Microscopy Morphology — Conjugated Metal-Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity

5 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CuTOTP-OC4 bulk powder/pellet sample · Powder

AFM in air on Bruker Icon; 1 mg/mL solution shaken, sonicated 20 s, drop-cast onto freshly cleaved mica.

Measurement source: SI S2 · General materials and methods; supplementary figures · Fig. S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
AFM striation/edge separation	~4	—	—	Caption Approximate	SI S24 · Supplementary figures · Fig. S9
average columnar stack length	23(6)	—	6	Caption Exact Reported	SI S24 · Supplementary figures · Fig. S9

CuTOTP-OC18 bulk powder/pellet sample · Powder

DLS on CuTOTP-OC18 number particle size distribution in THF, CHCl3 and toluene.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
OC18 hydrodynamic diameter in CHCl3	5.367	—	0.787	SI Table Exact Reported	SI S16 · Supplementary tables · Table S1
OC18 hydrodynamic diameter in THF	5.174	—	1.12	SI Table Exact Reported	SI S16 · Supplementary tables · Table S1
OC18 hydrodynamic diameter in Toluene	3.939	—	0.944	SI Table Exact Reported	SI S16 · Supplementary tables · Table S1

CuTOTP-OR family-level sample (variant not individually separated in reported result) · Unknown

THF dispersions of OC2, OC4 and OC6 after sonication; unstable and further aggregation observed over time.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
THF-dispersed CuTOTP-OC2 particle size	around 90	—	—	Text Approximate	main p.3 · Synthesis and structure
THF-dispersed CuTOTP-OC4 particle size	around 200	—	—	Text Approximate	main p.3 · Synthesis and structure
THF-dispersed CuTOTP-OC6 particle size	around 300	—	—	Text Approximate	main p.3 · Synthesis and structure

CuTOTP-OC18 bulk powder/pellet sample · Powder

TEM of THF drop-cast CuTOTP-OC18; over 250 particles measured.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
macrocycle diameter	1.80 +/- 0.29	—	0.29	Caption Exact Reported	SI S23 · Supplementary figures · Fig. S8

CuTOTP-OC4 bulk powder/pellet sample · Powder

TEM of dilute THF drop-cast CuTOTP-OC4 on carbon/graphene support grids; over 250 particles measured by ImageJ.

Measurement source: SI S2-S3 · General materials and methods; supplementary figures · Fig. S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
macrocycle diameter	1.88 +/- 0.43	—	0.43	Caption Exact Reported	SI S23 · Supplementary figures · Fig. S7
stack spacing	~0.31	—	—	Caption Approximate	SI S23 · Supplementary figures · Fig. S7