin film electrodes assembled sandwich-style with PVA/KCl gel electrolyte.ITO-PET · 370 um | S7 · Figures · Fig. S6 |
| CuNi-HHTP computational modelresearch_0768__mat__mat_cuni_hhtp | Model · Model System · Model | DFT model constructed by partial metal substitution. | S4 · DFT Calculations |
| Laser-scribed interdigital CuNi-HHTP MSCresearch_0768__mat__mat_cuni_hhtp | Electrode · Target Sample · Composite | CO2-laser-scribed interdigital device with Cu current collectors and PVA/KCl gel electrolyte.ITO-PET · 190 um | p005 / 9280 · Results and discussion · Fig. 5a-b |
| CuNi-HHTP nanorodsresearch_0768__mat__mat_cuni_hhtp | Powder · Target Sample · Mixed Metal | As-synthesised nanorod-like crystals. | S2 · Experimental Procedures |
| Ni-HHTPresearch_0768__mat__mat_ni_hhtp | Powder · Pristine Control · Pristine Framework | As-synthesised single-metal control. | S2 · Experimental Procedures |