Complete recipeSource: Both
Route 1: Solvothermal
SI p.S2 · S1 Experimental details
Metal precursors53 mg M(trifluoroacetylacetonate)2 for M = Cu(II)
Linker precursors37 mg 2,3,6,7,10,11-hexahydroxytriphenylene
Solvents5 mL deionized water; 0.5 mL NMP added after 10 min stirring; water and acetone for activation solvent exchange
AtmosphereSynthesis atmosphere not stated; activated powder placed under argon atmosphere
Temperature85
Time12
Work-upAllowed to cool to room temperature, filtered with a 100 nm PTFE membrane filter, rinsed with a large amount of water and acetone, and collected as as-prepared dark purplish powder.
ActivationAs-prepared sample immersed in deionized water for a day, decanted/exchanged with fresh water and repeated three times; treated with acetone in the same manner; vacuumed for 3 h; stored under argon.
Scalability contextBatch preparation in a 30 mL vial; no scale-up discussion.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | M(trifluoroacetylacetonate)2 (for M = CuII) | 53 mg | SI p.S2 · S1 Experimental details |
| Linker | 2,3,6,7,10,11-hexahydroxytriphenlyene | 37 mg | SI p.S2 · S1 Experimental details |
| Solvent | deionized water | 5 mL | SI p.S2 · S1 Experimental details |
| Solvent | NMP (N-methyl-2-pyrrolidone) | 0.5 mL | SI p.S2 · S1 Experimental details |
| Solvent | acetone | large amount for rinse; used for solvent exchange | SI p.S2 · S1 Experimental details |