Electrical Transport — Mn2(2,5-disulfhydrylbenzene-1,4-dicarboxylate): A microporous metal-organic framework with infinite (-Mn-S-)∞ chains and high intrinsic charge mobility

6 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Activated 1/PMMA FP-TRMC film · Thin Film

FP-TRMC phi-sum-mu divided by TOF-derived carrier generation efficiency.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Charge mobility from combined FP-TRMC/TOFMarked as a best value within this paper	0.01 cm2 V-1 s-1	—	—	Text Exact Reported	main p.8187 · Main text, transport · Figure 4

Methanol-exchanged 1/PMMA FP-TRMC film · Thin Film

FP-TRMC phi-sum-mu divided by TOF-derived carrier generation efficiency.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Charge delocalisation length in Mn-S units	8-12 Mn-S units	—	range 8-12	Text Range	main p.8187 · Main text, transport
Charge-carrier displacement length per microwave period	2-3 nm	—	range 2-3	Text Range	main p.8187 · Main text, transport
Charge mobility from combined FP-TRMC/TOFMarked as a best value within this paper	0.02 cm2 V-1 s-1	—	—	Text Exact Reported	main p.8187 · Main text, transport · Figure 4

Activated 1/PMMA FP-TRMC film · Thin Film

25 deg C ambient; 355 nm Nd:YAG excitation; 1.4e16 photons/cm2 per pulse; microwave power 3 mW and frequency about 9.1 GHz.

Temperature: 298
Atmosphere: ambient
Geometry: 50/50 wt% activated MOF/PMMA film on quartz in resonant microwave cavity
Context: Composite film containing activated framework
Measurement source: SI p.S3 · FP-TRMC measurements · Figure 4a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Maximum FP-TRMC phi-sum-mu	2 x 10^-5 cm2 V-1 s-1	—	—	Text Rounded Reported	main p.8187 · Main text, transport · Figure 4a

Methanol-exchanged 1/PMMA FP-TRMC film · Thin Film

25 deg C ambient; 355 nm Nd:YAG excitation; 1.4e16 photons/cm2 per pulse; microwave power 3 mW and frequency about 9.1 GHz.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Maximum FP-TRMC phi-sum-mu	2 x 10^-5 cm2 V-1 s-1	—	—	Text Rounded Reported	main p.8187 · Main text, transport · Figure 4a

Activated 1/PMMA TOF device · Electrode

355 nm excitation; 1.9e14 photons/cm2 per pulse; 10 kOhm terminating resistance; applied bias 3e4 V/cm.

Geometry: 50/50 wt% activated MOF/PMMA film between 50 nm Al and 30 nm Au electrodes on silicon wafer
Context: Composite device containing activated framework
Measurement source: SI p.S3-S4 · TOF measurements · Figures 4b,S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Figure S5 activated first-component mobility range	approximately 0.0007-0.002 cm2 V-1 s-1	—	visual range	Visual Estimate Approximate	SI p.S12 · Figure S5 · Figure S5c
TOF long-range mobility at E = 0 V/cm	0.001 cm2 V-1 s-1	—	—	Text Exact Reported	main p.8187 · Main text, transport · Figure S5
TOF-derived carrier generation quantum efficiencyMarked as a best value within this paper	1.4 x 10^-3	—	—	Text Exact Reported	main p.8187 · Main text, transport · Figure 4b

Methanol-exchanged 1/PMMA TOF device · Electrode

355 nm excitation; 1.9e14 photons/cm2 per pulse; 10 kOhm terminating resistance; applied bias 3e4 V/cm.

Geometry: 50/50 wt% MOF/PMMA film between 50 nm Al and 30 nm Au electrodes on silicon wafer
Context: Composite device containing methanol-exchanged framework
Measurement source: SI p.S3-S4 · TOF measurements · Figures 4b,S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Figure S5 methanol-exchanged first-component mobility range	approximately 0.001-0.004 cm2 V-1 s-1	—	visual range	Visual Estimate Approximate	SI p.S12 · Figure S5 · Figure S5c
Figure S5 second-component mobility scale	approximately 1e-5 to 1e-4 cm2 V-1 s-1	—	visual range	Visual Estimate Approximate	SI p.S12 · Figure S5 · Figure S5c
TOF-derived carrier generation quantum efficiencyMarked as a best value within this paper	9.7 x 10^-4	—	—	Text Exact Reported	main p.8187 · Main text, transport · Figure 4b