Primary study2022
Atomically Precise Integration of Multiple Functional Motifs in Catalytic Metal-Organic Frameworks for Highly Efficient Nitrate Electroreduction
Lv Y., Su J., Gu Y. et al. · JACS Au · 2022
Reported here: 2D In-MOF In8
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1 papers
Lv Y., Su J., Gu Y. et al. · JACS Au · 2022
Reported here: 2D In-MOF In8
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Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| 2D In-MOF In82022 · Atomically Precise Integration of Multiple Functional Motifs in Catalytic Metal-Organic Frameworks for Highly Efficient Nitrate Electroreduction | [(CH3)2NH2][In(TTFOC)] / In8; elemental formula reported as C45H89N6O34S4InIndium carboxylate [In(COO)4]- nodes with atomically dispersed In sites; in situ ligand dissociation forms InII active sites during NO3RR. · Redox-active tetrathiafulvaleneoctacarboxylate ligand H8TTFOC/TTFOC with uncoordinated carboxylic acid groups. | 2D · PristineRigid 2D porous In-MOF with b-direction channels of about 4 and 5 A and c-direction rectangular channels of about 8 x 10 A and 6 x 10 A; PXRD agrees with calculated pattern. | main p.2-4, article pp.2766-2768 · Results and Discussion · Fig. 1; Figs. S7-S11 |