cMOF Evidence Base
Porosity — Conjugated Metal-Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity

Measurement evidence

Porosity

Conjugated Metal-Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity · Zasada L.B., Guio L., Kamin A.A. et al. · Journal of the American Chemical Society · 2022 · 4515-4521

1 measurement group · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Gas sorption / BET from CO2 at 195 K

Gas sorption and porosity

CuTOTP-OC2 bulk powder/pellet sample · Powder

77 K N2 adsorption showed no porosity; 195 K CO2 isotherm gave BET surface area.

Measurement source
main p.3 · Synthesis and structure · Table S8; Fig. S25
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET C67.558525——SI Table
Exact Reported		SI S18 · Supplementary tables · Table S8
BET correlation coefficient0.9994359——SI Table
Exact Reported		SI S18 · Supplementary tables · Table S8
BET Qm2.6448——SI Table
Exact Reported		SI S18 · Supplementary tables · Table S8
BET slope0.3725——SI Table
Exact Reported		SI S18 · Supplementary tables · Table S8
BET surface area from 195 K CO2Marked as a best value within this paper226.1698 +/- 2.5043—2.5043SI Table
Exact Reported		SI S18 · Supplementary tables · Table S8
BET Y-intercept0.0056——SI Table
Exact Reported		SI S18 · Supplementary tables · Table S8
77 K N2 porosity observationNo porosity observed——Text
Qualitative		main p.3 · Synthesis and structure