Primary study2017
Synthesis of ordered carbonaceous frameworks from organic crystals
Nishihara H., Hirota T., Matsuura K. et al. · Nature Communications · 2017
Reported here: Ni2-CPDPy593(0) crystalline covalent-organic framework intermediate
Reported material
Ni2-CPDPy593(0) crystalline covalent-organic framework intermediate
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2017–2017publication span
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Ni2-CPDPy593(0) crystalline covalent-organic framework intermediate2017 · Synthesis of ordered carbonaceous frameworks from organic crystals | C92H48N12Ni2Retained square-planar Ni-N4 porphyrin centres · Poly(diacetylene) backbone cross-linking CPDPy units | 2D · PristineCrystalline polymer/COF intermediate; stacked two-dimensional sheets after thermal polymerisation at 593 K. | 4 · Crystallographic structural changes upon carbonization · Fig. 2h-j; Supplementary Fig. 4-5 |