Diffraction Structure — A Nanotubular Metal–Organic Framework with a Narrow Bandgap from Extended Conjugation**

Measurement evidence

Diffraction Structure

A Nanotubular Metal–Organic Framework with a Narrow Bandgap from Extended Conjugation** · Ayhan M.M., Bayraktar C., Yu K.B. et al. · Chemistry - A European Journal · 2020 · 14813-14816

1 measurement group · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Single-crystal X-ray diffraction on Bruker APEX II QUAZAR; SHELXT/SHELXL refinement in Olex2; PLATON/SQUEEZE solvent treatment

GTUB-4 dark red needle-like crystals · Single Crystal

MoKalpha radiation, lambda = 0.71073 A; 296 K; orthorhombic Cccm; crystallographic data deposited as CCDC 1968405.

Temperature
296
Context
pristine framework crystal
Measurement source
3-4 · X-ray crystallography · Table S1; Table S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Unit-cell a parameter12.286(2)(2)SI Table
Exact Reported
4 · X-ray crystallography · Table S1
Unit-cell b parameter32.337(5)(5)SI Table
Exact Reported
4 · X-ray crystallography · Table S1
Unit-cell c parameter36.554(6)(6)SI Table
Exact Reported
4 · X-ray crystallography · Table S1
CCDC deposition number1968405SI Table
Exact Reported
4 · X-ray crystallography · Table S1
Unit-cell volume14523(4)(4)SI Table
Exact Reported
4 · X-ray crystallography · Table S1
Calculated density1.078SI Table
Exact Reported
4 · X-ray crystallography · Table S1
Space groupCccmSI Table
Exact Reported
4 · X-ray crystallography · Table S1
Nanotubular structure dimensionalityone-dimensional tubular structureText
Qualitative
2 · Structure discussion · Figure 1
Cross-packed nanotube angle41.87 degreesText
Exact Reported
2 · Structure discussion · Figure 2D
Potential solvent area fraction of unit cell38.4%Text
Exact Reported
3 · X-ray crystallography
Potential solvent void volume5581.8 A3Text
Exact Reported
3 · X-ray crystallography
Z value8SI Table
Exact Reported
4 · X-ray crystallography · Table S1