Electrochemistry Application — A stable lanthanum hydroxamate metal-organic framework with radical character and electrical conductivity

Measurement evidence

Electrochemistry Application

A stable lanthanum hydroxamate metal-organic framework with radical character and electrical conductivity · Yan Y., Zhang N.-N., Fuhrmann D. et al. · Dalton Transactions · 2022 · 15946-15953

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

solid-state cyclic voltammetry

La-ONDI-DMA single crystals · Single Crystal

Three-electrode cell at room temperature; about 8 mg La-ONDI abraded with ethanol, water and 5 wt% Nafion, drop-cast on glassy carbon; Pt wire counter, Ag/Ag+ reference; 0.1 M [(n-Bu)4N]PF6 in acetonitrile under N2; referenced to Fc/Fc+.

Temperature
room temperature
Atmosphere
N2
Geometry
La-ONDI/Nafion dispersion on glassy carbon working electrode
Context
La-ONDI in electrochemical electrode mixture
Measurement source
6 · Experimental - Cyclic voltammetry · Fig. S19
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
La-ONDI solid-state CV redox wave E1/2 more negativeE1/2 = -1.16 eVCaption
Rounded Reported
14 · Fig. S19 · Fig. S19
La-ONDI solid-state CV redox wave E1/2 less negativeE1/2 = -0.82 eVCaption
Rounded Reported
14 · Fig. S19 · Fig. S19