Spectroscopy — Rational designs for highly proton-conductive metal-organic frameworks

Measurement evidence

Spectroscopy

Rational designs for highly proton-conductive metal-organic frameworks · Sadakiyo M., Yamada T., Kitagawa H. · Journal of the American Chemical Society · 2009 · 9906-9907

1 measurement group · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FT-IR spectroscopy with compacted KBr pellets

Air-dried sample of compound 1 · Powder

Thermo Nicolet NEXUS 670 FT-IR; spectra compared for reference oxalate framework, air-dried compound 1, adipamide and adipic acid.

Geometry
compacted KBr pellets
Context
pristine target MOF
Measurement source
S2 · IR spectroscopy · Figure S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
amide stretching mode in compound 1amide group stretching mode absentText
Qualitative
1 · structure discussion · Figure S1
carboxylic-acid C=O stretching mode in air-dried sampleweakly observed at 1736 cm-1Text
Exact Reported
S2 · IR spectroscopy · Figure S1
oxalate C=O stretching mode in air-dried sample1628 cm-1Text
Exact Reported
S2 · IR spectroscopy · Figure S1