Synthesis evidence

Rational designs for highly proton-conductive metal-organic frameworks

Sadakiyo M., Yamada T., Kitagawa H. · Journal of the American Chemical Society · 2009 · 9906-9907

1 structured synthesis route

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

Route 1: Hydrothermal

S1 · Synthesis of (NH4)2(adp)[Zn2(ox)3].3H2O

Metal precursorsZnO (10 mmol, 814 mg)
Linker precursorsH2(ox).2H2O (20 mmol, 2521 mg) and adipamide (10 mmol, 1442 mg); adipamide converted to adipic acid under hydrothermal conditions.
Solventsdistilled water (550 mmol, 10 ml)
Atmospherenot specified
Temperature130
Time24
Work-upSlowly cooled to room temperature over 168 h; precipitate collected by filtration and washed with distilled water.
ActivationAir-dried; no separate activation reported.
Scalability contextYield reported as 2891 mg, 92%.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceZnO10 mmol, 814 mgS1 · Synthesis of (NH4)2(adp)[Zn2(ox)3].3H2O
LinkerH2(ox).2H2O20 mmol, 2521 mgS1 · Synthesis of (NH4)2(adp)[Zn2(ox)3].3H2O
Linkeradipamide10 mmol, 1442 mgS1 · Synthesis of (NH4)2(adp)[Zn2(ox)3].3H2O
Solventdistilled water550 mmol, 10 mlS1 · Synthesis of (NH4)2(adp)[Zn2(ox)3].3H2O