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1 papers
Zasada L.B., Guio L., Kamin A.A. et al. · Journal of the American Chemical Society · 2022
Reported here: CuTOTP-OC2 copper metal-organic macrocycle
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| CuTOTP-OC2 copper metal-organic macrocycle2022 · Conjugated Metal-Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity | (CuC22H16O6)(H2O)1.7(C3H7O)0.2 (analytical formula); CuTOTP-OC2Cu centres; XANES/XPS support predominantly Cu(II) in square-planar Cu-O coordination. · H4TOTP-OC2 ligand; TOTP-OR = alkoxy-capped 2,3,6,7-tetraoxidotriphenylene with linear alkyl R = C2. | 0D · PristineDiscrete planar hexagonal metal-organic macrocycle; self-assembles by pi-pi stacking into ordered 1D columnar/nanotube assemblies with ca. 2 nm internal channels and ca. 3.20 A interlayer spacing. | main p.1 · Abstract |