Complete recipeSource: Both
Route 1: Solvothermal
664 · 2.2 Synthesis of [Zn3(HL)6]n (1)
Metal precursorsZn(NO3)2.6H2O (0.029 g, 0.1 mmol)
Linker precursors3-hydroxypyridine-2-carboxylic acid (0.014 g, 0.1 mmol)
SolventsEtOH (5 mL)
Additivesgallic acid (0.019 g, 0.1 mmol)
Atmospherenot specified; sealed 25 mL Teflon-lined stainless steel vessel
Temperature85
Time24
Work-upAllowed to cool to room temperature at 10 K per hour; colorless crystals washed with ethanol.
Activationnot reported
Scalability contextSmall sealed-vessel batch; yield 35% based on Zn(NO3)2.6H2O.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Zn(NO3)2.6H2O | 0.029 g, 0.1 mmol | 664 · 2.2 Synthesis of [Zn3(HL)6]n (1) |
| Linker | 3-hydroxypyridine-2-carboxylic acid | 0.014 g, 0.1 mmol | 664 · 2.2 Synthesis of [Zn3(HL)6]n (1) |
| Additive | gallic acid | 0.019 g, 0.1 mmol | 664 · 2.2 Synthesis of [Zn3(HL)6]n (1) |
| Solvent | EtOH | 5 mL | 664 · 2.2 Synthesis of [Zn3(HL)6]n (1) |