Primary study2022
A stable lanthanum hydroxamate metal-organic framework with radical character and electrical conductivity
Yan Y., Zhang N.-N., Fuhrmann D. et al. · Dalton Transactions · 2022
Reported here: La-ONDI
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1 papers
Yan Y., Zhang N.-N., Fuhrmann D. et al. · Dalton Transactions · 2022
Reported here: La-ONDI
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Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| La-ONDI2022 · A stable lanthanum hydroxamate metal-organic framework with radical character and electrical conductivity | {[La(ONDI)(H2O)2]Cl.2H2O.0.75DMA}n; SI empirical formula C17H18.75ClLaN2.75O10.75La3+ nodes in linear one-dimensional La-O chains; each La3+ is ten-fold coordinated by eight O atoms from four ONDI2- ligands and two coordinated water molecules. · ONDI2- hydroxamate linker from H2ONDI, 2,7-dihydroxybenzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone. | 3D · PristineCationic porous 3D hydroxamate framework, [La(ONDI)]+, crystallising in C2/c with 1D channels along the c axis; described as MIL-47/MOF-69A-like rod packing. | 1-2 · Abstract; Results and discussion - Synthesis and crystal structure · Fig. 1 |