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Kon K., Uchida K., Fuku K. et al. · ACS Applied Materials and Interfaces · 2021
Reported here: {Fe(Hdhbq)2}2 / Fe2(dhbq)(Hdhbq)2(H2O)4 model systems
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| {Fe(Hdhbq)2}2 / Fe2(dhbq)(Hdhbq)2(H2O)4 model systems2021 · Electron-Conductive Metal-Organic Framework, Fe(dhbq)(dhbq = 2,5-Dihydroxy-1,4-benzoquinone): Coexistence of Microporosity and Solid-State Redox Activity | {Fe(Hdhbq)2}2; Fe2(dhbq)(Hdhbq)2(H2O)4Fe(II) centres in finite dimer model complexes · Hdhbq/dhbq ligands | 0D · Model SystemDFT-optimised dimer and calculated orbital/spectral models used to rationalise Fe(dhbq) structure and MLCT absorption. | 3 · Results and Discussion · Figure S9 |