Complete recipeSource: Both
Route 1: Solvothermal
SI S4 / rendered p005 · 2.3 Synthesis of Cu-HHTQ · Scheme S2
Metal precursorsCuSO4*5H2O (45 mg, 0.18 mmol)
Linker precursorsHHTQ (50 mg, 0.12 mmol)
Solvents1 mL N,N-dimethylformamide (DMF) plus 2 mL deionised water
AtmosphereSealed 10 mL scintillation vial; no inert gas specified.
Temperature85
Time24
Oxidant / reductantCu(II) salt; O2 shown in Scheme S2 as part of oxidative framework formation.
Work-upCollected by suction filtration using 0.45 um nylon membrane; washed twice with DMF, deionised water, ethanol, and acetone.
ActivationDried in vacuum at 120 C overnight.
Scalability contextSmall-vial batch recipe; no scale-up information reported.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | HHTQ | 50 mg, 0.12 mmol | SI S4 / rendered p005 · 2.3 Synthesis of Cu-HHTQ · Scheme S2 |
| Solvent | N,N-dimethylformamide (DMF) | 1 mL | SI S4 / rendered p005 · 2.3 Synthesis of Cu-HHTQ · Scheme S2 |
| Metal Source | CuSO4*5H2O | 45 mg, 0.18 mmol | SI S4 / rendered p005 · 2.3 Synthesis of Cu-HHTQ · Scheme S2 |
| Solvent | deionized water | 2 mL | SI S4 / rendered p005 · 2.3 Synthesis of Cu-HHTQ · Scheme S2 |
| Other | nylon membrane | pore size 0.45 um | SI S4 / rendered p005 · 2.3 Synthesis of Cu-HHTQ · Scheme S2 |