Primary study2021
Conjugated crosslinks boost the conductivity and stability of a single crystalline metal-organic framework
Zhou H.-Q., He Y., Hu J.-Y. et al. · Chemical Communications · 2021
Reported here: ZrBPD-4F4TS-Ox
Reported material
ZrBPD-4F4TS-Ox
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2021–2021publication span
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| ZrBPD-4F4TS-Ox2021 · Conjugated crosslinks boost the conductivity and stability of a single crystalline metal-organic framework | FeCl3-oxidised/crosslinked derivative of ZrBPD-4F4TS; exact post-oxidation framework formula not resolvedRetained Zr6-carboxylate host net after oxidative crosslinking · BPD-4F4TS linkers with FeCl3-homocoupled thiophene units forming conjugated C-C crosslinks through sulfide-linked thiophene arms | 3D · PristineCrosslinked UiO-67-type host net; SCXRD differences from ZrBPD-4F4TS not resolved, but PXRD confirms retained crystalline order under multiple tests. | PDF p.3 / article p.188 · Main text · Fig. 1; Fig. 2 |