Primary study2009
Rational designs for highly proton-conductive metal-organic frameworks
Sadakiyo M., Yamada T., Kitagawa H. · Journal of the American Chemical Society · 2009
Reported here: (NH4)2(adp)[Zn2(ox)3].3H2O (compound 1)
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1 papers
Sadakiyo M., Yamada T., Kitagawa H. · Journal of the American Chemical Society · 2009
Reported here: (NH4)2(adp)[Zn2(ox)3].3H2O (compound 1)
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Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| (NH4)2(adp)[Zn2(ox)3].3H2O (compound 1)2009 · Rational designs for highly proton-conductive metal-organic frameworks | (NH4)2(adp)[Zn2(ox)3].3H2O; adp = adipic acid; ox = oxalateZn2+ ions octahedrally coordinated by three oxalate ligands in oxalate-bridged [Zn2(ox)3]2- sheets. · Oxalate framework linkers plus adipic acid molecules in the interlayer/voids; NH4+ counterions and water molecules form the proton-conducting medium. | 2D · PristineLayered oxalate-bridged anionic honeycomb framework with interlayer adipic acid, NH4+ and water; SCXRD at 113 K. | 1 · main text · Figure 1 |