Spectroscopy — Tunable Charge Transport Properties Through Precise π-Stacking Modulation in Isostructural Porous Molecular Conductors

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

PMC-3-Cl single crystals · Single Crystal

Static magnetic susceptibility on polycrystalline PMC-3-Cl and PMC-3-Br from 2-300 K; fit to Curie plus singlet-triplet thermal excitation model.

Temperature: 2-300
Geometry: Polycrystalline sample
Context: Pristine framework powders
Measurement source: SI p.S11-p.S12 · Magnetic susceptibility · Figure S7; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PMC-3-Br fitted spin density n	n = 0.026	2.6 percent	—	SI Table Exact Reported	SI p.S12 · Parameters used in fitting chi · Table S2
PMC-3-Cl fitted spin density n	n = 0.033	3.3 percent	—	SI Table Exact Reported	SI p.S12 · Parameters used in fitting chi · Table S2

PMC-3-Br single crystals · Single Crystal

PMC-3 samples dispersed in KX pellets under N2; NDI-py dispersed in KBr pellet.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PMC-3 IVCT band maximum	maximum at approximately 0.35 eV	0.35 eV	—	Text Approximate	main p.4 · Electronic States · Figure 2
NDI radical intramolecular absorption band	around 2.0 eV (620 nm)	2 eV	—	Text Approximate	main p.4 · Electronic States · Figure 2