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1 papers
Liu J., Lu Z.-X., Wu F.-F. et al. · Chinese Chemical Letters · 2023
Reported here: Compound 1, chiral Ag(I) srs supramolecular framework
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Compound 1, chiral Ag(I) srs supramolecular framework2023 · A chiral SrSi2 (srs) superstructure constructed by a dual interaction system showing isotropic electrical conductivity | [Ag(I)3L2]2.3OTf; CIF formula C147 H105 Ag6 F9 N28 O9 S3; L = tris(2-naphthimidazolylmethyl)amineFan-shaped trinuclear [Ag(I)3L2] cations; Ag(I)...Ag(I) contact about 2.99 A in the main text and 2.9898(12) A in the CIF. · Tripodal ligand L = tris(2-naphthimidazolylmethyl)amine; OTf- anions hydrogen-bond to the framework; intermolecular pi-pi interactions function as supramolecular linkers. | 3D · PristineCubic chiral P4132/P 41 3 2 framework with srs topology, constructed by hydrogen bonding and bidirectional pi-pi interactions; pi-stacked helical columns run along all three Cartesian coordinates. | main p.2 · Main text · Fig. 1 |