Porosity — Conjugated crosslinks boost the conductivity and stability of a single crystalline metal-organic framework

Measurement evidence

Porosity

Conjugated crosslinks boost the conductivity and stability of a single crystalline metal-organic framework · Zhou H.-Q., He Y., Hu J.-Y. et al. · Chemical Communications · 2021 · 187-190

4 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CO2 adsorption/desorption isotherm and surface area

activated ZrBPD-4F4TS-Ox · Powder

CO2 at 195 K

Temperature
195
Atmosphere
CO2
Geometry
powder
Context
crosslinked framework
Measurement source
PDF p.4 / article p.189 · Main text · Fig. S36
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
CO2-derived surface area131.3 m2 g^-1Text
Rounded Reported
PDF p.4 / article p.189 · Main text · Fig. S36
CO2 sorption capacity at 1 bar60.6 cm3 g^-1Text
Rounded Reported
PDF p.4 / article p.189 · Main text · Fig. S36

CO2 adsorption/desorption isotherm and surface area

activated ZrBPD-4F4TS · Powder

CO2 at 195 K

Temperature
195
Atmosphere
CO2
Geometry
powder
Context
pristine framework
Measurement source
PDF p.4 / article p.189 · Main text · Fig. S35
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
CO2-derived surface area166.9 m2 g^-1Text
Rounded Reported
PDF p.4 / article p.189 · Main text · Fig. S35
CO2 sorption capacity at 1 bar76.0 cm3 g^-1Text
Rounded Reported
PDF p.4 / article p.189 · Main text · Fig. S35

N2 adsorption/desorption isotherm and BET analysis

activated ZrBPD-4F4TS-Ox · Powder

N2 at 77 K after activation

Temperature
77
Atmosphere
N2
Geometry
powder
Context
crosslinked framework
Measurement source
PDF p.4 / article p.189 · Main text · Fig. S34
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area from N23.6 m2 g^-1Text
Rounded Reported
PDF p.4 / article p.189 · Main text · Fig. S34

N2 adsorption/desorption isotherm and BET analysis

activated ZrBPD-4F4TS · Powder

N2 at 77 K after activation

Temperature
77
Atmosphere
N2
Geometry
powder
Context
pristine framework
Measurement source
PDF p.4 / article p.189 · Main text · Fig. S33
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area from N2177.2 m2 g^-1Text
Rounded Reported
PDF p.4 / article p.189 · Main text · Fig. S33