Primary study2022
Bromine Vapor Induced Continuous p- to n-Type Conversion of a Semiconductive Metal-Organic Framework Cu[Cu(pdt)2]
Gupta S., Tanaka H., Sato T. et al. · Inorganic Chemistry · 2022
Reported here: Cu[Cu(pdt)2]
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Cu[Cu(pdt)2]
This group combines only harmless case, dash and spacing variants of the reported identity. It does not assert a broader chemical equivalence without source review.
3primary papers
3material records
7linked samples
8linked measurements
35linked results
2009–2022publication span
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Primary study2010
Conductivity, doping, and redox chemistry of a microporous dithiolene-based metal-organic framework
Kobayashi Y., Jacobs B., Allendorf M.D. et al. · Chemistry of Materials · 2010
Reported here: Cu[Cu(pdt)2]
Primary study2009
Electroconductive porous coordination polymer Cu[Cu(pdt)2] composed of donor and acceptor building units
Takaishi S., Hosoda M., Kajiwara T. et al. · Inorganic Chemistry · 2009
Reported here: Cu[Cu(pdt)2]
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Cu[Cu(pdt)2]2022 · Bromine Vapor Induced Continuous p- to n-Type Conversion of a Semiconductive Metal-Organic Framework Cu[Cu(pdt)2] | Cu[Cu(pdt)2] (pdt = 2,3-pyrazinedithiolate)Copper centres; pristine oxidation-state description CuII[CuII(pdt)2] · 2,3-pyrazinedithiolate (pdt) | 3D · PristineTetragonal P42/mmc conductive MOF with 1D pores, pore diameter about 3.4 A; structure shown by prior crystal model and PXRD retained after bromine doping. | 1-2 · Introduction; Experimental Section · Figure 1 |
| Cu[Cu(pdt)2]2010 · Conductivity, doping, and redox chemistry of a microporous dithiolene-based metal-organic framework | Cu[Cu(pdt)2]; pdt2- = pyrazine-2,3-dithiolateCu connector units and copper bis-dithiolate units · Pyrazine-2,3-dithiolate (pdt2-) ligand | 3D · PristineIsostructural Cu analogue used as comparison; SI assigns the same P42/mmc unit-cell family before desolvation. | 1 · Main text |
| Cu[Cu(pdt)2]2009 · Electroconductive porous coordination polymer Cu[Cu(pdt)2] composed of donor and acceptor building units | Cu[Cu(pdt)2]; CIF formula sum C8 H4 Cu2 N4 S4Cu connector ions and Cu in [Cu(pdt)2] units; assigned as CuII[CuII(pdt)2] in the paper · 2,3-pyrazinedithiolate (pdt) with pyrazine N donor sites and dithiolate S donors | 3D · PristinePorous coordination polymer in a tetragonal lattice with one-dimensional vacant spaces; N atoms of the pyrazine moiety coordinate to Cu ions. | 9048 / p001 · Introduction |