Spectroscopy — Conductive Co-based metal organic framework nanostructures for excellent potassium- and lithium-ion storage: kinetics and mechanism studies

3 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Co-CAT MOF LIB anode electrode · Electrode

Fresh, lithiated, and delithiated Co-CAT MOF electrodes analysed for C 1s, Co 2p, FTIR, and XRD changes.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
new FTIR absorption during lithiation	near 1639 cm^-1	—	near	Text Approximate	4082 · Results and discussion · Fig. S16E
lithiated C-Li C 1s peak	289.7 eV	—	—	Text Exact Reported	4082 · Results and discussion · Fig. S16A-C

Co-CAT MOF PIB anode electrode · Electrode

Fresh, potassiated, and depotassiated Co-CAT MOF electrodes analysed to infer redox sites and reversibility.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
potassiated C 1s K-pi interaction peak 1	292.8 eV	—	—	Text Exact Reported	4080 · Results and discussion · Fig. 6B
potassiated C 1s K-pi interaction peak 2	295.6 eV	—	—	Text Exact Reported	4080 · Results and discussion · Fig. 6B
calculated theoretical capacity for 8-electron K storage	785.4 mA h g^-1	—	—	Calculated From Reported Exact Reported	4081 · Results and discussion · Eqn 6; Fig. S10

as-synthesised Co-CAT MOF powder · Powder

XPS survey/high-resolution C 1s, O 1s, Co 2p; FTIR 4000-400 cm^-1 compared with HHTP ligand.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C 1s C=C binding energy	284.1 eV	—	—	Text Exact Reported	4077 · Results and discussion · Fig. 2B
Co 2p3/2 binding energy	781.3 eV	—	—	Text Exact Reported	4077 · Results and discussion · Fig. 2D
FTIR C=C vibration	1468 cm^-1	—	—	Text Exact Reported	4077 · Results and discussion · Fig. 2E
FTIR O-H vibration	3410 cm^-1	—	—	Text Exact Reported	4077 · Results and discussion · Fig. 2E