Thermogravimetric analysis (TGA)
As-synthesised bulk dark maroon powder of compound 1 · Powder
TA Instruments Q500; SI methods state 0.5 deg C/min under nitrogen flow of 90 mL/min; Figure S1 caption states 1 deg C/min under N2.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Adsorbed solvent loss annotation in Figure S1 | 15.90% adsorbed solvent loss (0.4861 mg) | 15.9 % | — | Figure Axis Rounded Reported | SI p.S5 · Figure S1 · Figure S1 |
| Final decomposition temperature threshold | final decomposition upward of 400 deg C | 673.15 K | upward of | Text Approximate | main p.2 / article p.12933 · TGA discussion · Figure S1 |
| Expected mass loss for guest DMF and coordinated water | 28.2% expected | 28.2 % | — | Text Rounded Reported | main p.2 / article p.12933 · TGA discussion · Figure S1 |
| Mass loss between 100 and 140 deg C | 28.3% between 100 and 140 deg C | 28.3 % | — | Text Rounded Reported | main p.2 / article p.12933 · TGA discussion · Figure S1 |
| Thermal stability plateau onset | large plateau of thermal stability above 180 deg C | 453.15 K | above | Text Approximate | main p.2 / article p.12933 · TGA discussion · Figure S1 |
| Surface solvent loss annotation in Figure S1 | 12.40% surface solvent (0.3792 mg) | 12.4 % | — | Figure Axis Rounded Reported | SI p.S5 · Figure S1 · Figure S1 |