SpectroscopyUnspecified subtype
2026 · A conductive metal-organic framework-modified electrode for sensitive electrochemiluminescent detection of cardiac Troponin I
Cu3(HHTP)2 blue-black powder · Powder · Absorption spectrum of Cu3(HHTP)2.
Electrical TransportDiffuse reflectanceTauc / Kubelka-Munk
2026 · Activating a Metallization Switch for Record Hydrogen Evolution in Single-Atom Modified Polar MOF Piezocatalysts
Ni SAs@UiO-66-NH2(Hf) powder · Powder · Electronic-state, work-function, valence-band and bandgap comparison of UiO-66, UiO-66-NH2 and Ni SAs@UiO-66-NH2.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2026 · Electronically Conductive Metal−Organic Framework With Photoelectric and Photothermal Effect as a Stable Cathode for High-Temperature Photo-Assisted Zn/Sn-Air Battery
as-synthesised Ni2DDA black powder · Powder · Optoelectronic behaviour and semiconductor band structure of Ni2DDA.
Electrochemistry ApplicationUnspecified subtype
2026 · Intrinsically Conductive π-d Conjugated Layers with Co–N4 Active Sites for Efficient Nitrate Electrocatalysis and Zinc-Nitrate Batteries
Co3(HITP)2 drop-cast carbon paper electrode · Electrode · Fixed-potential nitrate electrolysis for 30 min; 1 M KOH + 1 M KNO3; ammonia quantified by alkaline hypochlorite and phenol nitroprusside colourimetry after 30 min dark incubation.
Electrochemistry ApplicationUnspecified subtype
2026 · Intrinsically Conductive π-d Conjugated Layers with Co–N4 Active Sites for Efficient Nitrate Electrocatalysis and Zinc-Nitrate Batteries
Bare carbon paper electrode control · Electrode · Post-catalysis electrolytes compared for Co3(HITP)2 in 1 M KNO3 + 1 M KOH, bare carbon paper in 1 M KNO3 + 1 M KOH, and Co3(HITP)2 in 1 M KOH blank electrolyte.
SpectroscopyTauc / Kubelka-Munk
2026 · Investigation of charge transport and Schottky properties in a 1D Cd(II) coordination polymer featuring 9-anthracenecarboxylic acid
as-synthesised bulk CP1 · Powder · UV-vis absorption at room temperature over 350-700 nm; optical band gap determined by extrapolating the linear region of the Tauc plot.
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Isoreticular Modulation of Electrical Conduction and Magnetic Properties in Semiconducting Lanthanide-based Based Metal−Organic Frameworks
Eu-HHTP powder · Powder · spectral_range: 400-2500 nm
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Isoreticular Modulation of Electrical Conduction and Magnetic Properties in Semiconducting Lanthanide-based Based Metal−Organic Frameworks
Gd-HHTP powder · Powder · spectral_range: 400-2500 nm
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Isoreticular Modulation of Electrical Conduction and Magnetic Properties in Semiconducting Lanthanide-based Based Metal−Organic Frameworks
Sm-HHTP powder · Powder · spectral_range: 400-2500 nm
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Isoreticular Modulation of Electrical Conduction and Magnetic Properties in Semiconducting Lanthanide-based Based Metal−Organic Frameworks
Tb-HHTP powder · Powder · spectral_range: 400-2500 nm
Electrochemistry ApplicationUnspecified subtype
2026 · Metal–(organic cocrystal) framework with a photothermal effect boosting the photocatalytic degradation of pollutants
Ac@[Ca-NDI] MOCF powder · Powder · 300 W Xe lamp, 300 nm < lambda < 1200 nm; phenol 30 mg/L; dark adsorption-desorption equilibrium 30 min; sampled every 20 min; absorbance at 510 nm.
SpectroscopyUnspecified subtype
2026 · Metal–(organic cocrystal) framework with a photothermal effect boosting the photocatalytic degradation of pollutants
Ac@[Ca-NDI] MOCF dark-green block single crystals · Single Crystal · Solid-state/material absorption and band gap diagrams for Ac@[Ca-NDI] MOCF and Ca-NDI MOF.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2026 · Microenvironment modulation in heterometallic MOFs for tailoring electron/proton transport and hydrophilicity toward photocatalytic hydrogen production
Ni-Ca dark brown crystals / powder · Powder
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2026 · Microenvironment modulation in heterometallic MOFs for tailoring electron/proton transport and hydrophilicity toward photocatalytic hydrogen production
Ni-Sr brown crystals / powder · Powder
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2026 · Nanostructured zinc-doped nickel/iron metal–organic framework electrode material for an efficient energy storage
Zn-doped Ni/Fe-MOF powder before carbonisation · Powder · Agilent Cary 300, 200-800 nm; BaSO4 reflectance standard
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Ca-HHTP film sample · Thin Film · Transmission mode using integrating sphere detector and 20 nm slit width.
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Co-HHTP film sample · Thin Film · Transmission mode using integrating sphere detector and 20 nm slit width.
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Cu-HHTP film sample · Thin Film · Transmission mode using integrating sphere detector and 20 nm slit width.
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Mg-HHTP film sample · Thin Film · Transmission mode using integrating sphere detector and 20 nm slit width.
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Ni-HHTP film sample · Thin Film · Transmission mode using integrating sphere detector and 20 nm slit width.
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Zn-HHTP film sample · Thin Film · Transmission mode using integrating sphere detector and 20 nm slit width.
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Tailoring Li-ion Storage and Transport in Two-Dimensional Conjugated Metal-Organic Frameworks via Precise Nitrogen Incorporation
Cu-N2-OHBA bulk powder crystals · Powder
SpectroscopyTauc / Kubelka-MunkNear infrared
2026 · Tailoring Li-ion Storage and Transport in Two-Dimensional Conjugated Metal-Organic Frameworks via Precise Nitrogen Incorporation
Cu-N4-OHBA bulk powder crystals · Powder
SpectroscopyNear infrared
2026 · Tunable Charge Transport Properties Through Precise π-Stacking Modulation in Isostructural Porous Molecular Conductors
PMC-3-Br single crystals · Single Crystal · PMC-3 samples dispersed in KX pellets under N2; NDI-py dispersed in KBr pellet.
Electrochemistry ApplicationDiffuse reflectanceNear infraredIn situ / operando
2026 · Tunable Charge Transport Properties Through Precise π-Stacking Modulation in Isostructural Porous Molecular Conductors
PMC-3-Br solid-state electrochemical sample · Electrode · CARY5000 with Harrick Omni Diff probe, 400-2000 nm; ITO working electrode, Pt counter, Ag quasi-reference; PMC-3-Br in 0.1 M LiBF4/MeCN.
Computational ModellingUnspecified subtype
2025 · 2D Rhodium-Isocyanide Frameworks
as-prepared SJTU-201 powder · Powder · stacked and monolayer SJTUs; Table S3 summarises electronic and optical properties
Computational ModellingUnspecified subtype
2025 · 2D Rhodium-Isocyanide Frameworks
as-prepared SJTU-202 powder · Powder · stacked and monolayer SJTUs; Table S3 summarises electronic and optical properties
Computational ModellingUnspecified subtype
2025 · 2D Rhodium-Isocyanide Frameworks
as-prepared SJTU-203 powder · Powder · stacked and monolayer SJTUs; Table S3 summarises electronic and optical properties
Electrochemistry ApplicationUnspecified subtype
2025 · 2D Rhodium-Isocyanide Frameworks
model compound M1 · Model · 0.1 M K2SO4, Ar/N2-saturated comparison
SpectroscopyUnspecified subtype
2025 · A Low-Symmetry Copper Benzenehexathiol Coordination Polymer with In-Plane Electrical Anisotropy
Cu5BHT crystal domains · Single Crystal · UPS acquired at 300 K; UV/vis on Cu5BHT deposited on a quartz substrate at room temperature.
SpectroscopyUnspecified subtype
2025 · A mixed-organic ligands Ru(bpy)32+@Zn mMOFs-NH2 nanoreactors integrated co-reaction accelerator and morphologic regulator for the electrochemiluminescence detection of ATP
Ru(bpy)3(2+)@Zn mMOFs-NH2 · Nanosheet · Compared Ru(bpy)3(2+), Zn mMOFs-NH2 and Ru(bpy)3(2+)@Zn mMOFs-NH2
Electrochemistry ApplicationUnspecified subtype
2025 · A novel 2D conductive MOF nanobelts for highly efficient electrosynthesis of hydrogen peroxide
Ni-PTC-60 flow-cell gas-diffusion electrode · Electrode · 1 mM Ce(SO4)2 in 0.5 M H2SO4; 400 uL Ce(SO4)2 solution added to cathode solution; Ce4+ concentration by UV-vis.
Sensing ApplicationUnspecified subtype
2025 · Advanced dual-signal point-of-care testing platform for sensitive T-2 toxin detection: Integrating copper-based conductive MOF with target-responsive DNA hydrogel
POCT reaction solution after hydrogel response and TMB/H2O2 addition · Unknown · TMB/H2O2 assay with DNA hydrogel with and without T-2 toxin; absorbance peak at 652 nm and temperature change under laser irradiation
SpectroscopyDiffuse reflectance
2025 · Advanced dual-signal point-of-care testing platform for sensitive T-2 toxin detection: Integrating copper-based conductive MOF with target-responsive DNA hydrogel
blue-black Cu3(HHTP)2 powder · Powder · Full-wavelength optical absorption assessment of pristine Cu3(HHTP)2
SpectroscopyTauc / Kubelka-Munk
2025 · Ammonia-Assisted Chemical Vapor Deposition Growth of Two-Dimensional Conjugated Coordination Polymer Thin Films
Fe-HHB-o CVD thin film without NH3 · Thin Film · Fe-HHB-o thin film directly grown on quartz substrate.
SpectroscopyTauc / Kubelka-Munk
2025 · Ammonia-Assisted Chemical Vapor Deposition Growth of Two-Dimensional Conjugated Coordination Polymer Thin Films
Fe-HHB-w NH3-assisted CVD thin film · Thin Film · Fe-HHB-w thin film directly grown on quartz substrate.
SpectroscopyUnspecified subtype
2025 · An optoelectronic synapse based on Cu-BHT MOF for multi-wavelength optical logic gates and neuromorphic vision system
Cu-BHT thin film on ultra-white glass substrate · Thin Film · Band gap from absorption truncation; work function from secondary electron cutoff; valence-band edge from UPS.
SpectroscopyUnspecified subtype
2025 · An optoelectronic synapse based on Cu-BHT MOF for multi-wavelength optical logic gates and neuromorphic vision system
Cu-BHT thin film on ultra-white glass substrate · Thin Film · Absorption spectrum of Cu-BHT thin film.
SpectroscopyUnspecified subtype
2025 · Catalytic Metal-Organic Framework-Functionalized Inverse-Opal Architectured Polymeric Separator for High-Performance Li-S Batteries
ZIF-PIO-3 separator · Thin Film · Separators immersed in 0.2 mM Li2S6 in DOL/DME 1/1 for 5 min, then solution absorbance analysed.
Sensing ApplicationUnspecified subtype
2025 · Comparing Ag-O coordinated AgMOF-5 and Ag-N coordinated Ag nanosphere catalytic polymers for real time monitoring of H2O2 level in cancer cells
AgMOF/GCE · Electrode · H2O2 secreted by fMLP-stimulated L929, HeLa, T98G and LN18 cells quantified by phenol red/HRPO UV-vis assay at 610 nm.
Sensing ApplicationUnspecified subtype
2025 · Comparing Ag-O coordinated AgMOF-5 and Ag-N coordinated Ag nanosphere catalytic polymers for real time monitoring of H2O2 level in cancer cells
AgMOF/GCE · Electrode · PRS solution with NaCl, PBS, dextrose and phenol red; H2O2 standards from 0.1 uM to 200 uM; HRPO; NaOH stop/developing step; UV-vis at 610 nm.
SpectroscopyUnspecified subtype
2025 · Comparing Ag-O coordinated AgMOF-5 and Ag-N coordinated Ag nanosphere catalytic polymers for real time monitoring of H2O2 level in cancer cells
greyish AgMOF powder · Powder · UV-vis spectra of AgMOF and Ag nanosphere used to identify silver and aromatic-group features.
Electrochemistry ApplicationUnspecified subtype
2025 · Construction of nanozyme based with mixed valence manganese oxide loaded on defective metal-organic frameworks for sensitive detection of biomarker procalcitonin
MdP nanoparticles · Powder · Oxidase-like catalytic oxidation of TMB by MdP without H2O2; absorbance at 650 nm tracked versus MdP concentration, TMB concentration and time.
Sensing ApplicationUnspecified subtype
2025 · Construction of nanozyme based with mixed valence manganese oxide loaded on defective metal-organic frameworks for sensitive detection of biomarker procalcitonin
MdPM magnetic immunosensor assay complex · Unknown · Ab1-MBs added to PCT sample, incubated 20 min, Ab2-MdP added 20 min, TMB 0.500 mM added and shaken 30 min; blue supernatant detected.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2025 · Continuous and reversible tuning of inter-layer spacings in two-dimensional conductive metal organic frameworks
Ga9HHTP4 multi-sample comparison series · Powder · DRUV spectra in Tauc coordinates for four Ga9HHTP4 samples with inter-layer spacings from 3.27 to 3.45 Angstrom.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2025 · Continuous and reversible tuning of inter-layer spacings in two-dimensional conductive metal organic frameworks
Ni6HHTT3 multi-sample comparison series · Powder · DRUV spectra for pristine and contracted Ni6HHTT3 samples.
SpectroscopyUnspecified subtype
2025 · Copper-Based Two-Dimensional Conductive Metal-Organic Framework Thin Films for Ultrasensitive Detection of Perfluoroalkyls in Drinking Water
Pristine Cu-HHTP thin films for structural and spectroscopic characterisation · Thin Film · Agilent Cary 6000i UV/vis/NIR on Cu-HHTP films grown on cleaned glass substrates.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field
As-synthesised Cu3(HHTP)2 powder · Powder · DR UV-Vis Tauc plots for LMCT and pi-pi* charge-transfer regions; SI includes normalised UV-vis-NIR spectra.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field
As-synthesised Cu3(HITP)2 powder · Powder · DR UV-Vis Tauc plots for LMCT and pi-pi* charge-transfer regions; SI includes normalised UV-vis-NIR spectra.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field
As-synthesised Cu3(THT)2 powder · Powder · DR UV-Vis Tauc plots for LMCT and pi-pi* charge-transfer regions; SI includes normalised UV-vis-NIR spectra.
SpectroscopyNear infrared
2025 · Dirac-cone induced metallic conductivity in Cu3(HHTP)2: high-quality MOF thin films fabricated via ML-driven robotic synthesis
Optimised Cu3(HHTP)2 SURMOF thin film · Thin Film · Agilent Cary 5000, 200-800 nm, reflection mode
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2025 · Discovery of Dual Ion-Electron Conductivity of Metal-Organic Frameworks via Machine Learning-Guided Experimentation
MOF 1 as-synthesised crystals/pellet · Pellet · ASD Quality Spec Pro UV-vis, 350-2500 nm; Eg extrapolated from (F(R) hv)^2 versus hv.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2025 · Discovery of Dual Ion-Electron Conductivity of Metal-Organic Frameworks via Machine Learning-Guided Experimentation
MOF 2 as-synthesised crystals/pellet · Pellet · ASD Quality Spec Pro UV-vis, 350-2500 nm; Eg extrapolated from (F(R) hv)^2 versus hv.
Electrochemistry ApplicationUnspecified subtype
2025 · Dual-metal sites enable conductive metal-organic frameworks with extraordinary high capacitance for transparent energy storage devices
Sandwich-type flexible transparent CuNi-HHTP supercapacitor · Electrode · Sandwich-type flexible transparent supercapacitor used as device-architecture control.
Electrochemistry ApplicationUnspecified subtype
2025 · Dual-metal sites enable conductive metal-organic frameworks with extraordinary high capacitance for transparent energy storage devices
Laser-scribed interdigital CuNi-HHTP MSC · Electrode · PVA/KCl gel electrolyte; patterned transparent CuNi-HHTP MSC; Table S2 comparison.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2025 · Electrically Conducting Redox-Complementary Dual-Ligand 2D Graphitic MOF with Orthogonal Charge Transport Pathways
CDL-MOF1 microcrystalline black powder · Powder · Shimadzu UV-2600 with ISR-2600 Plus integrating sphere, 300-1400 nm; direct optical band gaps from Tauc plots.
SpectroscopyTauc / Kubelka-Munk
2025 · Engineering the structures of ZnCo-MOFs via a ligand effect for enhanced supercapacitor performance
as-synthesised ZnCo-MOF-HMIM powder · Powder · Optical absorption spectra and indirect-transition Tauc band gaps for ligand-modified ZnCo-MOFs.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks
Cu-S-HHS interfacial film · Thin Film · Interfacial MOF film transferred to quartz; transmission mode with integrating sphere and 20 nm slit.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks
Cu-Se-HHS interfacial film · Thin Film · Interfacial MOF film transferred to quartz; transmission mode with integrating sphere and 20 nm slit.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks
Cu-Te-HHS interfacial film · Thin Film · Interfacial MOF film transferred to quartz; transmission mode with integrating sphere and 20 nm slit.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2025 · Extension of charge separation distance over isolated dual-metal sites in metal-organic frameworks for efficient CO2 photoreduction
CuCo-THQ powder · Nanosheet · Hitachi UH-4150, 800-200 nm range, BaSO4 background; Tauc plots used for band gaps.
Electrochemistry ApplicationUnspecified subtype
2025 · Fabrication of a Novel Cu Based Conjugated Coordination Polymer for Effective Electroreduction of Nitrate to Ammonia and Zn–Nitrate Batteries
Cu3(HITP)2/CF pine-like electrode · Electrode · N2H4 assays for Cu3(HITP)2/CF and Cu3(HHTP)2/CF after NRA at -0.5 to -0.9 V vs RHE; SI Figure S11.
Electrochemistry ApplicationUnspecified subtype
2025 · Fabrication of a Novel Cu Based Conjugated Coordination Polymer for Effective Electroreduction of Nitrate to Ammonia and Zn–Nitrate Batteries
Cu3(HHTP)2/CF pine-like comparison electrode · Electrode · NO2- assays for Cu3(HHTP)2/CF after NRA at -0.5 to -0.9 V vs RHE; plotted in SI Figure S10.
Electrochemistry ApplicationUnspecified subtype
2025 · Fabrication of a Novel Cu Based Conjugated Coordination Polymer for Effective Electroreduction of Nitrate to Ammonia and Zn–Nitrate Batteries
Cu3(HITP)2/CF pine-like electrode · Electrode · NO2- assays for Cu3(HITP)2/CF after NRA at -0.5 to -0.9 V vs RHE; calibration and potential-dependent FE plotted in SI Figures S8-S9.
SpectroscopyNear infrared
2025 · Fibrous Pb(II)-Based Coordination Polymer Operable as a Photocatalyst and Electrocatalyst for High-Rate, Selective CO2-to-Formate Conversion
MW_x KGF-9/KGF-17 comparison powder series · Powder · Diffuse-reflectance spectra for ordinary KGF-9, KGF-17 and MW_x samples.
SpectroscopyUnspecified subtype
2025 · Flexible conductive metal-organic framework Cu3(HHTP)2 film with high thermoelectric performance for low-grade heat harvesting
Optimised Cu3(HHTP)2/Nylon hot-pressed film at 353 K · Thin Film · UV-vis comparison of Cu3(HHTP)2 powder, Cu3(HHTP)2 film and nylon membrane.
SpectroscopyNear infrared
2025 · From 0D to 2D: Microwave-assisted synthesis of electrically conductive metal-organic frameworks with controlled morphologies
0D spherical Cu-HHTP powder · Powder · MOFs dispersed in IPA; spectra measured on CARY 5000 spectrophotometer.
SpectroscopyTauc / Kubelka-Munk
2025 · From Rigid to Flexible: Ce-BTC-MOF-Enabled Self-Powered Photodetectors with Record-High Responsivity and Detectivity
Ce-BTC thin films on glass, thickness series · Thin Film · Visible average transmittance and optical band gap as a function of Ce-BTC film thickness.
Diffraction StructureTauc / Kubelka-Munk
2025 · From Rigid to Flexible: Ce-BTC-MOF-Enabled Self-Powered Photodetectors with Record-High Responsivity and Detectivity
ZnO film used in flexible Ce-BTC/ZnO device · Thin Film · ZnO film deposited on glass; XRD compared to hexagonal wurtzite ZnO and UV-vis Tauc band gap calculated.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2025 · High-resolution structure of Zn3(HOTP)2 (HOTP = hexaoxidotriphenylene), a three-dimensional conductive MOF
As-synthesised Zn3(HOTP)2 black/dark-blue crystalline powder · Powder · UV-Vis spectra plotted as Kubelka-Munk transform; Tauc plot for direct allowed transitions.
PorosityUnspecified subtype
2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks
Ni3(HI12)2 activated powder · Powder · activated MOF powder dispersed in 10 mL MeOH solution containing 0.1 mM dye or 10 mL aqueous 0.2 mM vitamin B12; aliquots diluted 10-fold and analysed by UV-Vis
PorosityUnspecified subtype
2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks
Ni3(HI18)2 activated powder · Powder · activated MOF powder dispersed in 10 mL MeOH solution containing 0.1 mM dye or 10 mL aqueous 0.2 mM vitamin B12; aliquots diluted 10-fold and analysed by UV-Vis
PorosityUnspecified subtype
2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks
Ni3(HITP)2 activated powder · Powder · activated MOF powder dispersed in 10 mL MeOH solution containing 0.1 mM dye or 10 mL aqueous 0.2 mM vitamin B12; aliquots diluted 10-fold and analysed by UV-Vis
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks
Ni3(HI12)2 film on fused silica · Thin Film · MOF films on fused-silica substrates; broad profiles extending to 2000 nm or beyond
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks
Ni3(HI18)2 film on fused silica · Thin Film · MOF films on fused-silica substrates; broad profiles extending to 2000 nm or beyond
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks
Ni3(HITP)2 film on fused silica · Thin Film · MOF films on fused-silica substrates; broad profiles extending to 2000 nm or beyond
SpectroscopyDiffuse reflectance
2025 · Highly sensitive electrochemiluminescence glucose sensor under alkaline conditions based on glucose oxidase@conductive metal-organic framework nanocapsules
GOx@Zn-HHTP nanocapsule powder · Powder · Diffuse reflectance/absorption used to explain excess catalyst absorbing luminol emission.
Electrical TransportDiffuse reflectanceTauc / Kubelka-Munk
2025 · Interconnected Lamellar 3D Semiconductive PCP for Rechargeable Aqueous Zinc Battery Cathodes
As-prepared VO-HHTP black powder · Powder · Optical bandgap used as semiconductor evidence.
SpectroscopyUnspecified subtype
2025 · Mechanistic Insight into the Formation and Deposition of Conductive, Layered Metal-Organic Framework Nanocrystals
reduced HHTP powder · Powder · 2 mM HHTP in 2:1 H2O:DMF; fresh, aged, commercial compared
SpectroscopyUnspecified subtype
2025 · Mechanistic Insight into the Formation and Deposition of Conductive, Layered Metal-Organic Framework Nanocrystals
Ni-HHTP solution complex · Model · HHTP solution, Ni(OAc)2 solution, and combined Ni/HHTP solutions
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2025 · Metal-halide porous framework superlattices
S-MBA/PbI2@PCN-606 amine-modified crystals · Single Crystal · solid-state UV-vis; Kubelka-Munk direct bandgap linear fit
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Mixed Ionic and Electronic Conductivity in a Tetrathiafulvalene-Phosphonate Metal-Organic Framework
TTFTP-La MOF bulk dark crystals · Powder · Direct optical band gap obtained from linear fit to absorption onset.
SpectroscopyDiffuse reflectance
2025 · Modulating the redox states in a 3D conductive MOF for sweat ascorbic acid monitoring
I2@FeTHQ, 20 C 6 h · Powder · Diffuse reflectance spectra using BaSO4 reference
Electrochemistry ApplicationUnspecified subtype
2025 · Multifunctional covalent organic framework with extended π-d conjugated structure for lithium-sulfur batteries
as-synthesised Ni-COF powder/precipitate · Powder · 10 mM Li2S6 in DME prepared from Li2S:S = 1:5; 100 mg Ni-COF added to 10 mL solution
SpectroscopyUnspecified subtype
2025 · Multilevel Chiral Semiconductor Metal-Peptide Framework Thin Film for Highly Circularly Polarized Visible Photodetection
Highly oriented CAS-4 thin film grown for 20 LPE-LBL cycles · Thin Film · CAS-4 thin film on quartz substrate; bare quartz used as baseline; growth monitored by UV-vis absorption.
SpectroscopyTauc / Kubelka-Munk
2025 · Nano UiO-66 and UiO-66-NH2 MOFs as Bifunctional Electrocatalysts for Water-Splitting: A Comparative Study
UiO-66 powder, labelled U · Powder · Absorbance recorded across 200-800 nm; indirect band gap from (alpha hv)^1/2 Tauc plot.
SpectroscopyTauc / Kubelka-Munk
2025 · Nano UiO-66 and UiO-66-NH2 MOFs as Bifunctional Electrocatalysts for Water-Splitting: A Comparative Study
UiO-66-NH2 powder, labelled U-N · Powder · Absorbance recorded across 200-800 nm; indirect band gap from (alpha hv)^1/2 Tauc plot.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Nanoporous synthetic metal: A nickel MOF with an amino-functionalized macrocyclic ligand
Cu-HATC powders · Powder · Solid-state UV-vis-NIR absorbance and derived Tauc plot
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Nanoporous synthetic metal: A nickel MOF with an amino-functionalized macrocyclic ligand
Cu-HHTC powders · Powder · Solid-state UV-vis-NIR absorbance and derived Tauc plot
SpectroscopyNear infrared
2025 · Nanoporous synthetic metal: A nickel MOF with an amino-functionalized macrocyclic ligand
Ni-HATC thin film on glass · Thin Film · MOF thin film measured on CARY 5000; spectral trend compared with Cu-HATC and Cu-HHTC
SpectroscopyTauc / Kubelka-Munk
2025 · Photoactivated conductive MOF thin film arrays on micro-LEDs for chemiresistive gas sensing
CuHHTP-5C · Thin Film · cMOF films deposited on 1 x 1 cm2 transparent quartz substrates for absorbance measurement.
SpectroscopyTauc / Kubelka-Munk
2025 · Proton-electron coupling and mixed conductivity in a hydrogen-bonded coordination polymer
Ni-BAND thin film · Thin Film · Electronic characterisation to evaluate n-type doping and shallow-donor behaviour.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Selenium-Substitution Strategy for Enhanced Mobility, Tunable Bandgap, and Improved Electrochemical Energy Storage in Semiconducting Conjugated Coordination Polymers
Ag4TSHQ powder · Powder · Lambda 1050+ with integrating sphere.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Selenium-Substitution Strategy for Enhanced Mobility, Tunable Bandgap, and Improved Electrochemical Energy Storage in Semiconducting Conjugated Coordination Polymers
Ag4TXHQ-1:1 powder · Powder · Optical band gaps read from Figure S8 labels and Figure 4c.
SpectroscopyUnspecified subtype
2025 · Semiconducting Manganese-Bipyridyl Coordination Polymer via a Manganese-Metal-Nanoparticle Approach
Black-red shiny metallic crystals of 1 · Single Crystal · UV-vis spectrum measured from 220-850 nm using an integrating sphere against BaSO4; 0.5 mg of 1 was mortared with 50 mg BaSO4 and held air-tight under inert conditions.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2025 · Semiconductive Coordination Polymer with Multi-Channel Charge Transfer for High-Performance Direct X-ray Detection
as-synthesised orange plate single crystals of 1 · Single Crystal · Room-temperature diffuse reflectance using BaSO4 reference on PerkinElmer Lambda 950 with integrating sphere.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2025 · Solvent-Directed Assembly of π-Stacked 3D Metal-Organic Frameworks with Tunable Conductivity Enhanced by C60 Encapsulation
NU-4003 · Single Crystal · Kubelka-Munk-transformed diffuse reflectance spectra for NU-4003 and C60-loaded variants
SpectroscopyDiffuse reflectance
2025 · Structural Control of Photoconductivity in a Flexible Titanium-Organic Framework
MUV-35-c closed phase · Single Crystal
SpectroscopyUnspecified subtype
2025 · Structure-directing effect of terephthalate in bridging Zn(ii)- and Cd(ii)-based coordination polymers towards application in the detection of trace quantities of Pd2+ in aqueous media and their electrical conductivities
CP1 as-synthesised block-shaped yellow crystals · Single Crystal · DMF suspension; excitation at 285 nm for CP1; emission and absorption spectra used for sensing and band assignments.
SpectroscopyUnspecified subtype
2025 · Structure-directing effect of terephthalate in bridging Zn(ii)- and Cd(ii)-based coordination polymers towards application in the detection of trace quantities of Pd2+ in aqueous media and their electrical conductivities
CP2 as-synthesised yellow needle-like crystals · Single Crystal · DMF suspension; excitation at 278 nm for CP2; emission and absorption spectra used for sensing and band assignments.
SpectroscopyUnspecified subtype
2025 · Tuning the dxy Orbital Energy Level in 2D Cobalt-Organic-Framework via in-Plane Conjugated Phthalocyanine for Self-Powered Sensing
2D MOF@Pc nanosheets · Nanosheet · Chemical/electronic structure comparison between 2D MOF and 2D MOF@Pc.
OtherUnspecified subtype
2025 · Tuning the Electrical Conductivity of Bimetallic Co–Mn-Based MOFs via Precisely Regulating the Atomic Content of Metal Centers and Study on Their Dye Adsorption Properties
As-synthesised MOF1-MOF9 bulk series · Powder · Rhodamine B and methylene blue tested as positively charged dyes; no spectral change observed.
OtherUnspecified subtype
2025 · Tuning the Electrical Conductivity of Bimetallic Co–Mn-Based MOFs via Precisely Regulating the Atomic Content of Metal Centers and Study on Their Dye Adsorption Properties
As-synthesised MOF1-MOF9 bulk series · Powder · Methyl orange adsorption under same parameters as MeB adsorption; sample attribution reported at series level.
OtherUnspecified subtype
2025 · Tuning the Electrical Conductivity of Bimetallic Co–Mn-Based MOFs via Precisely Regulating the Atomic Content of Metal Centers and Study on Their Dye Adsorption Properties
As-synthesised MOF1 · Powder · 20 mg MOF in 30 mL of 15 ppm methanolic methyl blue solution; absorbance followed for 1 h.
OtherUnspecified subtype
2025 · Tuning the Electrical Conductivity of Bimetallic Co–Mn-Based MOFs via Precisely Regulating the Atomic Content of Metal Centers and Study on Their Dye Adsorption Properties
As-synthesised MOF3 · Powder · 20 mg MOF in 30 mL of 15 ppm methanolic methyl blue solution; absorbance followed for 1 h.
OtherUnspecified subtype
2025 · Tuning the Electrical Conductivity of Bimetallic Co–Mn-Based MOFs via Precisely Regulating the Atomic Content of Metal Centers and Study on Their Dye Adsorption Properties
As-synthesised MOF8 · Powder · 20 mg MOF in 30 mL of 15 ppm methanolic methyl blue solution; absorbance followed for 1 h.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc-O-Cu black powder · Powder · MOF in H2O drop-cast on quartz slide; 200-1600 nm spectra; Tauc plot used for optical band gap.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc-O-Ni black powder · Powder · MOF in H2O drop-cast on quartz slide; 200-1600 nm spectra; Tauc plot used for optical band gap.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc-O-Zn black powder · Powder · MOF in H2O drop-cast on quartz slide; 200-1600 nm spectra; Tauc plot used for optical band gap.
SpectroscopyTauc / Kubelka-MunkNear infrared
2025 · Two dimensional Conjugated Metal–Organic Frameworks with Multiple Redox-Active Sites towards High-Performance Sodium-Ion Battery
Cu-TTPQ black powder · Powder · Experimental LUMO, HOMO and band gap of Cu-TBPQ, Cu-DDQP and Cu-TTPQ from UV-vis absorption and VB-XPS.
SpectroscopyNear infrared
2025 · Two dimensional Conjugated Metal–Organic Frameworks with Multiple Redox-Active Sites towards High-Performance Sodium-Ion Battery
Cu-TTPQ black powder · Powder · FT-IR in ATR mode 400-4000 cm-1; UV-vis-NIR spectra measured for c-MOFs.
SpectroscopyTauc / Kubelka-Munk
2025 · Uninterrupted π-d Conjugated Three-Dimensional Conductive Metal-Organic Framework
As-synthesised Ni3HBC greenish-black nanocrystalline powder · Powder · Shimadzu UV-3600, 400-2600 nm; Ni3HBC blended with BaSO4 and pelletized; BaSO4 background subtraction; UVProbe conversion.
SpectroscopyUnspecified subtype
2025 · Unveiling high-mobility hot carriers in a two-dimensional conjugated coordination polymer
Cu3BHT film transferred onto highly doped conductive silicon · Thin Film · UV-Vis Cary 5000 and FT-IR Tensor II ATR; UPS with He I 21.11 eV source and negative 9 V substrate bias.
SpectroscopyUnspecified subtype
2025 · Volatolomics in Fritillarias and Their Identification by Orientation Controlled cMOF Thin Film Chemiresistors
Cu-HHTP[001]-10C/20C/30C/40C film series · Thin Film · Cu-HHTP[001] films grown on quartz glass with 10-40 growth cycles.
SpectroscopyUnspecified subtype
2025 · Volatolomics in Fritillarias and Their Identification by Orientation Controlled cMOF Thin Film Chemiresistors
Cu-HHTP[100]-10C/20C/30C/40C film series · Thin Film · Cu-HHTP[100] films grown on quartz glass with 10-40 growth cycles.
Electrochemistry ApplicationUnspecified subtype
2024 · 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation
NFZ blank without catalyst · Unknown · Same NFZ photolysis conditions as CP tests but without CP catalyst.
Electrochemistry ApplicationUnspecified subtype
2024 · 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation
CP 1 yellow block crystals · Single Crystal · 10 mg finely ground CP, 50 mL 25 mg/L NFZ aqueous solution, 30 min dark adsorption, 400 W Hg lamp with mean wavelength 365 nm, aliquots every interval, 30 min irradiation.
Electrochemistry ApplicationUnspecified subtype
2024 · 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation
CP 2 purple block crystals · Single Crystal · 10 mg finely ground CP, 50 mL 25 mg/L NFZ aqueous solution, 30 min dark adsorption, 400 W Hg lamp with mean wavelength 365 nm, aliquots every interval, 30 min irradiation.
Electrochemistry ApplicationUnspecified subtype
2024 · 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation
CP 3 pink block crystals · Single Crystal · 10 mg finely ground CP, 50 mL 25 mg/L NFZ aqueous solution, 30 min dark adsorption, 400 W Hg lamp with mean wavelength 365 nm, aliquots every interval, 30 min irradiation.
Electrochemistry ApplicationUnspecified subtype
2024 · 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation
CP 4 green block crystals · Single Crystal · 10 mg finely ground CP, 50 mL 25 mg/L NFZ aqueous solution, 30 min dark adsorption, 400 W Hg lamp with mean wavelength 365 nm, aliquots every interval, 30 min irradiation.
SpectroscopyTauc / Kubelka-Munk
2024 · 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation
CP 1 yellow block crystals · Single Crystal · Shimadzu UV-1800; optical absorption and band gap for pristine CP 1.
SpectroscopyTauc / Kubelka-Munk
2024 · 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation
CP 2 purple block crystals · Single Crystal · Shimadzu UV-1800; optical absorption and band gap for pristine CP 2.
SpectroscopyTauc / Kubelka-Munk
2024 · 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation
CP 3 pink block crystals · Single Crystal · Shimadzu UV-1800; optical absorption and band gap for pristine CP 3.
SpectroscopyTauc / Kubelka-Munk
2024 · 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation
CP 4 green block crystals · Single Crystal · Shimadzu UV-1800; optical absorption and band gap for pristine CP 4.
SpectroscopyUnspecified subtype
2024 · A highly sensitive AgNPs/Ni3(HHTP)2 SERS substrate for the detection of food additives and pesticide residues
PVP-modified monolayer AgNP film · Thin Film · UV-3600 Plus220; AgNPs in ethanol solution.
SpectroscopyUnspecified subtype
2024 · A highly sensitive AgNPs/Ni3(HHTP)2 SERS substrate for the detection of food additives and pesticide residues
Ni3(HHTP)2 mixed with crystal violet in ethanol · Unknown · UV-vis spectra of Ni3(HHTP)2 ethanol solution, CV ethanol solution, and mixed Ni3(HHTP)2/CV solution; Ni3(HHTP)2 1 mg ml^-1 and CV 10^-6 M.
SpectroscopyTauc / Kubelka-Munk
2024 · Acid-Dependent Charge Transport in a Solution-Processed 2D Conductive Metal-Organic Framework
Cu3(HHTATP)2 nanorod powder · Powder · 400-2600 nm on Shimadzu UV-3600; reflectance converted to Kubelka-Munk absorbance.
SpectroscopyUnspecified subtype
2024 · Aggregation-induced enhancement of pyrene-based metal-organic framework as a new electrochemiluminescence emitter for ultrasensitive detection of sulfadimethoxine
ZPM yellow precipitate powder · Powder · UV-vis and FT-IR compared ZPM with H4TBAPy; FL emission used lambda_ex = 360 nm; ECL emission measured for ZPM.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2024 · Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal-Organic Framework
Ni3(THT)2 black powder · Powder · UV-vis-NIR powder in Praying Mantis air-free diffuse reflectance cell using KBr; FT-IR KBr pellets in transmission mode with MCT detector at 77 K
SpectroscopyUnspecified subtype
2024 · An Enzyme-Encapsulated Metal-Organic Frameworks Nanomesh Biosensor for Salivary Glucose Detection
GOx electrode / GOx in solution · Electrode · GOx control measured with TMB chromogenic curves at glucose concentrations of 0.5, 1, 4 and 8 mM; kinetic fits shown in Figure S2c,d.
SpectroscopyUnspecified subtype
2024 · An Enzyme-Encapsulated Metal-Organic Frameworks Nanomesh Biosensor for Salivary Glucose Detection
CNT/GOx@ZIF-8 nanomesh · Powder · PBS containing glucose at 0.25, 0.5, 1 and 2 mM with TMB 0.5 mM, HRP 2 ug mL-1 and CNT/GOx@ZIF-8 100 ug mL-1.
SpectroscopyUnspecified subtype
2024 · An Enzyme-Encapsulated Metal-Organic Frameworks Nanomesh Biosensor for Salivary Glucose Detection
CNT/GOx@ZIF-8 nanomesh · Powder · Mixture containing 200 ug mL-1 CNT/GOx@ZIF-8, 0.5 mM TMB, 2 ug mL-1 HRP and 0.5 mM glucose; spectra recorded from 300 to 750 nm after colour change.
SpectroscopyTauc / Kubelka-Munk
2024 · Bimetallic synergy significantly enhances the photocatalytic performance of lanthanide porphyrin-based MOFs: Efficient photocatalytic oxidation of benzyl alcohol and benzylamine under mild conditions in air
All reported TCPP/PMOF samples · Unknown · Agilent UV-2450 UV-vis spectrophotometer with BaSO4 reference, 200-800 nm; band gaps from (alpha hv)^2 = B(hv - Eg).
SpectroscopyTauc / Kubelka-Munk
2024 · Chromone-Based Cd(II) Fluorescent Coordination Polymer Fabricated to Study Optoelectronic and Explosive Sensing Properties
Complex 1 light-yellow X-ray-quality crystals · Single Crystal · Absorption range 270-500 nm; direct optical band gap calculated with n = 1/2.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Conductive Metal-Organic Framework with Superior Redox Activity as a Stable High-Capacity Anode for High-Temperature K-Ion Batteries
bulk HAN-Cu-MOF powder · Powder · Optical band gap extracted from UV-vis-NIR spectrum
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Control of the Hydroquinone/Benzoquinone Redox State in High-Mobility Semiconducting Conjugated Coordination Polymers
as-synthesised Ag4TTBQ black solid/nanocrystalline film product · Powder · Room-temperature UV-vis-NIR spectra collected with a UV-2000 Shimadzu spectrophotometer.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Control of the Hydroquinone/Benzoquinone Redox State in High-Mobility Semiconducting Conjugated Coordination Polymers
as-synthesised Ag4TTHQ dark red/dark brown powder · Powder · Room-temperature UV-vis-NIR spectra collected with a UV-2000 Shimadzu spectrophotometer.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · De Novo Design and Facile Synthesis of Highly Crystalline 2D Conductive Metal-Organic Frameworks: A “Rotor-Stator” Strategy
Cu-DCB-MOF black powder · Powder · PerkinElmer Lambda 750, 250-2000 nm sweep range.
SpectroscopyIn situ / operando
2024 · Diffusional Electron Transport Coupled to Thermodynamically Driven Electron Transfers in Redox-Conductive Multivariate Metal-Organic Frameworks
Zn(NDI)0.5(PMDI)0.5 thin film on FTO · Thin Film · Slow cathodic CV scan at 10 mV s-1 while collecting UV-vis spectra; five redox states identified.
SpectroscopyDiffuse reflectance
2024 · Electrochemical Capacitance Traces with Interlayer Spacing in Two-dimensional Conductive Metal–Organic Frameworks
exfoliated Bu-MOF ethanol colloid · Nanosheet · Exfoliated Bu-MOF in ethanol compared with diffuse reflectance of bulk Bu-MOF; sonication progress compared after 0.5 h and 5 h.
SpectroscopyDiffuse reflectance
2024 · Electrochemical Capacitance Traces with Interlayer Spacing in Two-dimensional Conductive Metal–Organic Frameworks
exfoliated Pent-MOF ethanol colloid · Nanosheet · Exfoliated Pent-MOF in ethanol compared with diffuse reflectance of bulk Pent-MOF.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Electrosynthesis of a Nickel-Based Conductive Metal-Organic Framework with Controlled Morphology for Enhanced Capacitance
Ni-HHTP comparative sample set · Unknown · Solution-state UV-vis-NIR spectra with analytes dispersed in isopropyl alcohol; Tauc plots for band gaps.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2024 · Embedding Pt in Ni-MOF/CdS organic-inorganic hybrid materials as electron channel to promote photogenerated carrier separation for enhanced photocatalytic hydrogen evolution under visible light
0.3 NPC · Powder · Band gap and absorption response of 0.3 NPC.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2024 · Embedding Pt in Ni-MOF/CdS organic-inorganic hybrid materials as electron channel to promote photogenerated carrier separation for enhanced photocatalytic hydrogen evolution under visible light
CdS · Powder · Band gap calculated using direct-bandgap Tauc plot.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2024 · Embedding Pt in Ni-MOF/CdS organic-inorganic hybrid materials as electron channel to promote photogenerated carrier separation for enhanced photocatalytic hydrogen evolution under visible light
Ni-MOF · Powder · Band gap calculated using direct-bandgap Tauc plot.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Enhancing Near-Infrared Photothermal Performance by Molecular Aggregation Optimization in Semiconductive Coordination Polymers
compound 1 pure bulk product from CdCl2 variant · Powder · Crystalline powder used without BaSO4 dilution.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Enhancing Near-Infrared Photothermal Performance by Molecular Aggregation Optimization in Semiconductive Coordination Polymers
compound 2 pure microcrystalline product · Powder · Crystalline powder used without BaSO4 dilution.
SpectroscopyNear infrared
2024 · Fabrication of nonlinear optical metal-organic framework dizinc tetraglycinate dihydrate with optical limiting applications
DZTGD single crystal · Single Crystal · Transmittance, optical cut-off, Tauc band gap, refractive index and conductivity-derived optical parameters
SpectroscopyDiffuse reflectance
2024 · From insulator to semiconductor: effect of host-guest interactions on charge transport in M-MOF-74 metal-organic frameworks
TCNQ@Mn-MOF-74 film for DRS · Thin Film · DRS obtained with ASD Quality Spec Pro UV-Vis spectrometer with fibre optic mug light attachment; spectra scanned 350-2500 nm; Mn-MOF-74 films printed onto FTO-coated glass.
SpectroscopyUnspecified subtype
2024 · From insulator to semiconductor: effect of host-guest interactions on charge transport in M-MOF-74 metal-organic frameworks
TCNQ@Cu-MOF-74 pellet · Pellet · UV-Vis spectra collected on Shimadzu UV-3600 UV-VIS-NIR spectrophotometer; main text uses spectra to evaluate intermolecular charge transfer and band gap.
Electrochemistry ApplicationUnspecified subtype
2024 · Laccase-inspired bi-amino acid MOFs with high substrate affinity: Catalytic deposition induced “signal-down” electrochemical response towards PD-L1
Cu-F/Hs powder/nanoparticles · Powder · DA substrate oxidation/polymerisation kinetics of Cu-F/Hs without ODA.
Electrochemistry ApplicationUnspecified subtype
2024 · Laccase-inspired bi-amino acid MOFs with high substrate affinity: Catalytic deposition induced “signal-down” electrochemical response towards PD-L1
Cu-F/Hs with ODA in DA polymerisation mixture · Unknown · DA substrate oxidation/polymerisation kinetics of Cu-F/Hs in the presence of ODA.
Electrochemistry ApplicationUnspecified subtype
2024 · Laccase-inspired bi-amino acid MOFs with high substrate affinity: Catalytic deposition induced “signal-down” electrochemical response towards PD-L1
Cu-Fs powder/nanoparticles · Powder · DA substrate oxidation/polymerisation kinetics without ODA, fitted to V = Vmax[S]/(Km+[S]).
SpectroscopyUnspecified subtype
2024 · Laccase-inspired bi-amino acid MOFs with high substrate affinity: Catalytic deposition induced “signal-down” electrochemical response towards PD-L1
Cu-F/Hs powder/nanoparticles · Powder · Absorbance of TMB oxidation monitored at/near 652 nm for Cu-Fs, Cu-F/Hs, and TMB controls.
SpectroscopyUnspecified subtype
2024 · Laccase-inspired bi-amino acid MOFs with high substrate affinity: Catalytic deposition induced “signal-down” electrochemical response towards PD-L1
Cu-Hs reference · Unknown · Cu-Hs reference with TMB measured by UV-vis in the SI.
SpectroscopyUnspecified subtype
2024 · Laccase-inspired bi-amino acid MOFs with high substrate affinity: Catalytic deposition induced “signal-down” electrochemical response towards PD-L1
Cu-F/Hs powder/nanoparticles · Powder · Cu-F/Hs and raw materials compared by UV-vis spectra.
SpectroscopyTauc / Kubelka-Munk
2024 · Large-Area Metal–Organic Framework Glasses for Efficient X-Ray Detection
ZnPIm MOF glass film · Thin Film · Perkin-Elmer Lambda 950 UV-Vis-NIR spectrophotometer, 250 to 800 nm; Tauc plot from transmission curve.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2024 · Layered coordination polymer with two-dimensional covalent bismuth-organic networks: Semiconductor and lithium ion storage
as-made Bi-DSBDC-DMA yellow crystalline solid · Powder · Lambda 950 UV-Vis-NIR spectrophotometer with integrating sphere; reflectance transformed to absorption using Kubelka-Munk equation.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Macrocyclic ligand-driven ion selectivity and high surface area in a 2D conductive MOF
pristine Cu-EP powder · Powder · Solid-phase spectrum of Cu-EP compared with EP ligand
SpectroscopyNear infrared
2024 · Macrocyclic ligand-driven ion selectivity and high surface area in a 2D conductive MOF
EP ligand model · Model · EP ligand in MeOH/water (20:1 v/v), diluted 10 times; 1 equivalent LiNO3 or CsNO3 added
SpectroscopyDiffuse reflectanceNear infrared
2024 · Manipulating Photoconduction in Cu-Pyrene 1-D Coordination Nanosheets by Modulating Interlayer π-π Stacking
Cu-PTT nanosheet powder · Nanosheet · Diffuse reflectance spectra of nanosheet powder.
SpectroscopyDiffuse reflectanceNear infrared
2024 · Manipulating Photoconduction in Cu-Pyrene 1-D Coordination Nanosheets by Modulating Interlayer π-π Stacking
Cu-tBuPTT nanosheet powder · Nanosheet · Diffuse reflectance spectra of nanosheet powder.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2024 · Metal-organic frameworks with fine-tuned interlayer spacing for microwave absorption
Zn3Cu1-HHTP powder/rod crystals · Powder · DR UV-vis Shimadzu UV-3600; optical bandgaps estimated from Tauc coordinates.
Diffraction StructureUnspecified subtype
2024 · MOF-enabled high-density 2D molecular crystal optoelectronic memory transistor with floating gate architecture
Pristine DTT-8 two-dimensional molecular crystal film · Single Crystal · Crystal orientation and optical absorption of DTT-8 2DMC.
SpectroscopyUnspecified subtype
2024 · MOF-enabled high-density 2D molecular crystal optoelectronic memory transistor with floating gate architecture
Pristine 2D Cu3(HHTP)2 MOF thin film · Thin Film · Energy levels calculated from UPS spectrum and optical band gap for 12 nm-thick Cu3(HHTP)2 film.
SpectroscopyNear infrared
2024 · Naphthalene Diimide-Based Hydrogen-Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applications
Device B hydrazine-doped NDI(CPOH)2-SC, normal treatment · Single Crystal · comparison of pristine and hydrazine-doped NDI(CPOH)2-SCs; TEMPO used as ESR reference
SpectroscopyDiffuse reflectance
2024 · NiCo-MOFs in situ anchored on graphdiyne with metal-like properties form a strongly coupled electron transport interface and construct an ohmic contact to achieve efficient charge-hole spatial separation
Cu-GDY (CG) · Powder · BaSO4 reference background; indirect band gap from transformed UV-vis data
SpectroscopyDiffuse reflectance
2024 · NiCo-MOFs in situ anchored on graphdiyne with metal-like properties form a strongly coupled electron transport interface and construct an ohmic contact to achieve efficient charge-hole spatial separation
pure NiCo-MOF (NC) · Powder · BaSO4 reference background; indirect band gap from transformed UV-vis data
SpectroscopyUnspecified subtype
2024 · Novel 2D CuFe-MOF-based immunoprobe: Addressing antifouling electrochemical immunosensing inadequate sensitivity challenge
CuFe-MOF feed-ratio series · Nanosheet · Compared peroxidase-like activity of CuFe-MOF materials with different Cu:Fe feed ratios from Cu-BDC to 1:2.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Photocatalytic Hydrogen Peroxide Production through Functionalized Semiconductive Metal-Organic Frameworks
EFB-MOF powder · Powder · MOF nanoparticles dispersed in isopropanol; band gaps calculated from Tauc plot.
SpectroscopyUnspecified subtype
2024 · Reaction-Type-Dependent Behavior of Redox-Hopping in MOFs─Does Charge Transport Have a Preferred Direction?
[RuII(bpy)2(bpy-COOH)](PF6)2 homogeneous solution · Model · UV-vis spectra of [RuII(bpy)2(bpy-COOH)](PF6)2 at 1.0e-5 to 3.0e-5 M concentrations.
SpectroscopyNear infrared
2024 · Solid-State Electrochemical Carbon Dioxide Capture by Conductive Metal-Organic Framework Incorporating Nickel Bis(diimine) Units
Ni(DIB)2 solution electrochemical control · Unknown · 20 microL aliquots diluted to 3 mL DMF; reduction sampled every 20 min; CO2 exposure sampled every 15 min.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2024 · Superior Charge Transport in Ni-Diamine Conductive MOFs
Air-exposed Cu3(HITT)2 · Unknown · Diffuse reflectance UV-vis-NIR spectra for air-exposed Cu3(HITT)2 over 45 days; optical gaps extracted from Tauc plots.
SpectroscopyDiffuse reflectanceNear infrared
2024 · Superior Charge Transport in Ni-Diamine Conductive MOFs
Pristine Cu3(HITT)2 black powder · Powder · Optical spectra collected under N2 atmosphere.
SpectroscopyDiffuse reflectanceNear infrared
2024 · Superior Charge Transport in Ni-Diamine Conductive MOFs
Pristine Ni3(HITT)2 black powder · Powder · Optical spectra collected under N2 atmosphere.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Three-type precursors for low-temperature solution-processed void-and-crack-free copper(I) iodide films: comparison of electrical conductivities and optical transparency
CuI(1A2P) film on glass · Thin Film · Prepared CuI thin film; PYS measured using Riken Keiki AC-3.
SpectroscopyNear infrared
2024 · Three-type precursors for low-temperature solution-processed void-and-crack-free copper(I) iodide films: comparison of electrical conductivities and optical transparency
CuI(1A2P) film on glass · Thin Film · CuI films on glass; average transmittance and absorption feature at 410 nm discussed.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Triazacoronene-Based 2D Conductive Metal–Organic Framework for High-Capacity Lithium Storage
as-synthesised Cu-TAC powder · Powder · Room-temperature UV-vis-NIR spectrum used to estimate optical band gap.
PorosityUnspecified subtype
2024 · Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP
Co-HHTP powder · Powder · Co-HHTP immersed in cationic MB+ and anionic MO- dye solutions for 0.5 h; same-concentration MB comparison with Ni-HHTP and HHTP is partly SI-only.
PorosityUnspecified subtype
2024 · Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP
Co-HHTP powder · Powder · 3 mg powder in 4 mL of 0.1 mmol L^-1 methylene blue or methyl orange aqueous solution; stirred at room temperature for up to 24 h.
SpectroscopyUnspecified subtype
2024 · Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP
luminol@Co-HHTP powder · Powder · UV-vis patterns for luminol, luminol@Co-HHTP, Co-HHTP, luminol@Ni-HHTP and Ni-HHTP.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Tunable Charge Transport and Spin Dynamics in Two-Dimensional Conjugated Metal-Organic Frameworks
Ni3(HATI_H)2 black powder · Powder · Room-temperature UV/vis/NIR absorption; optical gaps estimated from Tauc plots.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance
Co-DHHBTN thin film on fused silica/quartz · Thin Film · 200-2500 nm spectra, Shimadzu SolidSpec-3700DUV, step size 0.5 nm, ambient conditions.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance
Cu-DHHBTN thin film on fused silica/quartz · Thin Film · 200-2500 nm spectra, Shimadzu SolidSpec-3700DUV, step size 0.5 nm, ambient conditions.
SpectroscopyTauc / Kubelka-MunkNear infrared
2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance
Ni-DHHBTN thin film on fused silica/quartz · Thin Film · 200-2500 nm spectra, Shimadzu SolidSpec-3700DUV, step size 0.5 nm, ambient conditions.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2024 · Unleashing the room temperature boronization: Blooming of Ni-ZIF nanobuds for efficient photo/electro catalysis of water
24-BNZ powder / 24 h boronized Ni-ZIF · Powder · NZ and 24-BNZ optical absorption and band-gap comparison; SI Fig. S14.
SpectroscopyUnspecified subtype
2024 · Upgrading Structural Conjugation in Three-Dimensional Ni-Based Metal-Organic Frameworks for Promoting Electrical Conductivity and Specific Capacitance
as-synthesised Ni-BPE crystals · Single Crystal · PERKINELMER LAMBDA750
SpectroscopyUnspecified subtype
2024 · Upgrading Structural Conjugation in Three-Dimensional Ni-Based Metal-Organic Frameworks for Promoting Electrical Conductivity and Specific Capacitance
as-synthesised Ni-BPY crystals · Single Crystal · PERKINELMER LAMBDA750
SpectroscopyNear infrared
2023 · 2D conjugated metal-organic framework as a proton-electron dual conductor
As-synthesised Zn-HHTP-H2O powder · Powder · Electronic absorption and Tauc plot; FTIR/TGA for coordinated water; XPS for Zn oxidation state, Na content and C 1s species.
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · 2D metal-organic frameworks for ultraflexible electrochemical transistors with high transconductance and fast response speeds
Pristine Cu3(HHTP)2 thin film · Thin Film · Water droplet contact angle; optical bandgap from Cu3(HHTP)2 film on glass.
OtherDiffuse reflectanceNear infrared
2023 · A chiral SrSi2 (srs) superstructure constructed by a dual interaction system showing isotropic electrical conductivity
Regenerated compound 1 crystals · Single Crystal · Main text states regenerated-sample results are almost the same as those of original compound 1.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2023 · A chiral SrSi2 (srs) superstructure constructed by a dual interaction system showing isotropic electrical conductivity
Regenerated compound 1 crystals · Single Crystal · SI Fig. S8 reports the regenerated-sample diffuse-reflectance spectrum; the rendered inset Tauc plot is labelled Eg = 2.29 eV.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2023 · A chiral SrSi2 (srs) superstructure constructed by a dual interaction system showing isotropic electrical conductivity
Powdered crystalline compound 1 · Powder · Cary 5000 spectrophotometer at room temperature, 200-2500 nm, integrating sphere; reflection converted to absorbance by Kubelka-Munk method.
SpectroscopyUnspecified subtype
2023 · A Humidity-Induced Large Electronic Conductivity Change of 107 on a Metal-Organic Framework for Highly Sensitive Water Detection
H2SO4@(NH2)2-MIL-125 powder · Powder · Absorption spectrum of H2SO4@(NH2)2-MIL-125 compared with (NH2)2-MIL-125
SpectroscopyUnspecified subtype
2023 · A Pyrazine-Based 2D Conductive Metal-Organic Framework for Efficient Lithium Storage†
HCl digestion product of TPQG-Cu-MOF · Powder · HCl digestion product compared with TPQ-8OH and TPQG-8OH.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2023 · A Pyrazine-Based 2D Conductive Metal-Organic Framework for Efficient Lithium Storage†
As-synthesised TPQG-Cu-MOF black powder · Powder · UV-visible spectra measured on PerkinElmer Lambda 750 spectrometer.
SpectroscopyUnspecified subtype
2023 · A simplistic approach for the synthesis of Covalent Organic Frameworks(COFs) comprising of tetrafunctionalized porphyrin and polyoxometalates to uncover catalytic applications
Anderson POM control sample · Unknown · Anderson POM control compared in FT-IR, UV-vis and Tauc/CV-derived energy-level tables.
SpectroscopyUnspecified subtype
2023 · A simplistic approach for the synthesis of Covalent Organic Frameworks(COFs) comprising of tetrafunctionalized porphyrin and polyoxometalates to uncover catalytic applications
P@Cu-AndCOF bulk solid · Powder · 1H NMR in DMSO-d6; FT-IR in KBr; UV-vis in DMF/CH3CN (v/v = 1:1).
SpectroscopyUnspecified subtype
2023 · A simplistic approach for the synthesis of Covalent Organic Frameworks(COFs) comprising of tetrafunctionalized porphyrin and polyoxometalates to uncover catalytic applications
P@Ni-AndCOF bulk solid · Powder · 1H NMR in DMSO-d6; FT-IR in KBr; UV-vis in DMF/CH3CN (v/v = 1:1).
Electrochemistry ApplicationUnspecified subtype
2023 · A simplistic approach for the synthesis of Covalent Organic Frameworks(COFs) comprising of tetrafunctionalized porphyrin and polyoxometalates to uncover catalytic applications
Tris@ZnP solution/control sample · Unknown · CV in DMF/CH3CN (v/v = 1:1) using Ag/AgCl reference and Fc+/Fc internal standard; UV-vis in DMSO.
SpectroscopyUnspecified subtype
2023 · Air/liquid interfacial formation process of conductive metal–organic framework nanosheets
HITP-Ni-NS_1 min · Nanosheet · HITP-Ni-NS samples transferred to quartz substrates at pi = 5 mN m-1 with one deposition cycle; room temperature in air.
SpectroscopyNear infrared
2023 · Chemical Vapor Deposition and High-Resolution Patterning of a Highly Conductive Two-Dimensional Coordination Polymer Film
CVD Cu-BHT nanofilm series · Thin Film · Transmission mode on Lambda 950 UV-Vis spectrophotometer.
SpectroscopyTauc / Kubelka-Munk
2023 · Chemiresistive and chem-FET Sensor: π-d conjugated metal-organic framework for ultra-sensitive and selective carbon monoxide detection
as-synthesised Zn-HHTP blue powder · Powder · Jasco V-750; Zn-HHTP powder dissolved in acetone and deionized water
SpectroscopyUnspecified subtype
2023 · Conductive Lanthanide Metal-Organic Frameworks with Exceptionally High Stability
Gd4-MOF after MnO4- anion exchange · Single Crystal · 21 mL of 50 ppm permanganate solution with 3 mg Gd4-MOF; monitored to 163 h
SpectroscopyDiffuse reflectance
2023 · Conductive Lanthanide Metal-Organic Frameworks with Exceptionally High Stability
as-synthesised Gd4-MOF single crystals · Single Crystal · BaSO4 reflectance standard
SpectroscopyUnspecified subtype
2023 · Conductive metal-organic framework flowers facilitate the anchoring and conversion kinetics of polysulfides for lithium‑sulfur batteries
MIL-47 powder / nanosheets collected from autoclave · Powder · MIL-47 material and CNT exposed to LPS solution; UV-vis spectra and photographs after adsorption.
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction
c-HBC-12O-Cu black powder · Powder · Optical band gaps estimated by Tauc plot from Figure S20.
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction
c-HBC-6O-Cu black powder · Powder · Optical band gaps estimated by Tauc plot from Figure S20.
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction
c-HBC-8O-Cu black powder · Powder · Optical band gaps estimated by Tauc plot from Figure S20.
SpectroscopyTauc / Kubelka-Munk
2023 · Correlation in Structural Architecture toward Fabrication of Schottky Device with a Series of Pyrazine Appended Coordination Polymers
ITO/1/Al Schottky thin-film device · Thin Film · Thin film deposited on ITO from DMSO dispersion; absorption spectra 200-600 nm.
SpectroscopyTauc / Kubelka-Munk
2023 · Correlation in Structural Architecture toward Fabrication of Schottky Device with a Series of Pyrazine Appended Coordination Polymers
ITO/2/Al Schottky thin-film device · Thin Film · Thin film deposited on ITO from DMSO dispersion; absorption spectra 200-600 nm.
SpectroscopyTauc / Kubelka-Munk
2023 · Correlation in Structural Architecture toward Fabrication of Schottky Device with a Series of Pyrazine Appended Coordination Polymers
ITO/3/Al Schottky thin-film device · Thin Film · Thin film deposited on ITO from DMSO dispersion; absorption spectra 200-600 nm.
Electrochemistry ApplicationUnspecified subtype
2023 · Decoupling Redox Hopping and Catalysis in Metal-Organic Frameworks -based Electrocatalytic CO2 Reduction
CoPc@NU-1000-h carbon/Nafion electrode · Electrode · CoPc@NU-1000-h electrode after 2 h to 4 h e-CRR; digestion in 0.1 M NaOH; electrolyte supernatant checks; recycled electrode analyses
SpectroscopyUnspecified subtype
2023 · Decoupling Redox Hopping and Catalysis in Metal-Organic Frameworks -based Electrocatalytic CO2 Reduction
CoPc@NU-1000-h · Powder · ca 2 mg MOF digested in 1 M KOH for 10 min, neutralised with 1 M HCl, diluted in DMF to 5 mL
Sensing ApplicationUnspecified subtype
2023 · Diazo-reaction based dual-mode colorimetric-electrochemical sensing of nitrite in pickled food
Cu-MOFs/EGP · Electrode · Optimised TMB concentration, Cu-MOFs/EGP area, incubation time, pH, temperature and diazotization time using Fig. S1.
Sensing ApplicationUnspecified subtype
2023 · Diazo-reaction based dual-mode colorimetric-electrochemical sensing of nitrite in pickled food
Cu-MOFs/EGP · Electrode · Cu-MOFs/EGP-TMB system with nitrite addition; TMB oxidation followed by diazotization at room temperature for 8 min.
Sensing ApplicationUnspecified subtype
2023 · Diazo-reaction based dual-mode colorimetric-electrochemical sensing of nitrite in pickled food
Cu-MOFs/EGP · Electrode · 0.5 cm x 1.5 cm Cu-MOFs/EGP incubated at 37 deg C in 0.1 M acetate buffer, pH 3.5, with 1.0 mM TMB for 15 min; absorbance at 652 nm recorded.
SpectroscopyUnspecified subtype
2023 · Dimensional Control of Highly Anisotropic and Transparent Conductive Coordination Polymers for Solution-Processable Large-Scale 2D Sheets
Large 2D CuCl-TU nanosheet on surface-treated PC film · Electrode · Transparent nanosheet electrode and absorption spectra of nanosheets/nanowires.
SpectroscopyUnspecified subtype
2023 · Dimensional Control of Highly Anisotropic and Transparent Conductive Coordination Polymers for Solution-Processable Large-Scale 2D Sheets
3D CuCl-TU polymer nanostructure · Powder · Optical transmittance of CuCl-TU 3D structure from Figure S6.
SpectroscopyDiffuse reflectanceNear infrared
2023 · Dominant Role of Hole Transport Pathway in Achieving Record High Photoconductivity in Two-Dimensional Metal–Organic Frameworks
Cu-HHTP dried powder · Powder · Diffuse reflectance spectra of Cu-HHTP, Cu/Zn-HHTP and Zn-HHTP; HHTP ligand solution spectrum in SI.
SpectroscopyTauc / Kubelka-Munk
2023 · Double advantages of 2D coordination polymer of coumarinyl-pyridyl Schiff base decorated Zn(II): The fabrication of Schottky device and Anti-carcinogenic activity
as-synthesised powdered Zn(II)-CP · Powder · Zn(II)-CP dispersion in DMF, 200-700 nm; indirect allowed transition used for band-gap extraction.
OtherTauc / Kubelka-MunkNear infrared
2023 · Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks
Co-CoOAPc powder and cold-pressed pellet · Powder · Table S5 property summary for each pristine MOF
OtherTauc / Kubelka-MunkNear infrared
2023 · Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks
Co-CuOAPc powder and cold-pressed pellet · Powder · Table S5 property summary for each pristine MOF
OtherTauc / Kubelka-MunkNear infrared
2023 · Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks
Co-NiOAPc powder and cold-pressed pellet · Powder · Table S5 property summary for each pristine MOF
OtherTauc / Kubelka-MunkNear infrared
2023 · Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks
Cu-CoOAPc powder and cold-pressed pellet · Powder · Table S5 property summary for each pristine MOF
OtherTauc / Kubelka-MunkNear infrared
2023 · Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks
Cu-CuOAPc powder and cold-pressed pellet · Powder · Table S5 property summary for each pristine MOF
OtherTauc / Kubelka-MunkNear infrared
2023 · Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks
Cu-NiOAPc powder and cold-pressed pellet · Powder · Table S5 property summary for each pristine MOF
OtherTauc / Kubelka-MunkNear infrared
2023 · Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks
Ni-CoOAPc powder and cold-pressed pellet · Powder · Table S5 property summary for each pristine MOF
OtherTauc / Kubelka-MunkNear infrared
2023 · Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks
Ni-CuOAPc powder and cold-pressed pellet · Powder · Table S5 property summary for each pristine MOF
OtherTauc / Kubelka-MunkNear infrared
2023 · Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks
Ni-NiOAPc powder and cold-pressed pellet · Powder · Table S5 property summary for each pristine MOF
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · Electrically conductive [Fe4S4]-based organometallic polymers
[Fe4S4Cl2(Me-NHC)] (1) powder · Powder · DR UV-vis-NIR spectrum under N2; solution-state UV-vis-NIR of (PPh4)2(Fe4S4Cl4) in DMF for comparison.
SpectroscopyUnspecified subtype
2023 · Electrically conductive [Fe4S4]-based organometallic polymers
[Fe4S4Cl2(Me-NHC)] (1) powder · Powder · Perkin Elmer Lambda 1050 UV/Vis/NIR with InGaAs integrating sphere and Harrick DRP/CHC; 2000-200 nm; sample diluted under N2 with dried MgSO4; measured under vacuum from 173 to 373 K.
SpectroscopyDiffuse reflectanceNear infrared
2023 · Electrically Conductive π-Intercalated Graphitic Metal-Organic Framework Containing Alternate π-Donor/Acceptor Stacks
iGMOF1 black powder · Powder · Composition and electronic-structure characterisation of iGMOF1, Cu3(HATP)2, HCTP-treated Cu3(HATP)2, and [HATP/HCTP]n array.
SpectroscopyIn situ / operando
2023 · Electrochromism in Isoreticular Metal-Organic Framework Thin Films with Record High Coloration Efficiency
Zn-NDI@FTO thin film · Thin Film · Diode-array spectrophotometer coupled to Autolab PGSTAT100; quartz cuvette, 1 cm path length; Zn-XDI@FTO working electrode, Pt counter electrode, non-aqueous Ag/Ag+ reference; bare FTO/electrolyte background
SpectroscopyIn situ / operando
2023 · Electrochromism in Isoreticular Metal-Organic Framework Thin Films with Record High Coloration Efficiency
Zn-PDI@FTO thin film · Thin Film · Diode-array spectrophotometer coupled to Autolab PGSTAT100; quartz cuvette, 1 cm path length; Zn-XDI@FTO working electrode, Pt counter electrode, non-aqueous Ag/Ag+ reference; bare FTO/electrolyte background
SpectroscopyIn situ / operando
2023 · Electrochromism in Isoreticular Metal-Organic Framework Thin Films with Record High Coloration Efficiency
Zn-PMDI@FTO thin film · Thin Film · Diode-array spectrophotometer coupled to Autolab PGSTAT100; quartz cuvette, 1 cm path length; Zn-XDI@FTO working electrode, Pt counter electrode, non-aqueous Ag/Ag+ reference; bare FTO/electrolyte background
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2023 · Engineering Band Gap and Photoconduction in Semiconducting Metal Organic Frameworks: Metal Node Effect
M-THQ powder series · Powder · DR spectra recorded with Cary 5000 UV-VIS-NIR spectrophotometer; KM plots fit from absorption band maxima to extract indirect band gaps.
SpectroscopyTauc / Kubelka-Munk
2023 · Enhancing the photo-electrocatalytic properties of g-C3N4 by boron doping and ZIF-8 hybridization
B-g-C3N4 powder · Powder · Absorption spectra 280-700 nm; band gap from Tauc plot.
SpectroscopyTauc / Kubelka-Munk
2023 · Enhancing the photo-electrocatalytic properties of g-C3N4 by boron doping and ZIF-8 hybridization
B-g-C3N4/ZIF-8 powder · Powder · Absorption spectra 280-700 nm; band gap from Tauc plot.
SpectroscopyTauc / Kubelka-Munk
2023 · Enhancing the photo-electrocatalytic properties of g-C3N4 by boron doping and ZIF-8 hybridization
g-C3N4 powder · Powder · Absorption spectra 280-700 nm; band gap from Tauc plot of (alpha h nu)^2 vs energy.
SpectroscopyTauc / Kubelka-Munk
2023 · Enhancing the photo-electrocatalytic properties of g-C3N4 by boron doping and ZIF-8 hybridization
g-C3N4/ZIF-8 powder · Powder · Absorption spectra 280-700 nm; band gap from Tauc plot.
Electrochemistry ApplicationUnspecified subtype
2023 · Enhancing the Photocatalytic Degradation Efficiency of Dyes of Copper-Based Metal-Organic Frameworks through a Dimension-Induced Structural Strategy
Complex 1 powder catalyst used for MB/dye degradation · Powder · 50 mL MB solution, 300 W Xe lamp with 420 nm cut-off; typical 10 mg/L MB, 30 mg catalyst 1, 100 mM H2O2; 25 C; 30 min dark adsorption before irradiation
SpectroscopyTauc / Kubelka-Munk
2023 · Enhancing the Photocatalytic Degradation Efficiency of Dyes of Copper-Based Metal-Organic Frameworks through a Dimension-Induced Structural Strategy
Complex 1 reddish-brown acicular crystals · Single Crystal · UV-vis spectra of 3-DPNDI and complexes 1-3; band gaps estimated by extrapolating linear part of (alpha hv)^2
SpectroscopyTauc / Kubelka-Munk
2023 · Exceptionally high charge mobility in phthalocyanine-based poly(benzimidazobenzophenanthroline)-ladder-type two-dimensional conjugated polymers
2DCP-CuPc thin film on fused silica · Thin Film · Film on fused silica; spectra corrected to determine optical bandgap.
SpectroscopyTauc / Kubelka-Munk
2023 · Exceptionally high charge mobility in phthalocyanine-based poly(benzimidazobenzophenanthroline)-ladder-type two-dimensional conjugated polymers
2DCP-NiPc thin film on fused silica · Thin Film · Film on fused silica; spectra corrected to determine optical bandgap.
SpectroscopyIn situ / operando
2023 · Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching
Zn(pyrazol-NDI) thin film on FTO · Thin Film · Controlled-potential UV-Vis spectra collected in kinetic mode while applying electrochemical potentials in Ar-saturated DMF with 0.1 M KPF6.
SpectroscopyDiffuse reflectance
2023 · Framework Dimensional Control Boosting Charge Storage in Conjugated Coordination Polymers
as-synthesised 1D-CuTABQ powder · Powder · FTIR 400-4000 cm^-1; Al Kalpha XPS; X-band EPR at room temperature; diffuse-reflectance UV-vis
SpectroscopyDiffuse reflectance
2023 · Framework Dimensional Control Boosting Charge Storage in Conjugated Coordination Polymers
as-synthesised 2D-CuTABQ powder · Powder · FTIR 400-4000 cm^-1; Al Kalpha XPS; X-band EPR at room temperature; diffuse-reflectance UV-vis
Electrical TransportTauc / Kubelka-Munk
2023 · In Situ Oxidation of Pyridyl-Dihydrobenzoimidazoquinazoline and the Synthesis of a Highly Luminescent Cd(II) Coordination Polymer: A Promising Candidate for Mutagenic Nitroaromatic Detection and Device Fabrication
Compound 1 suspension in acetonitrile · Unknown · Absorption spectrum from 250 to 500 nm in acetonitrile suspension; direct optical band gap derived using Tauc equation.
SpectroscopyUnspecified subtype
2023 · In Situ Oxidation of Pyridyl-Dihydrobenzoimidazoquinazoline and the Synthesis of a Highly Luminescent Cd(II) Coordination Polymer: A Promising Candidate for Mutagenic Nitroaromatic Detection and Device Fabrication
Compound 1 suspension in acetonitrile · Unknown · Acetonitrile suspension at room temperature; PerkinElmer Lambda 25 UV-vis and LS55 spectrofluorometer used according to SI.
SpectroscopyUnspecified subtype
2023 · Iodine uptake enhanced electrical conductivity by a metal-organic framework bearing nanotube array of π-stacked columns
compound 1 crystals · Single Crystal · I2 aqueous solutions at 0.1, 0.2, 0.4, 0.7, and 1 mM; linear relationship between absorbance at 460 nm and concentration
PorosityUnspecified subtype
2023 · Iodine uptake enhanced electrical conductivity by a metal-organic framework bearing nanotube array of π-stacked columns
compound 1 crystals · Single Crystal · 10.0 mg air-dried compound 1 in 10 mL of 1 mM I2 aqueous solution; Cary 5000 spectrophotometer, 200-800 nm, room temperature
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · Linker-Based Bandgap Tuning in Conductive MOF Solid Solutions
Cu3(TATHB)2 / Cu-TATHB (x = 0) · Pellet · Solution-phase UV-vis-NIR absorption spectra recorded on CARY 5000 with dispersion in isopropyl alcohol; Tauc plots derived from absorption spectra.
SpectroscopyDiffuse reflectance
2023 · Metal-Organic Framework Glass Catalysts from Melting Glass-Forming Cobalt-Based Zeolitic Imidazolate Framework for Boosting Photoelectrochemical Water Oxidation
Co-agZIF-62/NiO/BiVO4 photoanode · Electrode · Optical absorption comparison of BiVO4-based photoanodes
Diffraction StructureUnspecified subtype
2023 · Modular conductive MOF-gated field-effect biosensor for sensitive discrimination on the small molecular scale
HTP-Co sensor: Co3HHTP2 thin film-modified electrode · Electrode · Supplementary structural/spectroscopic confirmation of Co3HHTP2 thin film.
SpectroscopyUnspecified subtype
2023 · Modular conductive MOF-gated field-effect biosensor for sensitive discrimination on the small molecular scale
TCP sensor: Cu2TCPP thin film on SnO2/ITO extended gate, 10 growth cycles · Electrode · Cu2TCPP thin film fabricated by 10 cycles.
SpectroscopyUnspecified subtype
2023 · Modular conductive MOF-gated field-effect biosensor for sensitive discrimination on the small molecular scale
HTP sensor: Cu3HHTP2 thin film on SnO2/ITO extended gate, 10 growth cycles · Electrode · Cu3HHTP2 thin film fabricated by 10 cycles.
SpectroscopyUnspecified subtype
2023 · MOF-Assimilated High-Sensitive Organic Field-Effect Transistors for Rapid Detection of a Chemical Warfare Agent
as-synthesised CPO-27-Ni powder/crystals · Powder · Drop-casted freshly prepared CPO-27-Ni MOF sample measured by UV-visible spectroscopy.
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · Near IR Bandgap Semiconducting 2D Conjugated Metal-Organic Framework with Rhombic Lattice and High Mobility
Cu2(OHPTP) film on quartz glass · Thin Film · Agilent Cary 5000 UV-VIS-NIR with integration sphere; film on quartz slide at room temperature.
SpectroscopyUnspecified subtype
2023 · Orientation Control of a Two-Dimensional Conductive Metal-Organic Framework Thin Film by a Pyridine Vapor-Assisted Dry Process
(001)-oriented Cu3(HHTP)2 thin film annealed with 3 uL pyridine · Thin Film · UV-vis spectrum of 3 uL pyridine-vapour annealed film.
SpectroscopyUnspecified subtype
2023 · Orientation Control of a Two-Dimensional Conductive Metal-Organic Framework Thin Film by a Pyridine Vapor-Assisted Dry Process
as-deposited Cu3(HHTP)2-like thin film on alpha-Al2O3 (001) · Thin Film · UV-vis spectrum of as-deposited film.
SpectroscopyUnspecified subtype
2023 · Oxidatively Doped Tetrathiafulvalene-Based Metal-Organic Frameworks for High Specific Energy of Supercapatteries
1-ox · Single Crystal · Solid-state room-temperature DRS for py-TTF-py, 1, 1-ox, 2 and 2-ox.
SpectroscopyTauc / Kubelka-Munk
2023 · Pyridyl-Isonicotinoyl Hydrazone-Bridged Zn(II) Coordination Framework with Thiophenedicarboxylato Link: Structure, Biological Activity, and Electrical Conductivity
ITO/compound 1/Al metal-semiconductor thin-film device · Thin Film · Solid-state thin film absorbance of compound 1 deposited on quartz plate and dried in vacuum chamber; optical direct band gap calculated using Tauc equation with n = 1/2.
SpectroscopyNear infrared
2023 · Redox-Active Two-Dimensional Tetrathiafulvalene-Copper Metal-Organic Framework with Boosted Electrochemical Performances for Supercapatteries
Iodine-treated crystals of 1 (1-ox) · Single Crystal · Room-temperature optical diffuse reflectance spectra converted to absorption using Kubelka-Munk function.
SpectroscopyUnspecified subtype
2023 · Regulating Crystallization and Lead Leakage of Perovskite Solar Cell Via Novel Polyoxometalate-Based Metal–Organic Framework
POMOF reddish-brown block crystals · Single Crystal · TGA in nitrogen or air, 5 degC min-1; UV-vis spectrum of POMOF.
SpectroscopyUnspecified subtype
2023 · Regulating Crystallization and Lead Leakage of Perovskite Solar Cell Via Novel Polyoxometalate-Based Metal–Organic Framework
POMOF/Pb0/I0 redox model mixture · Unknown · Pb0 (50 mg) and I0 (42 mg) in 2.5 mL DMF/DMSO (9:1 v/v), +/- POMOF (45 mg), stirred 60 min at 100 degC.
Diffraction StructureIn situ / operando
2023 · Regulating Crystallization and Lead Leakage of Perovskite Solar Cell Via Novel Polyoxometalate-Based Metal–Organic Framework
POMOF-functionalised perovskite film · Thin Film · Perovskite precursor with/without POMOF heated at 100 degC for 1 h under N2; in situ XRD annealing sequence 0-3600 s; GIWAXS after 60 min anneal.
SpectroscopyTauc / Kubelka-Munk
2023 · Regulating Crystallization and Lead Leakage of Perovskite Solar Cell Via Novel Polyoxometalate-Based Metal–Organic Framework
POMOF-functionalised perovskite film · Thin Film · Control and POMOF-functionalised perovskite films compared for optical band gap, cutoff/onset energies, and calculated valence-band levels.
SpectroscopyUnspecified subtype
2023 · Ruthenium(II) complex-grafted conductive metal-organic frameworks with conductivity- and confinement-enhanced electrochemiluminescence for ultrasensitive biosensing application
Ru@Ni3(HITP)2 powder · Powder · Characterisation of Ru grafting, charge reversal, particle size and Ru/Ni ratio.
Electrochemistry ApplicationUnspecified subtype
2023 · Self-Powered Disinfection Using Triboelectric, Conductive Wires of Metal-Organic Frameworks
Cu-HHTP NW-Cu electrode · Electrode · H2O2 concentration measured at 316 nm under regulated TENG DC output; 10 mM PBS pH 7.0 when stated.
SpectroscopyTauc / Kubelka-Munk
2023 · Self-Powered Infrared Photodetectors with Ultra-High Speed and Detectivity Based on Amorphous Cu-Based MOF Films
p-a-Cu-HHTP/glass optical film · Thin Film · Optical transmittance and band gap of p-a-Cu-HHTP film on glass.
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · Stabilizing Redox-Active Hexaazatriphenylene in a 2D Conductive Metal–Organic Framework for Improved Lithium Storage Performance
Cu-HATN powder · Powder · EPR on Bruker EMX-6/1; solid UV-vis-NIR on Shimadzu UV-3600.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2023 · Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene
Complex 1 bulk powdered sample · Powder · Room-temperature diffuse reflectance, 200-2500 nm, BaSO4 baseline; Tauc-plot fitting of absorption onset
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2023 · Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene
Complex 2 bulk powdered sample · Powder · Room-temperature diffuse reflectance, 200-2500 nm, BaSO4 baseline; Tauc-plot fitting of absorption onset
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2023 · Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene
Complex 3 bulk powdered sample · Powder · Room-temperature diffuse reflectance, 200-2500 nm, BaSO4 baseline; Tauc-plot fitting of absorption onset
SpectroscopyUnspecified subtype
2023 · Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves
PcCu-Cu-30C MOF film · Thin Film · PcCu-Cu film; UV-vis/UPS electronic-structure measurement and derived LUMO.
SpectroscopyUnspecified subtype
2023 · Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves
PcH2-Cu-30C MOF film · Thin Film · PcH2-Cu film; UV-vis/UPS electronic-structure measurement and derived LUMO.
SpectroscopyUnspecified subtype
2023 · Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves
PcNi-Cu-30C MOF film · Thin Film · PcNi-Cu film; UV-vis/UPS electronic-structure measurement and derived LUMO.
SpectroscopyUnspecified subtype
2023 · Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves
PcM-Cu-nC MOF film series (M = Ni, Cu, H2; n = 10-40 cycles) · Thin Film · Electronic structure of PcM-Cu films; UPS acquired at 300 K in SI.
SpectroscopyUnspecified subtype
2023 · Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves
PcM-Cu-nC MOF film series (M = Ni, Cu, H2; n = 10-40 cycles) · Thin Film · PcM-Cu films with different cycle numbers.
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · Two-Dimensional Conjugated Metal-Organic Frameworks with Large Pore Apertures and High Surface Areas for NO2 Selective Chemiresistive Sensing
HIOTP-Ni black powder · Powder · UV-Vis-NIR from 250 to 2000 nm; UPS used to derive HOMO and LUMO values.
SpectroscopyTauc / Kubelka-MunkNear infrared
2023 · Wavy Two-Dimensional Conjugated Metal-Organic Framework with Metallic Charge Transport
Cu3(HFcHBC)2 polycrystalline film · Thin Film · Thin film on quartz glass in transmission mode.
SpectroscopyTauc / Kubelka-Munk
2023 · Zeolites as a Class of Semiconductors for High-Performance Electrically Transduced Sensing
Na-ZSM-5 (9.8) · Powder · Na-ZSM-5 series; direct-band-gap exponent n = 1/2
SpectroscopyTauc / Kubelka-Munk
2022 · 2D Cd(II)-MOF of Pyridyl-Imidazoquinazoline: Structure, Luminescence, and Selective Detection of TNP and Fabrication of Semiconducting Devices
CP 1 acetonitrile dispersion for fluorescence sensing · Unknown · Optical spectrum measured within 300-700 nm; Tauc equation used for direct optical band gap.
SpectroscopyTauc / Kubelka-MunkNear infrared
2022 · 2D Metal–Organic Framework Cu3(HHTT)2 Films for Broadband Photodetectors from Ultraviolet to Mid-Infrared
Optimised 12-cycle Cu3(HHTT)2 film on SiO2/Si · Thin Film · Tauc plot of absorption spectrum for 132 nm Cu3(HHTT)2 film.
SpectroscopyDiffuse reflectance
2022 · A Novel Electrically Conductive Perylene Diimide-Based MOF-74 Series Featuring Luminescence and Redox Activity
PDI-MOF-74(Mg) powder · Powder · UV-vis diffuse reflectance with BaSO4/Kubelka-Munk; PL excitation 405 nm; TCSPC with 476 nm excitation recorded at emission maxima
SpectroscopyDiffuse reflectance
2022 · A Novel Electrically Conductive Perylene Diimide-Based MOF-74 Series Featuring Luminescence and Redox Activity
PDI-MOF-74(Ni) powder · Powder · UV-vis diffuse reflectance with BaSO4/Kubelka-Munk; PL excitation 405 nm; TCSPC with 476 nm excitation recorded at emission maxima
SpectroscopyDiffuse reflectance
2022 · A Novel Electrically Conductive Perylene Diimide-Based MOF-74 Series Featuring Luminescence and Redox Activity
PDI-MOF-74(Zn) powder · Powder · UV-vis diffuse reflectance with BaSO4/Kubelka-Munk; PL excitation 405 nm; TCSPC with 476 nm excitation recorded at emission maxima
SpectroscopyUnspecified subtype
2022 · A semiconducting uranium-organic framework based on a tetrathiafulvalene derivative
SCU-125 bulk powder/ground crystals · Powder · Recorded from 200 to 800 nm; spectral data collected at 25 deg C +/- 2 deg C.
SpectroscopyNear infrared
2022 · A stable lanthanum hydroxamate metal-organic framework with radical character and electrical conductivity
La-ONDI-DMF pressed pellet · Pellet · UV-vis absorption spectra collected on Jasco V-670 UV-Vis-NIR spectrometer; DMF sample is representative sample key and all La-ONDI variants are recorded in results.
Electrochemistry ApplicationUnspecified subtype
2022 · Atomically Precise Integration of Multiple Functional Motifs in Catalytic Metal-Organic Frameworks for Highly Efficient Nitrate Electroreduction
In8 catalyst ink on carbon paper electrode · Electrode · H-type cell, Nafion 211 membrane, H2SO4 pH 1-5, KNO3 0.5-50 g L-1, Ar purge, typically -0.7 V vs RHE for 1 h.
Sensing ApplicationUnspecified subtype
2022 · Bifunctional 3D-MOF-based nanoprobes for electrochemical sensing and nanozyme enhanced with peroxidase mimicking for colorimetric detection of acetaminophen
ZIF-67-C powder · Powder · Varied ACM concentration with constant ZIF-67-C catalyst, TMB, and H2O2; absorbance at 652 nm.
Sensing ApplicationUnspecified subtype
2022 · Bifunctional 3D-MOF-based nanoprobes for electrochemical sensing and nanozyme enhanced with peroxidase mimicking for colorimetric detection of acetaminophen
ZIF-67-C powder · Powder · TMB/H2O2/ACM/buffer reaction systems; absorbance maximum at 652 nm; compared ZIF-67-C, ZIF-67-A, and ZIF-67-H.
Sensing ApplicationUnspecified subtype
2022 · Bifunctional 3D-MOF-based nanoprobes for electrochemical sensing and nanozyme enhanced with peroxidase mimicking for colorimetric detection of acetaminophen
ZIF-67-C powder · Powder · Varied ACM or TMB concentration with ZIF-67-C and constant remaining assay components; Michaelis-Menten and Lineweaver-Burk analysis discussed.
SpectroscopyUnspecified subtype
2022 · Boosting the Optoelectronic Performance by Regulating Exciton Behaviors in a Porous Semiconductive Metal-Organic Framework
RhB+@TbTATAB guest-loaded crystals · Powder · Single-crystal solid-state UV-vis absorption using microspectrophotometer.
SpectroscopyUnspecified subtype
2022 · Boosting the Optoelectronic Performance by Regulating Exciton Behaviors in a Porous Semiconductive Metal-Organic Framework
as-synthesised TbTATAB powder/crystals · Powder · Single-crystal solid-state UV-vis absorption using microspectrophotometer.
SpectroscopyDiffuse reflectanceNear infrared
2022 · Bromine Vapor Induced Continuous p- to n-Type Conversion of a Semiconductive Metal-Organic Framework Cu[Cu(pdt)2]
Brx@Cu[Cu(pdt)2] bromine-doped series · Powder · UV-vis-NIR range 2000-350 nm (0.6-3.5 eV) converted by Kubelka-Munk; FT-IR 0.1-0.5 eV by ATR ZnSe.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Bromo- and iodo-bridged building units in metal-organic frameworks for enhanced carrier transport and CO2 photoreduction by water vapor
As-synthesised TMOF-10-NH2(Br) · Single Crystal · UV-Vis DRS at room temperature; Kubelka-Munk/Tauc analysis for direct band gap; VB-XPS for valence-band maximum.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Bromo- and iodo-bridged building units in metal-organic frameworks for enhanced carrier transport and CO2 photoreduction by water vapor
As-synthesised TMOF-10-NH2(I) · Single Crystal · UV-Vis DRS at room temperature; Kubelka-Munk/Tauc analysis for direct band gap; VB-XPS for valence-band maximum.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2022 · Chemical structure modulation in conductive MOFs by adjusting the oxidation state of the ligand and introducing alkali metal ions
MnHHB dark-blue powder · Powder · 220-1400 nm at room temperature; powder spread on barium sulfate matrix.
SpectroscopyUnspecified subtype
2022 · Conductive NiCo bimetal-organic framework nanorods with conductivity-enhanced electrochemiluminescence for constructing biosensing platform
Ni-HHTP monometallic MOF control · Powder · Optical spectra of Ni-HHTP control; PL excitation wavelength reported as 257 nm.
SpectroscopyUnspecified subtype
2022 · Conductive NiCo bimetal-organic framework nanorods with conductivity-enhanced electrochemiluminescence for constructing biosensing platform
NiCo-HHTP nanorods · Powder · Optical properties of NiCo-HHTP; PL excitation wavelength reported as 259 nm.
SpectroscopyUnspecified subtype
2022 · Conjugated Metal-Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity
CuTOTP-OR family-level sample (variant not individually separated in reported result) · Unknown · ATR-IR of CuTOTP-OR; UV-Vis thin films drop-cast on quartz from 4 mg/mL THF; X-band EPR at 110 K.
SpectroscopyDiffuse reflectance
2022 · Constructing a Redox-Active Cu(I)-Pyridyltriazine Framework for Catalytic Photoreduction of Nitrobenzenes and Carboxylic Cyclization of Alkynol with CO2
As-synthesised Cu(I)-TPT orange rhombus single crystals · Single Crystal · UV-vis spectrum on UH4150; photoluminescence on EDINBURGH FLS 980 with 450 W xenon lamp; PL emission measured under 330 nm excitation.
SpectroscopyTauc / Kubelka-MunkNear infrared
2022 · Crystal Structure and Electrochemical and Charge Transfer Properties in Redox-Active Coordination Polymers Based on a Truncated Tetrathiafulvalene Linker
as-synthesised Cd-m-TTFTB red rod-like crystals · Powder · Room-temperature solid-state spectra with BaSO4 baseline; Kubelka-Munk transform.
SpectroscopyTauc / Kubelka-MunkNear infrared
2022 · Crystal Structure and Electrochemical and Charge Transfer Properties in Redox-Active Coordination Polymers Based on a Truncated Tetrathiafulvalene Linker
as-synthesised Zn-m-TTFTB red rod-like crystals · Powder · Room-temperature solid-state spectra with BaSO4 baseline; Kubelka-Munk transform.
SpectroscopyUnspecified subtype
2022 · Dense Conductive Metal-Organic Frameworks as Robust Electrocatalysts for Biosensing
Comparative pristine cMOF powder series · Powder · Solid FTIR of ligands and cMOF powders; UV-vis absorbance spectra of materials.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2022 · Dimensionality Modulates Electrical Conductivity in Compositionally Constant One-, Two-, and Three-Dimensional Frameworks
Ni-1D rods/bricks · Powder · Diffuse reflectance UV-vis-NIR from 200-2500 nm, stitched manually with DRIFTS spectra for Tauc plots.
Sensing ApplicationUnspecified subtype
2022 · Dual nanozyme based on ultrathin 2D conductive MOF nanosheets intergraded with gold nanoparticles for electrochemical biosensing of H2O2 in cancer cells
Au-NPs/Cu-HHTP-NSs · Nanosheet · TMB/H2O2 colourimetric POD-like activity comparison; SI method used 30 uL TMB (20 mM), 100 uL H2O2 (60 mM), 50 uL Au-NPs/Cu-HHTP-NSs (200 ug mL-1), 15 min incubation.
SpectroscopyUnspecified subtype
2022 · Dual nanozyme based on ultrathin 2D conductive MOF nanosheets intergraded with gold nanoparticles for electrochemical biosensing of H2O2 in cancer cells
Au-NPs/Cu-HHTP-NSs · Nanosheet · Spectroscopic confirmation of Cu-O coordination and Au-NP surface plasmon response.
OtherUnspecified subtype
2022 · Efficient sequestration of radioactive 99TcO4- by a rare 3-fold interlocking cationic metal-organic framework: A combined batch experiments, pair distribution function, and crystallographic investigation
ZJU-X6 powder/material for batch sorption · Powder · 30 mg ZJU-X6 in 30 mL 30 ppm 99TcO4- aqueous solution, room temperature, solid-liquid ratio 1 g/L; aliquots at 3, 5, 10 and 20 min filtered by 0.22 um membrane.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2022 · Electrical conductivity through π–π stacking in a two-dimensional porous gallium catecholate metal–organic framework
Supercritical CO2-activated Ga9(HOTP)4 powder · Powder · DRIFTS on 0.5-1 wt.% MOF/KBr mixtures, 8000-600 cm-1; diffuse reflectance 350-3300 nm under ambient conditions; UV-vis-NIR and DRIFTS manually stitched for Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Electrically Conductive Photoluminescent Porphyrin Phosphonate Metal–Organic Frameworks
GTUB3 single crystals / crystal powder · Single Crystal · Perkin Elmer Lambda 950 UV-Vis-NIR diffuse reflectance spectrum; Kubelka-Munk/Tauc treatment; indirect allowed transition factor n=2 best matched PL.
SpectroscopyTauc / Kubelka-Munk
2022 · Electrically regulating nonlinear optical limiting of metal-organic framework film
Cu-HHTP[001] film · Thin Film · UV-vis spectra measured by Lambda 365; band gaps estimated from Tauc plots.
SpectroscopyTauc / Kubelka-Munk
2022 · Exploration of Variable Temperature Magnetism and Electrical Properties of a Pyridyl-isonicotinoyl Hydrazone Bridged Three-Dimensional Mn-Metal-Organic Framework with a Thiophene Dicarboxylato Link
polycrystalline/finely ground compound 1 · Powder · well-dispersed compound 1 in DMF solution; absorption spectra in 250-600 nm range; exponent n assumed 1/2
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Fe–O–Zr in MOF for effective photo-Fenton Bisphenol A degradation: Boosting mechanism of electronic transmission
FeUiO-X series · Powder · Indirect semiconductor Tauc analysis with n = 4.
SpectroscopyTauc / Kubelka-MunkNear infrared
2022 · From 2D to 3D: Postsynthetic Pillar Insertion in Electrically Conductive MOF
Cu-THQ-BPY, Cu2+:BPY feed ratio 1:1 · Powder · MOFs dispersed in isopropyl alcohol for UV-vis-NIR; LUMO measured with 0.01 M Ag/AgNO3 in 0.1 M TBAPF6 acetonitrile reference, Pt counter, glassy carbon working electrode, 0.1 M TBAPF6 acetonitrile electrolyte, Fc/Fc+ reference.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Highly Effective Generation of Singlet Oxygen by an Imidazole-Linked Robust Photosensitizing Covalent Organic Framework
as-synthesized PyPor-COF powder · Powder · PyTO, p-Por-CHO and PyPor-COF compared as powders/solid-state samples.
Electrochemistry ApplicationUnspecified subtype
2022 · Host-guest molecular interaction promoted urea electrosynthesis over a precisely designed conductive metal-organic framework
Co-PMDA-2-mbIM electrode on carbon cloth · Electrode
Electrochemistry ApplicationUnspecified subtype
2022 · Host-guest molecular interaction promoted urea electrosynthesis over a precisely designed conductive metal-organic framework
Co-PMDA-2-mbIM electrode on carbon cloth · Electrode · 0.1 M KHCO3, 15N2 feed, H-type cell, Co-PMDA-2-mbIM electrode; potentials varied, optimum -0.5 V vs RHE.
SpectroscopyUnspecified subtype
2022 · Host-guest molecular interaction promoted urea electrosynthesis over a precisely designed conductive metal-organic framework
Co-PMDA-2-mbIM powder · Powder · Raman lambda 532 nm; UV-vis adsorption; magnetic susceptibility under H = 500 Oe.
SpectroscopyTauc / Kubelka-MunkNear infrared
2022 · Imparting Functionality and Enhanced Surface Area to a 2D Electrically Conductive MOF via Macrocyclic Linker
Pristine Cu-HHTC synthesised at 50 C for 8 h · Powder · As-synthesised MOF dispersed in isopropyl alcohol for UV-vis-NIR; Tauc plot derived from absorbance.
SpectroscopyTauc / Kubelka-Munk
2022 · Improved electrical conductivity of Co(ii) and Cu(ii) ladder polymers in the fabrication of photoresponsive Schottky devices
Co-CP brown block-shaped crystals · Single Crystal · Direct optical band gap extracted from (alpha hnu)^2 vs hnu plot.
SpectroscopyTauc / Kubelka-Munk
2022 · Improved electrical conductivity of Co(ii) and Cu(ii) ladder polymers in the fabrication of photoresponsive Schottky devices
Cu-CP green block-shaped crystals · Single Crystal · Direct optical band gap extracted from (alpha hnu)^2 vs hnu plot.
SpectroscopyTauc / Kubelka-Munk
2022 · Insight into charge transportation in cadmium based semiconducting organic-inorganic hybrid materials and their application in the fabrication of photosensitive Schottky devices
single crystals of complex 1 · Single Crystal · Band gap calculated by extrapolating the linear region of (alpha h nu)^2 vs h nu to alpha = 0; UV-Vis spectra in DMF shown in Fig. S3.
SpectroscopyTauc / Kubelka-Munk
2022 · Insight into charge transportation in cadmium based semiconducting organic-inorganic hybrid materials and their application in the fabrication of photosensitive Schottky devices
single crystals of complex 2 · Single Crystal · Band gap calculated by extrapolating the linear region of (alpha h nu)^2 vs h nu to alpha = 0; UV-Vis spectra in DMF shown in Fig. S3.
SpectroscopyTauc / Kubelka-Munk
2022 · Insight into charge transportation in cadmium based semiconducting organic-inorganic hybrid materials and their application in the fabrication of photosensitive Schottky devices
as-prepared H2L ligand · Powder · Band gap calculated by extrapolating the linear region of (alpha h nu)^2 vs h nu to alpha = 0; UV-Vis spectra in DMF shown in Fig. S3.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand
iodine-treated Tb-MOF bulk powder · Powder · Shimadzu UV-2600 with integrated sphere, 200-1100 nm range; optical band gaps determined from Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand
pristine Tb-MOF bulk powder/crystals · Powder · Shimadzu UV-2600 with integrated sphere, 200-1100 nm range; optical band gaps determined from Tauc plots.
SpectroscopyTauc / Kubelka-MunkNear infrared
2022 · Iron-Based 2D Conductive Metal-Organic Framework Nanostructure with Enhanced Pseudocapacitance
Fe-HHTP powder · Powder · CARY 5000 UV-Vis spectrophotometer; sample dispersed in isopropyl alcohol.
Electrochemistry ApplicationTauc / Kubelka-Munk
2022 · Large π-Conjugated Metal-Organic Frameworks for Infrared-Light-Driven CO2Reduction
TNP-MOF crystals · Single Crystal · Mott-Schottky in 0.2 M Na2SO4; Tauc plot for band gap
Electrical TransportUnspecified subtype
2022 · Large-Area Synthesis of Ultrathin, Flexible, and Transparent Conductive Metal–Organic Framework Thin Films via a Microfluidic-Based Solution Shearing Process
MASS-PRC Ni3(HITP)2 thin film · Thin Film · Sheet resistance and 550 nm transmittance measured on Ni3(HITP)2 films; transmittance measured on quartz substrates.
Electrochemistry ApplicationTauc / Kubelka-Munk
2022 · Li-TFSI endohedral Metal-Organic frameworks in stable perovskite solar cells for Anti-Deliquescent and restricting ion migration
Li-TFSI@NH2-MIL-101 powder · Powder · band alignment of MOF additives
Electrochemistry ApplicationUnspecified subtype
2022 · Li-TFSI endohedral Metal-Organic frameworks in stable perovskite solar cells for Anti-Deliquescent and restricting ion migration
PSC with Li-TFSI@NH2-MIL-101 doped HTL · Electrode · ambient environment at 90% RH and room temperature; ageing 0, 3, 5 and 12 h in Fig. 6a
OtherUnspecified subtype
2022 · Metal organic frameworks (MOFs) as potential anode materials for improving power generation from algal biophotovoltaic (BPV) platforms
biofilm loaded Cu-MOF/ITO · Electrode · Chl-a content measured from Chlorella biofilms on Days 0, 4, 8, and 12.
OtherUnspecified subtype
2022 · Metal organic frameworks (MOFs) as potential anode materials for improving power generation from algal biophotovoltaic (BPV) platforms
biofilm loaded Cu-Ni MOF/ITO · Electrode · Chl-a content measured from Chlorella biofilms on Days 0, 4, 8, and 12.
OtherUnspecified subtype
2022 · Metal organic frameworks (MOFs) as potential anode materials for improving power generation from algal biophotovoltaic (BPV) platforms
biofilm loaded ITO · Electrode · Chl-a content measured from Chlorella biofilms on Days 0, 4, 8, and 12.
SpectroscopyTauc / Kubelka-Munk
2022 · Millimeter-scale semiconductive metal-organic framework single crystal for X-ray imaging
SCU-15 large single crystal · Single Crystal · UV-visible absorption spectrum recorded on a single crystal using a Craic Technologies microspectrophotometer.
SpectroscopyDiffuse reflectance
2022 · Multi-stimulus semiconductor Cu(i)-I-pyrimidine coordination polymer with thermo- and mechanochromic sensing
CP1 precipitated bulk solid / polycrystalline powder · Powder · Diffuse reflectance spectrum of CP1 compared with aClpym ligand over roughly 300-1200 nm.
Electrochemistry ApplicationUnspecified subtype
2022 · Operando Elucidation of Electrocatalytic and Redox Mechanisms on a 2D Metal Organic Framework Catalyst for Efficient Electrosynthesis of Hydrogen Peroxide in Neutral Media
Ni-HAB/CFP electrode · Electrode · Custom H-cell, O2-saturated 0.5 M NaPi pH 6.64, 5 mL initial volume, potentials 0.6/0.5/0.4 V vs RHE, aliquots analysed by UV-vis.
OtherUnspecified subtype
2022 · Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal-organic framework
Purified HHTP · Model · 20 mL vial with quinone and inner 4 mL DMF vial heated at 80 deg C; sublimed quinone measured by UV-Vis.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Pd-Embedded Ti Metal–Organic Framework Nanostructures for Photocatalytic Reductive N-Formylation of Nitroarenes in Water
Pd1.5%/Ti-MOF · Powder · DR UV-vis spectrum with absorption edge and Tauc bandgap reported in main text and shown in rendered SI Figure S5.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Pd-Embedded Ti Metal–Organic Framework Nanostructures for Photocatalytic Reductive N-Formylation of Nitroarenes in Water
Ti-MOF · Powder · DR UV-vis spectrum with absorption edge and Tauc bandgap reported in main text and shown in rendered SI Figure S5.
SpectroscopyUnspecified subtype
2022 · Polythiophene hybrid film with zirconium–porphyrin metal–organic framework for improved charge carrier transport and NO2 gas sensing
pristine P3HT OTFT film · Thin Film · Pristine P3HT control film; spectra and thickness bar shown in SI Fig. S1.
SpectroscopyUnspecified subtype
2022 · Polythiophene hybrid film with zirconium–porphyrin metal–organic framework for improved charge carrier transport and NO2 gas sensing
PCN-222/P3HT blend film series · Thin Film · Pristine P3HT and P3HT films containing 10, 20, and 30 wt% PCN-222; spectra and thickness bars shown in SI Fig. S1.
SpectroscopyUnspecified subtype
2022 · Rapid and sensitive detection of PD-L1 exosomes using Cu-TCPP 2D MOF as a SPR sensitizer
Cu-TCPP 2D MOF nanosheets · Nanosheet · Comparison of TCPP ligand and Cu-TCPP 2D MOF to verify metallisation and Cu-carboxylate coordination.
SpectroscopyTauc / Kubelka-Munk
2022 · Rational synthesis of a pyridyl-imidazoquinazoline based multifunctional 3D Zn(ii)-MOF: structure, luminescence, selective and sensitive detection of Al3+ and TNP, and its semiconducting device application
As-synthesised bulk material of 1 · Powder · Direct optical band gap calculated using Tauc equation with n = 1/2
SpectroscopyUnspecified subtype
2022 · Rational synthesis of a pyridyl-imidazoquinazoline based multifunctional 3D Zn(ii)-MOF: structure, luminescence, selective and sensitive detection of Al3+ and TNP, and its semiconducting device application
10 uM suspension of 1 in acetonitrile · Unknown · Compound 1 dispersed in acetonitrile at ambient temperature; excitation at 380 nm for emission
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2022 · Redox-Active Metal-Organic Frameworks with Three-Dimensional Lattice Containing the m-Tetrathiafulvalene-Tetrabenzoate
Er-m-TTFTB polycrystalline/powder sample · Powder · Harrick Praying Mantis attachment over 200-900 nm; Kubelka-Munk transform.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2022 · Redox-Active Metal-Organic Frameworks with Three-Dimensional Lattice Containing the m-Tetrathiafulvalene-Tetrabenzoate
Gd-m-TTFTB polycrystalline/powder sample · Powder · Harrick Praying Mantis attachment over 200-900 nm; Kubelka-Munk transform.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2022 · Redox-Active Metal-Organic Frameworks with Three-Dimensional Lattice Containing the m-Tetrathiafulvalene-Tetrabenzoate
m-H4TTFTB red solid/free ligand powder · Powder · Ligand band gap estimated by the same Tauc approach; ligand conductivity comparator is literature cited [31], not first-hand in this paper.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2022 · Redox-Active Metal-Organic Frameworks with Three-Dimensional Lattice Containing the m-Tetrathiafulvalene-Tetrabenzoate
Tb-m-TTFTB polycrystalline/powder sample · Powder · Harrick Praying Mantis attachment over 200-900 nm; spectra reported as Kubelka-Munk transform.
Electrochemistry ApplicationUnspecified subtype
2022 · Redox-Active Ni(II) Nodes Induced Electrochromism in a Two-Dimensional Conductive Metal-Organic Framework
Ni3(HITP)2-362 nm/FTO electrode · Electrode · Delta T calculated as Tb - Tc according to eq S1; biases 0.2 V and -1.5 V in 1 M LiClO4/PC.
Electrochemistry ApplicationIn situ / operando
2022 · Redox-Active Ni(II) Nodes Induced Electrochromism in a Two-Dimensional Conductive Metal-Organic Framework
Ni3(HITP)2-362 nm/FTO electrode · Electrode · Three-electrode cell; 1 M LiClO4/PC electrolyte; spectra at 0.2 V coloured state and -1.5 V bleached state over 400-800 nm.
SpectroscopyUnspecified subtype
2022 · Size-Dependent Properties of Solution-Processable Conductive MOF Nanocrystals
Fe(TA)2 nanoparticle series synthesised with 1-methylimidazole · Powder · Air-free quartz cuvettes; long-range scans 1350-265 nm and Beer law experiments 900-265 nm; extinction coefficients from absorbance versus particle concentration.
SpectroscopyTauc / Kubelka-MunkNear infrared
2022 · sp-Carbon Incorporated Conductive Metal-Organic Framework as Photocathode for Photoelectrochemical Hydrogen Generation
Cu3HHAE2 drop-cast film on quartz glass · Thin Film · Catalyst drop-cast on quartz glass in transmission mode; compared HHAE and Cu3HHAE2, absorption followed to 1600 nm.
SpectroscopyUnspecified subtype
2022 · Synthesis and Characterization of Schiff Base Polymers via Metal Coordination and Its Application in Infrared Stealth Coating
D230-PyAL-Cu coating · Thin Film · FTIR/XPS used to evaluate coordination; ICP determined Cu content; UV-Vis used to determine optical band gap
SpectroscopyUnspecified subtype
2022 · Synthesis and Characterization of Schiff Base Polymers via Metal Coordination and Its Application in Infrared Stealth Coating
D230-PyAL coating/polymer · Thin Film · 1H NMR in CDCl3 at 300 K; UV-Vis used to determine optical band gap; FTIR/XPS used for structure assignment
SpectroscopyUnspecified subtype
2022 · Synthesis and Characterization of Schiff Base Polymers via Metal Coordination and Its Application in Infrared Stealth Coating
D230-PyAL-Ni coating · Thin Film · FTIR/XPS used to evaluate coordination; ICP determined Ni content; UV-Vis used to determine optical band gap
SpectroscopyUnspecified subtype
2022 · Synthesis and Characterization of Schiff Base Polymers via Metal Coordination and Its Application in Infrared Stealth Coating
D230-PyAL-Sm coating · Thin Film · FTIR/XPS used to evaluate coordination; ICP determined Sm content; UV-Vis used to determine optical band gap
SpectroscopyUnspecified subtype
2022 · Tunable Capacitive Behavior in Metallopolymer-based Electrochromic Thin Film Supercapacitors
poly-Fe-L2 isolated metallopolymer powder · Powder · MeOH, c = 15 microM; electronic absorption and emission spectra
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Ultra-thin Two-Dimensional Trimetallic Metal-Organic Framework for Photocatalytic Reduction of CO2
Ni-BDC nanosheets · Nanosheet · powder UV-vis plus Mott-Schottky-derived band positions
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Ultra-thin Two-Dimensional Trimetallic Metal-Organic Framework for Photocatalytic Reduction of CO2
NiZr-BDC nanosheets · Nanosheet · powder UV-vis plus Mott-Schottky-derived band positions
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2022 · Ultra-thin Two-Dimensional Trimetallic Metal-Organic Framework for Photocatalytic Reduction of CO2
NiZrCu-BDC nanosheets · Nanosheet · powder UV-vis plus Mott-Schottky-derived band positions
SpectroscopyUnspecified subtype
2022 · Ultra-thin Two-Dimensional Trimetallic Metal-Organic Framework for Photocatalytic Reduction of CO2
NiZrCu-BDC nanosheets · Nanosheet · powder-state UV-vis absorption
Microscopy MorphologyUnspecified subtype
2022 · Ultrathin Self-Assembly Two-Dimensional Metal-Organic Framework Films as Hole Transport Layers in Ideal-Bandgap Perovskite Solar Cells
Cu3(HHTT)2 film on SiO2/Si · Thin Film · AFM roughness and edge-profile thickness of cMOF films; UV-vis absorption of thick cMOF film.
Diffraction StructureTauc / Kubelka-Munk
2022 · Ultrathin Self-Assembly Two-Dimensional Metal-Organic Framework Films as Hole Transport Layers in Ideal-Bandgap Perovskite Solar Cells
FA0.83Cs0.17Sn0.35Pb0.65I2.9Br0.1 perovskite on Cu3(HHTT)2 · Thin Film · Pb-Sn perovskite films on Cu3(HHTT)2 and NiOx HTLs compared under the same processing conditions.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · A 3D Cu-Naphthalene-Phosphonate Metal–Organic Framework with Ultra-High Electrical Conductivity
As-synthesised TUB40 single-phase crystals · Single Crystal · Reflectance spectrum of handpicked TUB40 crystals; band gap estimated by indirect Tauc plotting.
SpectroscopyUnspecified subtype
2021 · A multifunctional n-doped cu–mofs (N–cu–mof) nanomaterial-driven electrochemical aptasensor for sensitive detection of deoxynivalenol
AP1/N-Cu-MOF material · Powder · UV-vis spectra of N-Cu-MOF, AP1, and AP1-N-Cu-MOF.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands
I2-treated sine-MOF powder · Powder · Diffuse-reflectance spectra measured from 200-1400 nm using an integrating sphere; optical bandgap determined from Tauc plot.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands
pristine sine-MOF evacuated powder · Powder · Diffuse-reflectance spectra measured from 200-1400 nm using an integrating sphere; optical bandgap determined from Tauc plot.
SpectroscopyUnspecified subtype
2021 · A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands
Z-DPTTF ligand in DMF · Model · Z-DPTTF ligand measured in DMF on Shimadzu UV-2600 spectrophotometer.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2021 · An Electrically Conducting Three-Dimensional Iron–Catecholate Porous Framework
Fe-HHTP-MOF black microcrystalline powder · Powder · PerkinElmer Lambda 1050 with 150 mm InGaAs integrating sphere; Praying Mantis diffuse-reflectance accessory; BaSO4 white standard.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivity
Co@Mn2DSBDC powder · Powder · Shimadzu UV-2600 with integrating sphere; band gaps extracted from Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivity
Cu@Mn2DSBDC powder · Powder · Shimadzu UV-2600 with integrating sphere; band gaps extracted from Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivity
as-prepared Mn2DSBDC powder · Powder · Shimadzu UV-2600 with integrating sphere; band gaps extracted from Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivity
Ni@Mn2DSBDC powder · Powder · Shimadzu UV-2600 with integrating sphere; band gaps extracted from Tauc plots.
SpectroscopyUnspecified subtype
2021 · Conductive metal-organic frameworks promoting polysulfides transformation in lithium-sulfur batteries
Ni-HHTP particles · Powder · UV-vis spectra of polysulfide solution after 6 h adsorption with Ni-HHTP or Ni-BTC.
SpectroscopyTauc / Kubelka-MunkNear infrared
2021 · Conductive Stimuli-Responsive Coordination Network Linked with Bismuth for Chemiresistive Gas Sensing
Bi(HHTP) transparent thin film on quartz cuvette · Thin Film · Drop-cast transparent Bi(HHTP) film on quartz cuvette; Jasco v570; room temperature
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Conjugated crosslinks boost the conductivity and stability of a single crystalline metal-organic framework
activated ZrBPD-4F4TS-Ox · Powder · activated ZrBPD-4F4TS-Ox
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Conjugated crosslinks boost the conductivity and stability of a single crystalline metal-organic framework
activated ZrBPD-4F4TS · Powder · activated ZrBPD-4F4TS
Electrochemistry ApplicationTauc / Kubelka-Munk
2021 · Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons
PCN-222(Fe) · Powder · Bandgaps estimated from Tauc plots for PCN-222(Fe), PCN-222(Co), PCN-222(Ni), and PCN-222(Cu); UV-vis spectra obtained using Shimadzu UV-2600; supporting figures S8a, S9a, S10a and Figure 7a.
SpectroscopyUnspecified subtype
2021 · Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal–organic frameworks to achieve useful hydrocarbons
PCN-222(Fe) · Powder · UV-vis spectra of PCN-222(M) and metalloporphyrin precursors; spectra are in missing SI Figures S2-S3.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
Cs-MOF 4 · Powder · Shimadzu UV-2600/ISR-2600 Plus (400-1400 nm) and Cary 7000 up to 2400 nm; direct optical band gap from Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
K-MOF 2 · Powder · Shimadzu UV-2600/ISR-2600 Plus (400-1400 nm) and Cary 7000 up to 2400 nm; direct optical band gap from Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
K-MOF 2-ox · Powder · Shimadzu UV-2600/ISR-2600 Plus (400-1400 nm) and Cary 7000 up to 2400 nm; direct optical band gap from Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
Na-MOF 1-ox · Powder · Shimadzu UV-2600/ISR-2600 Plus (400-1400 nm) and Cary 7000 up to 2400 nm; direct optical band gap from Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
Rb-MOF 3 · Powder · Shimadzu UV-2600/ISR-2600 Plus (400-1400 nm) and Cary 7000 up to 2400 nm; direct optical band gap from Tauc plots.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
Rb-MOF 3-ox · Powder · Shimadzu UV-2600/ISR-2600 Plus (400-1400 nm) and Cary 7000 up to 2400 nm; direct optical band gap from Tauc plots.
SpectroscopyUnspecified subtype
2021 · Electrically Conductive Metal–Organic Framework Thin Film-Based On-Chip Micro-Biosensor: A Platform to Unravel Surface Morphology-Dependent Biosensing
Cu-BHT film on quartz wafer · Thin Film · Cu-BHT thin film transferred to quartz wafer; transmittance spectrum recorded from visible to near-infrared range.
SpectroscopyUnspecified subtype
2021 · Electrochemical Synthesis of Large Area Two-Dimensional Metal–Organic Framework Films on Copper Anodes
As-grown Cu3(HHTP)2 MOF film on single-crystal Cu(100) anode · Thin Film · Cu3(HHTP)2 MOF film, Cu3(HHTP)2 powder and HHTP ligand spectra.
Computational ModellingNear infrared
2021 · Electron-Conductive Metal-Organic Framework, Fe(dhbq)(dhbq = 2,5-Dihydroxy-1,4-benzoquinone): Coexistence of Microporosity and Solid-State Redox Activity
Fe dimer computational model · Model · Dimer model {Fe(Hdhbq)2}2 and Fe2(dhbq)(Hdhbq)2(H2O)4 frontier orbitals; code/functional not specified in extracted text
SpectroscopyTauc / Kubelka-MunkNear infrared
2021 · Electron-Conductive Metal-Organic Framework, Fe(dhbq)(dhbq = 2,5-Dihydroxy-1,4-benzoquinone): Coexistence of Microporosity and Solid-State Redox Activity
Anhydrous Fe(dhbq) powder · Powder · Samples diluted with BaSO4; Kubelka-Munk conversion; Zn analogues used as comparison
SpectroscopyNear infrared
2021 · Emergence of Metallic Conductivity in Ordered One-Dimensional Coordination Polymer Thin Films upon Reductive Doping
Cu-DMD film on quartz for UV-vis-NIR · Thin Film · Perkin Elmer Lambda 1050 with integrating sphere; PMT/InGaAs detectors; 15 nm films on quartz
SpectroscopyNear infrared
2021 · Enhancing Electrical Conductivity of Semiconducting MOFs via Defect Healing
HAB-treated Cu3(HAB)2, 30 min · Pellet · Samples dispersed in isopropyl alcohol.
SpectroscopyNear infrared
2021 · Growth and Characterisation of Copper Complex of 2, 4, 6-Trioxypyrimidine: A Novel Luminescent and Active Pharmaceutical Material in Metal Organic Framework
Grown emerald coloured CuB single crystal · Single Crystal · Reported instrument range 200-2000 nm; optical band gap, extinction coefficient, refractive index, and optical conductivity calculated from spectra/reflectance.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Th-34% · Powder · Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Th5U-50% · Powder · Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Th-65% · Powder · Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Zr-33% · Powder · Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Zr-65% · Powder · Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Zr-MOF powder · Powder · Diffuse reflectance spectra; direct allowed transition assumption; dark and after 1 min UV irradiation at 365 nm.
SpectroscopyUnspecified subtype
2021 · Highly Selective and Sensitive Detection of Volatile Sulfur Compounds by Ionically Conductive Metal-Organic Frameworks
Cu-TCPP IC-MOF thin-film sensor on ITO interdigital electrodes · Electrode · H2TCPP and Cu-TCPP IC-MOF spectra compared
SpectroscopyTauc / Kubelka-Munk
2021 · Immobilizing Redox-Active Tricycloquinazoline into a 2D Conductive Metal–Organic Framework for Lithium Storage
Pristine Cu-HHTQ black powder · Powder · UV-vis spectrum measured with UV-2600 spectrophotometer; band gap from Tauc extrapolation.
SpectroscopyUnspecified subtype
2021 · Interfacial Synthesis of Layer-Oriented 2D Conjugated Metal-Organic Framework Films toward Directional Charge Transport
Cu2[PcCu-O8] edge-on MOF film · Thin Film · FTIR on copper foil; XPS AXIS Ultra DLD calibrated to C1s 284.6 eV; UV-vis on 3 x 3 cm quartz wafer
SpectroscopyUnspecified subtype
2021 · Interplay of structural dynamics and electronic effects in an engineered assembly of pentacene in a metal-organic framework
Zn-Pn SURMOF-2 thin film · Thin Film · Absorption using Cary5000 UMA; PL excitation at 3.49 eV; steady-state and time-resolved fluorescence instrumentation in SI
SpectroscopyUnspecified subtype
2021 · Interplay of structural dynamics and electronic effects in an engineered assembly of pentacene in a metal-organic framework
Pn-linker in ethanol · Unknown · 20 microM Pn-linker in ethanol
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2021 · Large Single Crystals of Two-Dimensional π-Conjugated Metal-Organic Frameworks via Biphasic Solution-Solid Growth
Ni-CAT-1 powder · Powder · MOF powder diluted 1% in KBr for diffuse reflectance; dispersed in methanol and drop-cast on quartz for transmission.
SpectroscopyUnspecified subtype
2021 · Layer-by-layer assembled dual-ligand conductive MOF nano-films with modulated chemiresistive sensitivity and selectivity
x mol% HITP doped Cu-HHTP-10C nanofilm series · Thin Film · Maximum absorption peaks monitored for Cu-HITP at 212 nm and Cu-HHTP at 353 nm; I212/I353 compared for 0.5 and 5.0 mol% samples.
SpectroscopyDiffuse reflectance
2021 · Macrocycle-Based Metal-Organic Frameworks with NO2-Driven On/Off Switch of Conductivity
As-grown red MOF A single crystals/powder · Single Crystal · UV-vis absorption spectra at 200-800 nm for A, A-100, A-NO2, and A-100-NO2; UV-vis-NIR diffuse reflectance over 200-2500 nm for bandgaps.
SpectroscopyUnspecified subtype
2021 · Metal-organic framework transistors for dopamine sensing
15-cycle Cu3(HHTP)2 film on glass · Thin Film · Cu3(HHTP)2 films with different growth cycles on substrate.
SpectroscopyUnspecified subtype
2021 · MOF-74(M) Films Obtained through Vapor-Assisted Conversion - Impact on Crystal Orientation and Optical Properties
MOF-74(Co) thin film on quartz · Thin Film · MOF-74(Co) film on quartz; UV-vis and PL with 378 nm excitation.
SpectroscopyUnspecified subtype
2021 · MOF-74(M) Films Obtained through Vapor-Assisted Conversion - Impact on Crystal Orientation and Optical Properties
MOF-74(Mg) thin film on quartz · Thin Film · MOF-74(Mg) film on quartz; UV-vis in transmission; PL with 378 nm excitation.
SpectroscopyUnspecified subtype
2021 · MOF-74(M) Films Obtained through Vapor-Assisted Conversion - Impact on Crystal Orientation and Optical Properties
MOF-74(Ni) thin film on quartz · Thin Film · MOF-74(Ni) film on quartz; UV-vis and PL with 378 nm excitation.
SpectroscopyUnspecified subtype
2021 · MOF-74(M) Films Obtained through Vapor-Assisted Conversion - Impact on Crystal Orientation and Optical Properties
MOF-74(Zn) thin film on quartz · Thin Film · MOF-74(Zn) film on quartz; UV-vis in transmission; PL with 378 nm excitation.
SpectroscopyUnspecified subtype
2021 · NH2-UiO-66 Metal-Organic Framework Nanoparticles for Hydroxide Ion Conductive Photoswitches
NH2-UiO-66-50 · Powder · SI comparison of NH2-UiO-66-10 and NH2-UiO-66-50 powder absorption.
SpectroscopyUnspecified subtype
2021 · NH2-UiO-66 Metal-Organic Framework Nanoparticles for Hydroxide Ion Conductive Photoswitches
NH2-UiO-66-10 · Powder · Light absorption curves of UiO-66 and NH2-UiO-66-10 powders.
SpectroscopyTauc / Kubelka-Munk
2021 · Oriented Growth of In-Oxo Chain Based Metal-Porphyrin Framework Thin Film for High-Sensitive Photodetector
In-TCPP SURMOF, 15 LPE cycles · Thin Film · Spectra from 300 to 800 nm; visible absorption and Q bands assessed.
SpectroscopyDiffuse reflectanceIn situ / operando
2021 · Photochromism and photomagnetism in three cyano-bridged 3d-4f heterobimetallic viologen frameworks
CoDy after UV-vis irradiation · Single Crystal · time-dependent irradiation with 300 W xenon lamp at room temperature
SpectroscopyNear infrared
2021 · Redox Ladder of Ni3 Complexes with Closed-Shell, Mono-, and Diradical Triphenylene Units: Molecular Models for Conductive 2D MOFs
complex 2 dark blue needle-shaped crystals · Single Crystal · Dichloromethane solutions in a home-made Schlenk cuvette at room temperature under nitrogen; solvent/cuvette blank correction.
Electrochemistry ApplicationUnspecified subtype
2021 · Self-Nanocavity-Confined Halogen Anions Boosting the High Selectivity of the Two-Electron Oxygen Reduction Pathway over Ni-Based MOFs
Br-Ni MOF catalyst · Powder · 50 uL catalyst ink on carbon paper; three-electrode H-cell separated by Nafion 117; cathode/anode each 70 mL 0.1 M KOH; O2 purged at least 30 min; ORR at 0.4 V vs RHE and 1600 rpm for 60 min; aliquots sampled at 0-60 min.
SpectroscopyUnspecified subtype
2021 · Simultaneous defect passivation and hole mobility enhancement of perovskite solar cells by incorporating anionic metal-organic framework into hole transport materials
synthesised FJU-17 powder · Powder · FJU-17 dispersed in ethyl alcohol; rhodamine B reference in ethyl alcohol; emission light 300 nm.
SpectroscopyUnspecified subtype
2021 · Simultaneous defect passivation and hole mobility enhancement of perovskite solar cells by incorporating anionic metal-organic framework into hole transport materials
PSC with HTM-FJU-17 DFL · Electrode · PSCs with pristine HTM and HTM-FJU-17 compared from 320 to 800 nm.
ThermoelectricNear infrared
2021 · Solar-driven ionic power generation: Via a film of nanocellulose @ conductive metal-organic framework
Freestanding CCM film · Thin Film · Film floated on water at about 17 C and illuminated under one sun (1 kW m-2); surface temperature and thermal gradient recorded.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2021 · Sulfur vacancies enriched Nickel-Cobalt sulfides hollow spheres with high performance for All-Solid-State hybrid supercapacitor
r-NiCo2S4-6 HSs · Powder · DRS from 200 to 800 nm; band gap determined assuming direct transition n = 2.
SpectroscopyTauc / Kubelka-MunkNear infrared
2021 · The Different Roles of Cobalt and Manganese in Metal-Organic Frameworks for Supercapacitors
Co-MOF exfoliated nanosheets · Nanosheet · Exfoliated Co-MOF suspended in water for UV-VIS-NIR; CV on glassy carbon under ambient pressure and N2 atmosphere using Ag/Ag+ reference and ferrocene calibration.
SpectroscopyTauc / Kubelka-MunkNear infrared
2021 · The Different Roles of Cobalt and Manganese in Metal-Organic Frameworks for Supercapacitors
Mn-MOF exfoliated nanosheets · Nanosheet · Exfoliated Mn-MOF suspended in water for UV-VIS-NIR; CV on glassy carbon under ambient pressure and N2 atmosphere using Ag/Ag+ reference and ferrocene calibration.
SpectroscopyTauc / Kubelka-MunkNear infrared
2021 · Truxone-Based Conductive Metal-Organic Frameworks for the Oxygen Reductive Reaction
truxone-Cu MOF powder/nanosheets · Powder · Solid UV/Vis spectra on Perkin-Elmer Lambda 900; liquid UV/Vis on Shimadzu UV-2600 for ligand comparisons.
SpectroscopyNear infrared
2021 · Two-dimensional d-π conjugated metal-organic framework based on hexahydroxytrinaphthylene
as-synthesised Cu3(HHTN)2 dark brown powder · Powder · Absorption spectrum and absorbance-squared versus energy inset used to estimate optical band gap at room temperature.
SpectroscopyDiffuse reflectance
2021 · Ultra-Stable Metal-Organic Framework with Concurrent High Proton Conductivity and Fluorescence Sensing for Nitrobenzene
yellow block single crystals of compound 1 · Single Crystal · room-temperature diffuse reflectance spectrum; BaSO4 reference
SpectroscopyUnspecified subtype
2021 · Uniaxially Oriented Electrically Conductive Metal-Organic Framework Nanosheets Assembled at Air/Liquid Interfaces
HITP-Ni-NS on quartz after five deposition cycles · Thin Film · HITP-Ni-NS and HATP-water-NS on quartz or Si substrates; room temperature.
SpectroscopyNear infrared
2020 · 2D Semiconducting Metal–Organic Framework Thin Films for Organic Spin Valves
Cu3(HHTP)2 thin film on quartz glass · Thin Film · 100 nm Cu3(HHTP)2 thin film; HOMO and LUMO estimated from UPS and optical bandgap.
SpectroscopyUnspecified subtype
2020 · 2D Semiconducting Metal–Organic Framework Thin Films for Organic Spin Valves
Cu3(HHTP)2 thin film on quartz glass · Thin Film · Cu3(HHTP)2 films with different layer-by-layer growth cycle numbers on quartz glass.
SpectroscopyUnspecified subtype
2020 · A conductive metal-organic framework photoanode
Zn2TTFTB powder, standard synthesis · Powder · Zn2TTFTB powder diffuse reflectance compared with H4TTFTB and TDDFT spectra.
SpectroscopyUnspecified subtype
2020 · A highly oriented conductive MOF thin film-based Schottky diode for self-powered light and gas detection
Cu3(C18H6(NH)6)2-x nm thin-film series (x = 40, 60, 80, 100) · Thin Film · UV-vis absorbance spectra of Cu3(C18H6(NH)6)2-x nm films; inset plots 227 nm absorbance versus deposition cycles.
SpectroscopyUnspecified subtype
2020 · A Light-Responsive Metal–Organic Framework Hybrid Membrane with High On/Off Photoswitchable Proton Conductivity
SSP@ZIF-8-10% membrane · Thin Film · SSP@ZIF-8-10% membrane at 298 K during visible-light irradiation.
SpectroscopyUnspecified subtype
2020 · A Light-Responsive Metal–Organic Framework Hybrid Membrane with High On/Off Photoswitchable Proton Conductivity
Synthesised sulfated spiropyran / SSP · Powder · SSP in DI water at 298 K under visible-light irradiation and subsequent dark recovery for 0-30 min.
SpectroscopyUnspecified subtype
2020 · A Nanotubular Metal–Organic Framework with a Narrow Bandgap from Extended Conjugation**
Cu-H8TPPA red solid · Powder · Absorption spectra recorded with Shimadzu 2001 UV spectrophotometer using 1 cm path length cuvette at room temperature.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2020 · A Nanotubular Metal–Organic Framework with a Narrow Bandgap from Extended Conjugation**
GTUB-4 dark red needle-like crystals · Single Crystal · Crystalline-state optical band gap estimated from DRS collected using a Shimadzu 2600 UV-Vis-NIR spectrometer; direct and indirect Tauc plots considered.
SpectroscopyUnspecified subtype
2020 · A Nanotubular Metal–Organic Framework with a Narrow Bandgap from Extended Conjugation**
H8-TPPA free-base porphyrin derivative · Powder · Absorption spectra recorded with Shimadzu 2001 UV spectrophotometer using 1 cm path length cuvette at room temperature.
SpectroscopyUnspecified subtype
2020 · Ag-DNA@ZIF-8 membrane: A proton conductive photoswitch
20 mM Ag-DNA@ZIF-8 · Thin Film · UV-vis spectra of Ag-DNA@ZIF-8 membranes to identify Ag LSPR absorption.
SpectroscopyTauc / Kubelka-Munk
2020 · Application of two Cu(II)-azido based 1D coordination polymers in optoelectronic device: Structural characterization and experimental studies
complex 1 reddish coloured needle crystals · Single Crystal · Electronic spectra recorded from 1500-250 nm on Hitachi U-3501; direct-transition Tauc relation using n = 1/2.
SpectroscopyTauc / Kubelka-Munk
2020 · Application of two Cu(II)-azido based 1D coordination polymers in optoelectronic device: Structural characterization and experimental studies
complex 2 crystalline product · Single Crystal · Electronic spectra recorded from 1500-250 nm on Hitachi U-3501; direct-transition Tauc relation using n = 1/2.
Electrochemistry ApplicationIn situ / operando
2020 · Biporous Cd(II) Coordination Polymer via in Situ Disulfide Bond Formation: Self-Healing and Application to Photosensitive Optoelectronic Device
Bulk/crude material of compound 1 · Powder · Electrolysis in DMF with 0.2 M [N(n-Bu)4]PF6 during disulfide reduction.
SpectroscopyTauc / Kubelka-Munk
2020 · Biporous Cd(II) Coordination Polymer via in Situ Disulfide Bond Formation: Self-Healing and Application to Photosensitive Optoelectronic Device
Spin-coated compound 1 thin film · Thin Film · Thin film of compound 1 prepared by dispersion in DMF on glass plate; spectra in 400-800 nm range.
SpectroscopyUnspecified subtype
2020 · Colloidal crystal engineering with metal–organic framework nanoparticles and DNA
Ag+-stabilized PCN-222 2D superlattice photocatalyst · Powder · Porphyrin leaching quantified from supernatant absorbance compared with isolated catalyst.
SpectroscopyUnspecified subtype
2020 · Colloidal crystal engineering with metal–organic framework nanoparticles and DNA
DNA-PEG5k-functionalised UiO-66 PAEs · Powder · Surface DNA coverage determined using Tamra-labelled DNA; UV-vis measured with Cary 5000 and 1 cm quartz cells.
SpectroscopyTauc / Kubelka-Munk
2020 · Construction of a Succinate-Bridged Cd(II)-Based Two-Dimensional Coordination Polymer for Efficient Optoelectronic Device Fabrication and Explosive Sensing Application
Compound 1 thin film on normal glass for solid-state UV-vis · Thin Film · Solid-state UV-vis spectrum of thin film on glass; 300-700 nm range; direct-transition Tauc exponent n = 1/2.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
Co3(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co0.51Cu2.49)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co0.71Cu2.29)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co1.09Cu1.91)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co1.59Cu1.41)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co1.83Cu1.17)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co2.47Cu0.53)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co0.60Ni2.40)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co1.14Ni1.86)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co1.54Ni1.45)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co1.83Ni1.17)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Co2.38Ni0.62)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
Cu3(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Cu0.50Ni2.50)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Cu1.17Ni1.83)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Cu1.39Ni1.61)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Cu1.63Ni1.37)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
(Cu2.32Ni0.68)(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
Ni3(HITP)2 powder/pellet · Powder · Diffuse reflectance spectra stitched manually with DRIFTS; Kubelka-Munk/Tauc fits used to determine optical band gaps.
SpectroscopyDiffuse reflectance
2020 · Direct Evidence of Photoinduced Charge Transport Mechanism in 2D Conductive Metal Organic Frameworks
Cu-THQ powder · Powder · Solid samples measured by ATR FTIR and Cary 5000 UV-VIS-NIR diffuse reflectance; Cu-THQ, Cu/Zn-THQ and THQ ligand compared, with Zn-THQ diffuse reflectance in SI.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2020 · Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks
HoHHTP powder · Powder · Diffuse reflectance spectra from 350-3000 nm stitched with DRIFTS; Tauc plots for direct allowed transitions.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2020 · Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks
LaHHTP powder · Powder · Diffuse reflectance spectra from 350-3000 nm stitched with DRIFTS; Tauc plots for direct allowed transitions.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2020 · Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks
NdHHTP powder · Powder · Diffuse reflectance spectra from 350-3000 nm stitched with DRIFTS; Tauc plots for direct allowed transitions.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2020 · Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks
YbHHTP powder · Powder · Diffuse reflectance spectra from 350-3000 nm stitched with DRIFTS; Tauc plots for direct allowed transitions.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkIn situ / operando
2020 · Electrical Conductivity in a Porous, Cubic Rare-Earth Catecholate
Y6HOTP2 diffuse-reflectance heating sample · Powder · 300-1200 nm spectra under dinitrogen; sample heated to 90 C for 12 h; spectra approximately every 20 min.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-πInteraction and Efficient Charge-Transport Capabilities
Evacuated [Ag2(HATHCN)(CF3SO3)2]n bulk material · Powder · MOF UV-vis-NIR diffuse-reflectance spectrum; sample mixed with BaSO4 (30% by weight) per SI, with Figure 2b red trace described as MOF film; direct-transition optical band gap from Tauc plot.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-πInteraction and Efficient Charge-Transport Capabilities
Free HATHCN ligand powder/crystals · Powder · Free HATHCN control diffuse-reflectance spectrum; sample mixed with BaSO4 (30% by weight); direct-transition optical band gap from Tauc plot.
SpectroscopyDiffuse reflectanceNear infrared
2020 · Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction
purple crystals of 1 · Single Crystal · Shimadzu UV-3100; ambient air within approx. 10 minutes according to SI.
SpectroscopyDiffuse reflectanceNear infrared
2020 · Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction
black solid 2 from 1 · Powder · Shimadzu UV-3100; ambient air within approx. 10 minutes according to SI.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2020 · Enhancement in electrical conductivity of a porous indium based metal-organic framework upon I2 uptake: Combined experimental and theoretical investigations
I2@1 iodine uptake time-series samples · Powder · Optical band gaps measured for 1 and I2@1 at different iodine uptake times at room temperature.
SpectroscopyUnspecified subtype
2020 · Enhancement in electrical conductivity of a porous indium based metal-organic framework upon I2 uptake: Combined experimental and theoretical investigations
I2@1 - about 10 days · Powder · Iodine release from I2@1 dispersed in cyclohexane monitored at different time intervals.
SpectroscopyNear infrared
2020 · High Thermopower in a Zn-Based 3D Semiconductive Metal-Organic Framework
Zn-HAB drop-cast film on glass · Thin Film · Drop-cast Zn-HAB film on glass measured after drying.
SpectroscopyDiffuse reflectance
2020 · Isoreticular Linker Substitution in Conductive Metal–Organic Frameworks with Through-Space Transport Pathways
Zn activated bulk microcrystalline powder · Powder · MOF powders ground with BaSO4 to 1 wt%; Kubelka-Munk transform normalised to F(R) at 290 nm
SpectroscopyDiffuse reflectance
2020 · M-008: A stable and reusable metalorganic framework with high crystallinity applied in the photocatalytic hydrogen evolution and the degradation of methyl orange
M-008a · Powder · Cary 5000 spectrophotometer with integrating sphere; BaSO4 reference; Kubelka-Munk band gap calculation.
SpectroscopyDiffuse reflectance
2020 · M-008: A stable and reusable metalorganic framework with high crystallinity applied in the photocatalytic hydrogen evolution and the degradation of methyl orange
M-008b · Powder · Cary 5000 spectrophotometer with integrating sphere; BaSO4 reference; Kubelka-Munk band gap calculation.
SpectroscopyUnspecified subtype
2020 · Metal-organic framework nanosheets for enhanced performance of organic photovoltaic cells
dropcast Zn2(ZnTCPP) MON film · Thin Film · Solution spectra in suspension and thin-film spectra on quartz; MON film dropcast from 5 mg/mL suspension and dried.
SpectroscopyNear infrared
2020 · Multifunctional coordination polymers based on copper(i) and mercaptonicotinic ligands: Synthesis, and structural, optical and electrical characterization
CP1 gently crushed powder · Powder · absorption from Kubelka-Munk converted reflectance; emission spectra at room temperature and 77 K, excitation at 400 nm in Fig. 5; lifetime by TCSPC with pulsed NanoLED excitation
SpectroscopyNear infrared
2020 · Multifunctional coordination polymers based on copper(i) and mercaptonicotinic ligands: Synthesis, and structural, optical and electrical characterization
CP2 gently crushed powder · Powder · absorption from Kubelka-Munk converted reflectance; emission spectra at room temperature and 77 K, excitation at 400 nm in Fig. 5; lifetime by TCSPC with pulsed NanoLED excitation
SpectroscopyNear infrared
2020 · Multifunctional coordination polymers based on copper(i) and mercaptonicotinic ligands: Synthesis, and structural, optical and electrical characterization
CP3 gently crushed powder · Powder · absorption from Kubelka-Munk converted reflectance; emission spectra at room temperature and 77 K, excitation at 400 nm in Fig. 5; lifetime by TCSPC with pulsed NanoLED excitation
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2020 · Nanorods of a novel highly conductive 2D metal-organic framework based on perthiolated coronene for thermoelectric conversion
Ni-PTC nanorod dark powder · Powder · Tauc plot of (h nu alpha)^2 versus photon energy for Ni-PTC.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2020 · Paramagnetic Conducting Metal–Organic Frameworks with Three-Dimensional Structure
Co-THBQ well-crystallised powder · Powder · UV-2000 SHIMADZU spectrophotometer at room temperature; sample powder on BaSO4.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2020 · Paramagnetic Conducting Metal–Organic Frameworks with Three-Dimensional Structure
Fe-THBQ black powder · Powder · UV-2000 SHIMADZU spectrophotometer at room temperature; sample powder spread on barium sulfate non-absorbing matrix.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2020 · Paramagnetic Conducting Metal–Organic Frameworks with Three-Dimensional Structure
Mn-THBQ powder · Powder · UV-2000 SHIMADZU spectrophotometer at room temperature; sample powder on BaSO4.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2020 · Phosphonate Metal–Organic Frameworks: A Novel Family of Semiconductors
Hand-picked TUB75 crystals · Single Crystal · Hand-picked TUB75 crystals measured on a Varian Cary 300 UV-Vis spectrophotometer.
SpectroscopyNear infrared
2020 · Semiconducting Supramolecular Organic Frameworks Assembled from a Near-Infrared Fluorescent Macrocyclic Probe and Fullerenes
solution host-guest complex of 2 with C60 · Unknown · 2 at 1 x 10^-6 M against C60 from 0 to 2.8 x 10^-5 M in anhydrous toluene at 298 K; fit at 655 nm.
SpectroscopyNear infrared
2020 · Semiconducting Supramolecular Organic Frameworks Assembled from a Near-Infrared Fluorescent Macrocyclic Probe and Fullerenes
solution host-guest complex of 2 with C70 · Unknown · 2 at 1 x 10^-6 M against C70 from 0 to 5.0 x 10^-5 M in anhydrous toluene at 298 K; fit at 655 nm.
Electrochemistry ApplicationNear infraredIn situ / operando
2020 · Semiconducting Supramolecular Organic Frameworks Assembled from a Near-Infrared Fluorescent Macrocyclic Probe and Fullerenes
receptor 2 in solution · Unknown · Benzonitrile, NBu4PF6 supporting electrolyte; voltage stepped from +0.0 to +1.0 V.
SpectroscopyUnspecified subtype
2020 · Single-Site, Single-Metal-Atom, Heterogeneous Electrocatalyst: Metal–Organic-Framework Supported Molybdenum Sulfide for Redox Mediator-Assisted Hydrogen Evolution Reaction
MoSx-SIM-NDC-SALI/FTO electrode · Electrode · Shimadzu 1601 UV-Vis; decomposed MoSx-SIM-NDC-SALI film used to deduce turnover frequency
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2020 · The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands
1, activated pristine dhMOF · Powder · Optical absorption/band gap analysis for pristine 1; SI: Shimadzu UV-2600 with integrated sphere, 200-1100 nm range; optical band gaps from Tauc plots
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2020 · The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands
1a, iodine-treated washed evacuated dhMOF · Powder · Optical absorption/band gap analysis for iodine-treated 1a; SI: Shimadzu UV-2600 with integrated sphere, 200-1100 nm range; optical band gaps from Tauc plots
SpectroscopyUnspecified subtype
2020 · The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands
Free ExTTFTB ligand · Model · Free ExTTFTB ligand in DMF; SI: Shimadzu UV-2600 with integrated sphere, 200-1100 nm range; optical band gaps from Tauc plots
SpectroscopyDiffuse reflectanceNear infrared
2020 · Tuning Electrical- and Photo-Conductivity by Cation Exchange within a Redox-Active Tetrathiafulvalene-Based Metal–Organic Framework
MV@1 crystals · Single Crystal · Room temperature; PE Lambda 900 UV-vis spectrometer with integrating sphere; BaSO4 reference; 300-2000 nm.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2020 · Tuning Lewis acidity of MIL-88B-Fe with mix-valence coordinatively unsaturated iron centers on ultrathin Ti3C2 nanosheets for efficient photo-Fenton reaction
CUCs-MIL-88B-Fe powder · Powder · DRS-derived Tauc plot in SI Fig. S2a.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2020 · Tuning Lewis acidity of MIL-88B-Fe with mix-valence coordinatively unsaturated iron centers on ultrathin Ti3C2 nanosheets for efficient photo-Fenton reaction
CUCs-MIL-88B-Fe/Ti3C2 powder · Powder · DRS measured by UV-250; Tauc plots from DRS data.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2020 · Tuning Lewis acidity of MIL-88B-Fe with mix-valence coordinatively unsaturated iron centers on ultrathin Ti3C2 nanosheets for efficient photo-Fenton reaction
Ultrathin Ti3C2 nanosheets · Nanosheet · SI Fig. S2b Tauc plot for Ti3C2Tx.
SpectroscopyNear infrared
2020 · Two-Dimensional Conductive Metal-Organic Frameworks Based on Truxene
2,3,7,8,12,13-hexahydroxyl truxene linker · Powder · NMR in DMSO; HRMS MALDI-TOF; liquid UV/Vis on Shimadzu UV-2600; TGA comparison.
SpectroscopyTauc / Kubelka-MunkNear infrared
2020 · Two-Dimensional Conductive Metal-Organic Frameworks Based on Truxene
truxene-Cu cMOF black powder · Powder · Solid UV/Vis recorded by mixing sample with BaSO4 on integration sphere attachment ISR-2600PLUS; Tauc plot used to determine optical band gap.
SpectroscopyUnspecified subtype
2020 · Ultrasensitive Detection of Electrolyte Leakage from Lithium-Ion Batteries by Ionically Conductive Metal-Organic Frameworks
IC-MOF thin film on quartz or silicon wafer · Thin Film · UV-vis spectra of MOF thin films and H2TCPP; later spectra before and after DMC/ethanethiol exposure.
SpectroscopyNear infrared
2020 · Ultrathin two-dimensional conjugated metal-organic framework single-crystalline nanosheets enabled by surfactant-assisted synthesis
HHB-Cu nanosheets · Nanosheet · Raman at ambient conditions; UV/vis on HHB-Cu NSs dispersed on a quartz substrate at room temperature.
SpectroscopyTauc / Kubelka-Munk
2020 · Underpinning the conductivity mechanism in wide bandgap metal organic framework through chemical sensing
50-50 Zn:Co ZIF powder · Powder · Spectra recorded from 200 nm to 800 nm with 1 nm step size for ZIF-8, ZIF-67, and 50-50 mixture.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2020 · Valence-Dependent Electrical Conductivity in a 3D Tetrahydroxyquinone-Based Metal-Organic Framework
FeTHQ as-prepared pressed pellet · Pellet · 0.25 wt% FeTHQ powders ground with KBr and pressed into pellets; spectra collected from 200 to 1800 nm.
SpectroscopyUnspecified subtype
2019 · A Copper Coordination Polymer with Matching Energy Level for Modifying Hole Transport Layers to Improve the Performance of Perovskite Solar Cells
as-prepared Cu-bix pale-yellow crystals · Single Crystal · Solid-sample UV/Vis absorption spectra obtained with BaSO4 baseline correction.
SpectroscopyUnspecified subtype
2019 · A Copper Coordination Polymer with Matching Energy Level for Modifying Hole Transport Layers to Improve the Performance of Perovskite Solar Cells
Cu-bix-doped HTL concentration series · Thin Film · Spiro-OMeTAD with Cu-bix, LiTFSI, or both; solution colour changes used to infer charge transfer/oxidation.
SpectroscopyDiffuse reflectance
2019 · A Copper Coordination Polymer with Matching Energy Level for Modifying Hole Transport Layers to Improve the Performance of Perovskite Solar Cells
optimised Cu-bix-doped PSC · Electrode · HTL reflectance, device absorption and IPCE compared for PSCs with and without Cu-bix doping.
SpectroscopyTauc / Kubelka-Munk
2019 · A highly crystalline anthracene-based MOF-74 series featuring electrical conductivity and luminescence
ANMOF-74(Co) bulk powder · Powder · UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
SpectroscopyTauc / Kubelka-Munk
2019 · A highly crystalline anthracene-based MOF-74 series featuring electrical conductivity and luminescence
ANMOF-74(Mg) bulk powder · Powder · UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
SpectroscopyTauc / Kubelka-Munk
2019 · A highly crystalline anthracene-based MOF-74 series featuring electrical conductivity and luminescence
ANMOF-74(Mn) bulk powder · Powder · UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
SpectroscopyTauc / Kubelka-Munk
2019 · A highly crystalline anthracene-based MOF-74 series featuring electrical conductivity and luminescence
ANMOF-74(Ni) bulk powder · Powder · UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
SpectroscopyTauc / Kubelka-Munk
2019 · A highly crystalline anthracene-based MOF-74 series featuring electrical conductivity and luminescence
ANMOF-74(Zn) bulk powder · Powder · UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
SpectroscopyUnspecified subtype
2019 · A semiconducting layered metal-organic framework magnet
as-synthesised K3Fe2[PcFe-O8] dark black powder · Powder · Powders dispersed in DMF compared with PcFe-OH8 monomer.
SpectroscopyTauc / Kubelka-MunkNear infrared
2019 · Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks
As-synthesised bulk powder of compound 1 · Powder · Powders ground with KBr to 1 wt%; UV-vis-NIR 400-2275 nm, DRIFTS 4200-2000 cm-1; spectra normalised and Tauc fits applied.
SpectroscopyTauc / Kubelka-MunkNear infrared
2019 · Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks
As-synthesised bulk powder of compound 2 · Powder · Powders ground with KBr to 1 wt%; UV-vis-NIR 400-2275 nm, DRIFTS 4200-2000 cm-1; spectra normalised and Tauc fits applied.
SpectroscopyTauc / Kubelka-MunkNear infrared
2019 · Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks
As-synthesised bulk powder of compound 3 · Powder · Powders ground with KBr to 1 wt%; UV-vis-NIR 400-2275 nm, DRIFTS 4200-2000 cm-1; spectra normalised and Tauc fits applied.
SpectroscopyUnspecified subtype
2019 · Efficient MOF-Sensitized Solar Cells Featuring Solvothermally Grown [100]-Oriented Pillared Porphyrin Framework-11 Films on ZnO/FTO Surfaces
C60-doped PPF-11 crystals · Powder · Known C60-doped PPF-11 soaked in hot toluene; washes analysed by Lambert-Beer law
SpectroscopyDiffuse reflectance
2019 · Efficient MOF-Sensitized Solar Cells Featuring Solvothermally Grown [100]-Oriented Pillared Porphyrin Framework-11 Films on ZnO/FTO Surfaces
C60-doped PPF-11 crystals · Powder · Shimadzu UV-2600 integrated sphere; undoped and C60-doped PPF-11
SpectroscopyUnspecified subtype
2019 · Efficient MOF-Sensitized Solar Cells Featuring Solvothermally Grown [100]-Oriented Pillared Porphyrin Framework-11 Films on ZnO/FTO Surfaces
[100]-oriented PPF-11 film on TCPP-coated ZnO-FTO · Electrode · Shimadzu UV-2600; solid films
Electrical TransportIn situ / operando
2019 · Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal-Organic Framework Thin Film
UU-100(Co)|FTO thin-film electrode · Electrode · DMF containing 0.1 M LiClO4; potential switched between -1.50 V and -0.05 V; absorbance monitored at 520 and 670 nm.
SpectroscopyTauc / Kubelka-Munk
2019 · Enhancement of Electrical Conductivity due to Structural Distortion from Linear to Nonlinear Dicarboxylato-Bridged Zn(II) 1D-Coordination Polymers
Compound 1 ITO/compound/Al Schottky thin-film device · Thin Film · Solid-state electronic absorption spectra on PerkinElmer LAMBDA 25; optical characterisation with Shimadzu 2401 PC UV-vis over 250-800 nm; Tauc and Kubelka-Munk analyses reported.
SpectroscopyTauc / Kubelka-Munk
2019 · Enhancement of Electrical Conductivity due to Structural Distortion from Linear to Nonlinear Dicarboxylato-Bridged Zn(II) 1D-Coordination Polymers
Compound 2 ITO/compound/Al Schottky thin-film device · Thin Film · Solid-state electronic absorption spectra on PerkinElmer LAMBDA 25; optical characterisation with Shimadzu 2401 PC UV-vis over 250-800 nm; Tauc and Kubelka-Munk analyses reported.
SpectroscopyUnspecified subtype
2019 · From Low-to High-Crystallinity Bimetal-Organic Framework Nanosheet with Highly Exposed Boundaries: An Efficient and Stable Electrocatalyst for Oxygen Evolution Reaction
(U+S)-CoFe-MOF hierarchical nanosheets · Nanosheet · Mechanistic comparison before/after solvothermal treatment, ligand/metal dissolution and surface electronic states.
SpectroscopyUnspecified subtype
2019 · Highly Electroconductive Metal-Organic Framework: Tunable by Metal Ion Sorption Quantity
TMU-60-Cd powder · Powder · TMU-60 in water and immersed TMU-60 in 100 ppm Cd(II) aqueous solution.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2019 · Integration of a (–Cu–S–) n plane in a metal–organic framework affords high electrical conductivity
As-synthesised brown rod-shaped crystals of compound 1 · Single Crystal · Perkin-Elmer Lambda 750 UV-vis; finely powdered MOF sample; BaSO4 reference; indirect bandgap from ([F(R) x hv])^0.5 vs hv extrapolation.
SpectroscopyUnspecified subtype
2019 · Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance
Synthesised In10 MOF powder · Powder · Solid-state UV-vis absorption and diffuse reflectance measured on Shimadzu UV-2250; steady-state PL measured through FLS920.
SpectroscopyDiffuse reflectance
2019 · Metal organic framework doped Spiro-OMeTAD with increased conductivity for improving perovskite solar cell performance
HTM/In10-4 film · Thin Film · Liquid UV-vis for HTM/In10 solutions and solid-state UV-vis diffuse reflectance/absorption for HTM/In10 based films.
SpectroscopyUnspecified subtype
2019 · Metal-Organic Framework Photoconductivity via Time-Resolved Terahertz Spectroscopy
Zn2TTFTB thin film on FTO · Thin Film · Thin film on FTO used to calculate 400 nm optical penetration length for photoconductivity analysis.
SpectroscopyUnspecified subtype
2019 · Metal-Organic Framework Photoconductivity via Time-Resolved Terahertz Spectroscopy
As-synthesised Zn2TTFTB powder · Powder · As-synthesised dark maroon powder measured with a Shimadzu UV-2600 integrating sphere setup.
SpectroscopyTauc / Kubelka-Munk
2019 · Novel semiconducting iron–quinizarin metal–organic framework for application in supercapacitors*
as-synthesised FeQ black precipitate / powder with small crystals · Powder · Finely powdered material compressed between quartz disks; 200-1000 nm, 3000 nm min^-1 scan rate, 0.5 nm intervals, 0.1 s average time; F(R) used analogously to absorbance due to scattering
SpectroscopyUnspecified subtype
2019 · Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional MetalOrganic Frameworks
Co-CAT-1 thin film on quartz · Thin Film · Transmission UV-vis/NIR with integrating sphere on quartz films; PL with 378 nm excitation.
SpectroscopyUnspecified subtype
2019 · Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional MetalOrganic Frameworks
Ni-CAT-1 thin film on quartz · Thin Film · Transmission UV-vis/NIR with integrating sphere on quartz films; PL with 378 nm excitation.
SpectroscopyNear infrared
2019 · Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers
PMC-1 bulk powder/crystals · Powder · Shimadzu UV-3100; KBr pellets also used in IR spectroscopy.
SpectroscopyDiffuse reflectance
2019 · Redox-Active 1D Coordination Polymers of Iron-Sulfur Clusters
Compound 1 as-synthesized black powder · Powder · Solid compound 1 ground with MgSO4 for diffuse reflectance
SpectroscopyDiffuse reflectance
2019 · Redox-Active 1D Coordination Polymers of Iron-Sulfur Clusters
Compound 2 as-synthesized black powder · Powder · Solid compound 2 diffuse reflectance and DMF solution absorbance
SpectroscopyUnspecified subtype
2019 · Self-assembly and optoelectronic properties of isoreticular MOF nanocrystals
2,6-NDC ligand solution · Model · 2,6-NDC ligand in solution for comparison with microstructures.
SpectroscopyUnspecified subtype
2019 · Self-assembly and optoelectronic properties of isoreticular MOF nanocrystals
2,6-NDC ligand thin film · Model · Ligand thin film for absorption and band-gap comparison.
SpectroscopyUnspecified subtype
2019 · Self-assembly and optoelectronic properties of isoreticular MOF nanocrystals
IRMOF-8 microstructures in ethanol solution · Unknown · Microstructures in ethanol solution.
SpectroscopyUnspecified subtype
2019 · Self-assembly and optoelectronic properties of isoreticular MOF nanocrystals
spin-coated IRMOF-8 microstructure thin film for UV-vis · Thin Film · Spin-coated microstructure thin film; band gap calculated from absorption onset.
SpectroscopyTauc / Kubelka-Munk
2019 · Synthesis, Crystal Structure, and Photocatalytic Properties of a Zinc(II) Coordination Polymer Based on 3-Hydroxy-2-pyridinecarboxylic Acid
Complex 1 bulk crystalline product · Powder · UV/Vis spectrophotometer (Puxi UV 1901), BaSO4 reflectance standard, room temperature; absorption data converted using the Kubelka-Munk function.
SpectroscopyTauc / Kubelka-Munk
2019 · Three-Dimensional-Coordination Polymer of Zn(II)-Carboxylate: Structural Elucidation, Photoelectrical Conductivity, and Biological Activity
compound 1 thin-film Schottky diode · Thin Film · Thin film; UV-vis absorption spectrum 250-900 nm; direct-transition Tauc plot with n = 1/2.
SpectroscopyTauc / Kubelka-Munk
2019 · Three-Dimensional-Coordination Polymer of Zn(II)-Carboxylate: Structural Elucidation, Photoelectrical Conductivity, and Biological Activity
ppmh ligand thin-film Schottky diode · Thin Film · Thin film; UV-vis absorption spectrum 250-900 nm; direct-transition Tauc plot with n = 1/2.
SpectroscopyNear infrared
2019 · Tunable electrical conductivity of a new 3D MOFs: Cu-TATAB
TCNQ@Cu-TATAB dark crystals · Single Crystal · Compared Cu-TATAB, H3TATAB, TCNQ@Cu-TATAB and TCNQ.
SpectroscopyNear infrared
2018 · A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior
black polycrystalline PTC-Fe 2D MOF powder/crystals · Powder · Solid-state UV-Vis spectrum measured at room temperature.
SpectroscopyTauc / Kubelka-MunkNear infrared
2018 · A new semiconducting coordination polymer consisting of copper(I)-iodide and 3-pyridinecarboxaldehyde
Pelletised 1/MgO mixture for diffuse-reflectance spectroscopy · Pellet · Pelletised mixture containing 1 (0.01 mmol) and MgO powder (80 mg); reflectance converted using f(R) = (1 - R)^2/2R; band gap from (f(R)*E)^1/2 vs E.
SpectroscopyIn situ / operando
2018 · Development of a UiO-Type Thin Film Electrocatalysis Platform with Redox-Active Linkers
Zr(dcphOH-NDI)@FTO thin film · Thin Film · Thin film in 10 mm quartz cuvette with Pt counter electrode and Ag/AgNO3 reference; 0.8 M KPF6 or n-Bu4NPF6 in DMF; potentials vs Fc+/0.
SpectroscopyTauc / Kubelka-Munk
2018 · Effect on Schottky behaviour of 1D coordination polymers by altering para-substituents on benzoate ligands
Compound 1 yellow block crystals · Single Crystal · Absorbance measured with PerkinElmer LAMBDA 35; direct and indirect optical transitions evaluated.
SpectroscopyTauc / Kubelka-Munk
2018 · Effect on Schottky behaviour of 1D coordination polymers by altering para-substituents on benzoate ligands
Compound 2 yellow block crystals · Single Crystal · Absorbance measured with PerkinElmer LAMBDA 35; direct and indirect optical transitions evaluated.
SpectroscopyDiffuse reflectance
2018 · Electron delocalization and charge mobility as a function of reduction in a metal-organic framework
Bulk KxFe2(BDP)3 powder series · Powder · CARY 5000 spectrophotometer; Praying Mantis air-free diffuse reflectance cell; Kubelka-Munk transform.
SpectroscopyUnspecified subtype
2018 · Fabrication of an Active Electronic Device Using a Hetero-bimetallic Coordination Polymer
Powdered/bulk [(NCS)Pb(H2O)LNi(NCS)]n · Powder · PerkinElmer Spectrum Two IR, Lambda 35 UV-vis, Shimadzu RF-5301PC fluorescence, Hamamatsu MCP photomultiplier for lifetime.
SpectroscopyTauc / Kubelka-Munk
2018 · Fabrication of an Active Electronic Device Using a Hetero-bimetallic Coordination Polymer
ITO/[(NCS)Pb(H2O)LNi(NCS)]n/Al thin-film Schottky device · Thin Film · Absorption spectrum of deposited thin film prepared as a DMF dispersion, 200-1000 nm; direct band gap from (alpha h nu)^2 versus h nu.
SpectroscopyUnspecified subtype
2018 · Fabrication of an Active Electronic Device Using a Hetero-bimetallic Coordination Polymer
Powdered/bulk [(NCS)Pb(H2O)LNi(NCS)]n · Powder · PerkinElmer Lambda 35 UV-visible spectrophotometer; room temperature.
SpectroscopyTauc / Kubelka-Munk
2018 · High-mobility band-like charge transport in a semiconducting two-dimensional metal–organic framework
Large-area free-standing Fe3(THT)2(NH4)3 multilayer film · Thin Film · Optical transmission/absorption used to estimate direct bandgap and below-gap tail.
SpectroscopyUnspecified subtype
2018 · In situ growth of ultrathin Co-MOF nanosheets on Α-Fe2O3 hematite nanorods for efficient photoelectrochemical water oxidation
Fe2O3@Co-MOF varied Co/MIm ratio series · Electrode · Supplemental UV-vis absorbance spectra for bare hematite and Fe2O3@0.1Co@0.4/0.8/1.6MIm ratio series.
SpectroscopyUnspecified subtype
2018 · In situ growth of ultrathin Co-MOF nanosheets on Α-Fe2O3 hematite nanorods for efficient photoelectrochemical water oxidation
Fe2O3@Co-MOF varied Co/MIm ratio series · Electrode · Optical absorption of surface-modified alpha-Fe2O3 films; BaSO4 reference.
SpectroscopyUnspecified subtype
2018 · Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests
NiCB@NU-1000 powder · Powder · CV of NiCB and TBAPy solutions converted to NHE by adding 0.21 V; UV-vis absorption used for TBAPy band gap; NU-1000 values from previous electrochemically addressable thin-film and diffuse-reflectance estimates.
SpectroscopyUnspecified subtype
2018 · Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests
NiCB@NU-1000 powder · Powder · Emission excited at 380 nm and monitored 400-700 nm; diffuse reflectance UV-vis collected from 1600 to 360 nm using PTFE baseline.
SpectroscopyUnspecified subtype
2018 · Mithrene is a self-assembling robustly blue luminescent metal-organic chalcogenolate assembly for 2d optoelectronic applications
Mithrene concentration and growth-time screening samples · Thin Film · Crystal suspensions in isopropyl alcohol for UV-vis/PL; isolated crystals on glass coverslips imaged with 405 nm laser excitation, 400-700 nm emission collected in 10 nm bins.
SpectroscopyDiffuse reflectance
2018 · Nanopore-induced host-guest charge transfer phenomena in a metal-organic framework
TTF plus AQDC reaction residue · Powder · Reaction residues from AQDC plus donor molecules compared with guest-impregnated Mn-MOF samples.
SpectroscopyDiffuse reflectanceNear infrared
2018 · Nanopore-induced host-guest charge transfer phenomena in a metal-organic framework
Compound 1 Mn-MOF 5TTF crystals · Single Crystal · Mn-MOF, donor molecules and guest-loaded crystals measured from 200-1400 nm; guest crystals mixed with BaSO4 1:10 by weight.
Computational ModellingUnspecified subtype
2018 · Polyethenetetrathiolate or polytetrathiooxalate? Improved synthesis, a comparative analysis of a prominent thermoelectric polymer and implications to the charge transport mechanism
Ni(dmid)2(2-) TD-DFT model · Model · TD-DFT spectrum for Ni(dmid)2(2-) in NMF used to assign ligand-to-ligand electron transfer band.
SpectroscopyNear infrared
2018 · Polyethenetetrathiolate or polytetrathiooxalate? Improved synthesis, a comparative analysis of a prominent thermoelectric polymer and implications to the charge transport mechanism
P1 poly[Kx(Ni-ett)] · Pellet · Very dilute NMF solutions, 200-2400 nm, Varian Cary 5000; pristine and vapour-treated spectra discussed.
SpectroscopyNear infrared
2018 · Polyethenetetrathiolate or polytetrathiooxalate? Improved synthesis, a comparative analysis of a prominent thermoelectric polymer and implications to the charge transport mechanism
P3 poly[Ni-tto] · Pellet · Very dilute NMF solutions, 200-2400 nm, Varian Cary 5000; pristine and vapour-treated spectra discussed.
SpectroscopyNear infrared
2018 · Stabilization of Hexaaminobenzene in a 2D Conductive Metal-Organic Framework for High Power Sodium Storage
Drop-cast Co-HAB film on quartz · Thin Film · As-synthesised Co-HAB dispersed in water, drop-cast on quartz and measured after water evaporation on CARY 6000i.
SpectroscopyTauc / Kubelka-Munk
2018 · Synthesis of a Cd(ii) based 1D coordination polymer by: In situ ligand generation and fabrication of a photosensitive electronic device
Yellow needle crystals / bulk compound 1 · Single Crystal · Absorption spectrum measured in DMF medium over 300-800 nm.
SpectroscopyNear infrared
2018 · Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal-Organic Framework
Cu-HHB H2O 60 C post-treated powder · Powder · Absorption spectra taken on a CARY 6000i; PESA measured with Riken AC-2; Cu-HHB powder dispersed/spray-coated for optical spectra according to SI instrumentation.
SpectroscopyUnspecified subtype
2018 · Tarnishing Silver Metal into Mithrene
[AgSePh]inf thin films on glass coverslips · Thin Film · Absorption spectra of glass-supported films before and after 3 days tarnishing; Ag precursor thicknesses 1-10 nm
SpectroscopyDiffuse reflectance
2018 · Tarnishing Silver Metal into Mithrene
[AgSePh]inf film from 100 nm Ag on silicon under humidity variants · Thin Film · Diffuse reflectance spectra of control, dry, room-air, and air-plus-water tarnishing experiments on silicon-supported 100 nm Ag films
SpectroscopyTauc / Kubelka-Munk
2018 · Two isostructural linear coordination polymers: The size of the metal ion impacts the electrical conductivity
compound 2 solid-state UV-vis film on glass · Thin Film · UV-vis spectra recorded from 250-550 nm; direct band gap estimated using n = 1/2.
SpectroscopyTauc / Kubelka-Munk
2018 · Two isostructural linear coordination polymers: The size of the metal ion impacts the electrical conductivity
compound 1 solid-state UV-vis film on glass · Thin Film · UV-vis spectra recorded from 250-550 nm; direct band gap estimated using n = 1/2.
SpectroscopyTauc / Kubelka-Munk
2017 · Cation dependent charge transport in linear dicarboxylate based isotypical 1D coordination polymers
powdered compound 1 · Powder · Shimadzu 2401 PC UV-vis spectrophotometer, 250-800 nm; direct optical band gap from (alpha h nu)^2 versus h nu.
SpectroscopyTauc / Kubelka-Munk
2017 · Cation dependent charge transport in linear dicarboxylate based isotypical 1D coordination polymers
powdered compound 2 · Powder · Shimadzu 2401 PC UV-vis spectrophotometer, 250-800 nm; direct optical band gap from (alpha h nu)^2 versus h nu.
SpectroscopyUnspecified subtype
2017 · Colossal Increase in Electric Current and High Rectification Ratio in a Photoconducting, Self-Cleaning, and Luminescent Schottky Barrier NMOF Diode
NMOF-1 bulk nanosheets/powder · Nanosheet · THF dispersion and solid-state emission/absorption measurements
SpectroscopyUnspecified subtype
2017 · Defects as Color Centers: The Apparent Color of Metal-Organic Frameworks Containing Cu2+-Based Paddle-Wheel Units
1 mM copper(II) acetate in acetic acid · Unknown · 1 mM copper(II) acetate in acetic acid; pure acetic acid solvent spectrum shown as dotted line.
SpectroscopyUnspecified subtype
2017 · Defects as Color Centers: The Apparent Color of Metal-Organic Frameworks Containing Cu2+-Based Paddle-Wheel Units
high-quality HKUST-1 HQ-SURMOF · Thin Film · High-quality HKUST-1 HQ-SURMOF compared with conventional SURMOF and quartz substrate over 200-1000 nm.
SpectroscopyUnspecified subtype
2017 · Defects as Color Centers: The Apparent Color of Metal-Organic Frameworks Containing Cu2+-Based Paddle-Wheel Units
conventional low-quality HKUST-1 SURMOF · Thin Film · Conventional low-quality HKUST-1 SURMOF compared with HQ-SURMOF and quartz substrate over 200-1000 nm.
SpectroscopyUnspecified subtype
2017 · Defects as Color Centers: The Apparent Color of Metal-Organic Frameworks Containing Cu2+-Based Paddle-Wheel Units
pristine/HQ SURMOF after elevated-temperature exposure series · Thin Film · Pristine SURMOF compared with films exposed to 200 C for 16 h, 200 C for 72 h, 220 C for 24 h, and 250 C for 1 h, plotted from 300-900 nm in SI Figure S3a.
SpectroscopyUnspecified subtype
2017 · Defects as Color Centers: The Apparent Color of Metal-Organic Frameworks Containing Cu2+-Based Paddle-Wheel Units
pristine/HQ SURMOF after 10 min water vapour exposure for UV-vis · Thin Film · Pristine SURMOF before and after water vapour exposure for 10 min, plotted from 300-900 nm in SI Figure S3b.
PorosityUnspecified subtype
2017 · Direct Observation of Confined I−⋅⋅⋅I2⋅⋅⋅I− Interactions in a Metal–Organic Framework: Iodine Capture and Sensing
I2@1 iodine-loaded crystals · Single Crystal · I2 incorporation after saturated I2/cyclohexane soaking; kinetic curve used 0.174 mg/mL I2/cyclohexane solution.
SpectroscopyTauc / Kubelka-Munk
2017 · Direct Observation of Confined I−⋅⋅⋅I2⋅⋅⋅I− Interactions in a Metal–Organic Framework: Iodine Capture and Sensing
I2@1 iodine-loaded crystals · Single Crystal · UV-Vis-NIR spectra measured using BaSO4 reflectance reference; absorption spectra calculated by Kubelka-Munk function; 1 and I2@1 compared.
Electrochemistry ApplicationUnspecified subtype
2017 · Efficient and Selective Uptake of TcO4- by a Cationic Metal-Organic Framework Material with Open Ag+ Sites
SCU-100 crystals · Single Crystal · 50 mg SCU-100 added to 50 mL of 28 ppm TcO4- solution; 25 C batch method; UV-vis peak at 290 nm and 99Tc LSC used.
SpectroscopyDiffuse reflectance
2017 · Efficient hydrogen production from MIL-53(Fe) catalyst-modified Mo: BiVO4 photoelectrodes
FMBV-2 / 2% Mo:BiVO4-MIL-53(Fe) · Electrode · BaSO4 reference; 2% Mo:BiVO4, MIL-53(Fe) and FMBV samples compared.
SpectroscopyUnspecified subtype
2017 · Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework
NDI-py ligand · Powder · Molar absorption coefficients calculated at 380, 360, 341 and 324 nm in the 0.2-0.8 absorptivity window.
SpectroscopyDiffuse reflectance
2017 · Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework
MOF-CoNDI-py-2 purple leaf-like crystals/powder · Single Crystal · Vis-NIR 350-2500 nm and UV-Vis 250-800 nm, MgO reference.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2017 · Fluorescent metal-organic frameworks for selective sensing of toxic cations (Tl3+, Hg2+) and highly oxidizing anions ((CrO4)2−, (Cr2O7)2−, (MnO4)−)
compound I yellow platelike crystals · Single Crystal · Optical band gap from [F(R) x hnu]^(1/2) versus hnu Tauc plot.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2017 · Fluorescent metal-organic frameworks for selective sensing of toxic cations (Tl3+, Hg2+) and highly oxidizing anions ((CrO4)2−, (Cr2O7)2−, (MnO4)−)
compound II yellow needlelike crystals · Single Crystal · Optical band gap from [F(R) x hnu]^(1/2) versus hnu Tauc plot.
SpectroscopyTauc / Kubelka-Munk
2017 · Giant Enhancement of Carrier Mobility in Bimetallic Coordination Polymers
Fe-BTC-Cr 1:1 xerogel pressed pellet · Pellet · Solid-state UV-vis spectra measured from 250-800 nm and converted using Kubelka-Munk function; band gaps estimated from Tauc plots.
SpectroscopyUnspecified subtype
2017 · Hybrid metal-organic chalcogenide nanowires with electrically conductive inorganic core through diamondoid-directed assembly
As-synthesised 1ADCu needle-shaped crystals · Single Crystal · Ethanolic suspension drop-cast on sapphire and measured against white diffuse reflectance background.
Sensing ApplicationUnspecified subtype
2017 · Hydrolytically Stable Luminescent Cationic Metal Organic Framework for Highly Sensitive and Selective Sensing of Chromate Anions in Natural Water Systems
finely ground powder of 1 · Powder · Kinetics: 150 mg powder in 60 mL of 1 ppm K2Cr2O7; filtered with 0.22 um nylon membrane and monitored by ICP-MS. Isotherm: 12 mg powder in 6 mL K2Cr2O7 solutions from 0.2 to 300 ppm, stirred 24 h, monitored by UV-vis at CrO4^2- absorption near 350 nm.
SpectroscopyUnspecified subtype
2017 · Hydrolytically Stable Luminescent Cationic Metal Organic Framework for Highly Sensitive and Selective Sensing of Chromate Anions in Natural Water Systems
finely ground powder of 1 · Powder · Excitation at 280 nm; Eu3+ emissions monitored at 592, 616, 653 and 696 nm. UV-vis absorption spectra of 1 and Cr(VI) compared.
SpectroscopyTauc / Kubelka-Munk
2017 · Intercatenated Coordination Polymers (ICPs) of Carboxylato Bridged Zn(II)-Isoniazid and Their Electrical Conductivity
ITO/1/Al Schottky thin-film device · Thin Film · Thin films of 1, 2, and 3 prepared from well-dispersed DMSO solutions; Shimadzu 2401 PC, 200-900 nm.
Microscopy MorphologyUnspecified subtype
2017 · Layer-by-Layer Assembled Conductive Metal–Organic Framework Nanofilms for Room-Temperature Chemiresistive Sensing
Cu3(HHTP)2-xC layer-by-layer thin-film series · Thin Film · Cycle-dependent film morphology and thickness characterised for Cu3(HHTP)2-xC.
SpectroscopyNear infrared
2017 · Lowering Band Gap of an Electroactive Metal-Organic Framework via Complementary Guest Intercalation
DSNDI ligand reference · Unknown · Ligand reference spectrum; optical band gap determined from onset of longest-wavelength absorption.
SpectroscopyNear infrared
2017 · Lowering Band Gap of an Electroactive Metal-Organic Framework via Complementary Guest Intercalation
Activated DSNDI-based MOF-74 powder · Powder · UV-vis-NIR spectra of MOF-74 in absence of TTF guests; optical band gap from absorption onset.
SpectroscopyNear infrared
2017 · Lowering Band Gap of an Electroactive Metal-Organic Framework via Complementary Guest Intercalation
TTF-doped DSNDI-based MOF-74 powder · Powder · MOF-74 after soaking in TTF solution for 2 days; new charge-transfer band used to estimate optical band gap.
SpectroscopyUnspecified subtype
2017 · Novel Solid-State Solar Cell Based on Hole-Conducting MOF-Sensitizer Demonstrating Power Conversion Efficiency of 2.1%
Co-DAPV film on glass · Thin Film · Optical absorption spectrum of Co-DAPV film on glass; comparison of aqueous CoCl2.6H2O and DAPV precursor solutions.
SpectroscopyUnspecified subtype
2017 · Novel Solid-State Solar Cell Based on Hole-Conducting MOF-Sensitizer Demonstrating Power Conversion Efficiency of 2.1%
2000 rpm TiO2/Co-DAPV device series, 5-30 LbL cycles · Electrode · About 500 nm mesoporous TiO2 films on FTO sensitized with Co-DAPV for 0, 5, 10, 15, 20, or 30 LbL cycles.
SpectroscopyTauc / Kubelka-Munk
2017 · Synthesis and structural characterization of a Cu(II)-based 1D coordination polymer and its application in Schottky devices
as-synthesised compound 1 bulk crystals/powder · Powder · Shimadzu 2401 PC UV-Vis spectrophotometer; well-dispersed material in DMF; absorption recorded over 200-900 nm.
SpectroscopyNear infrared
2017 · Synthesis of ordered carbonaceous frameworks from organic crystals
Ni2-CPDPy873(1) · Powder · Raman at 532.2 nm; absorption from 0.04949 to 4.959 eV.
SpectroscopyUnspecified subtype
2017 · TCNQ-doped Cu-metal organic framework as a novel conductometric immunosensing platform for the quantification of prostate cancer antigen
antibody-TCNQ-Cu3(BTC)2-SPE · Electrode · Cu3(BTC)2, TCNQ, and antibody-TCNQ-Cu3(BTC)2 samples prepared as thin films under hydraulic pressure.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2016 · Coordination environments and π-conjugation in dense lithium coordination polymers
Compound 1 pale yellow plates · Single Crystal · PerkinElmer Lambda 750 with integrating sphere, 2500 to 220 nm; powder diluted 5-20 wt% with dry BaSO4
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2016 · Coordination environments and π-conjugation in dense lithium coordination polymers
Compounds 3-6 hydroxy-aq LCP diffuse-reflectance group · Powder · PerkinElmer Lambda 750 with integrating sphere, 2500 to 220 nm; powders diluted 5-20 wt% with dry BaSO4
SpectroscopyNear infrared
2016 · Modulating the electrical conductivity of metal-organic framework films with intercalated guest π-systems
MV2+-loaded BMOF film · Thin Film · BMOF/ZnO film before and after MV2+ doping
Electrochemistry ApplicationUnspecified subtype
2015 · A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution
NU-1000_Ni-S · Electrode · Aqueous HCl pH 1; 10 mA cm-2 for 2 h; PXRD before/after; electrolyte UV-vis after catalysis.
SpectroscopyUnspecified subtype
2015 · A two-dimensional π-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour
60 nm Cu-BHT film · Thin Film · CIMPS system with balanced tungsten-deuterium light source from 220 to 1100 nm; blank glass substrate reference; same film as sheet-resistance measurement.
SpectroscopyUnspecified subtype
2015 · Charge Transfer-Induced Molecular Hole Doping into Thin Film of Metal-Organic Frameworks
Iodine plus naphthalene dicarboxylic acid model · Model · I2, undoped Co3(NDC)3, iodine-doped Co3(NDC)3, and iodine/NDC saturated suspensions in chloroform.
SpectroscopyUnspecified subtype
2015 · Charge Transfer-Induced Molecular Hole Doping into Thin Film of Metal-Organic Frameworks
Iodine-doped Co3(NDC)3 LbL film on glass · Thin Film · Co3(NDC)3 LbL and DB films before and after iodine doping; iodine/acetonitrile solution comparison in SI.
SpectroscopyUnspecified subtype
2015 · Confinement of single polysilane chains in coordination nanospaces
PMPrS extracted from UV-irradiated 1a-PMPrS · Unknown · 1-PMPrS and bulk PMPrS irradiated under air with 500 W mercury lamp, 300-400 nm, 24 h at room temperature; spectra of extracted PMPrS recorded in hexane.
SpectroscopyUnspecified subtype
2015 · Effect of solvent on the perovskite thin film morphology and crystallinity
unannealed DMF-derived PbI2-MAI-DMF layered MOF film · Thin Film · DMF-derived unannealed and 100 C annealed films compared; samples prepared in glovebox, sealed, and tested within 10 min.
SpectroscopyUnspecified subtype
2015 · Effect of solvent on the perovskite thin film morphology and crystallinity
GBL-derived MAPbI3 film on mesoporous TiO2 · Thin Film · GBL-derived annealed film; samples prepared in glovebox, sealed, and tested within 10 min.
SpectroscopyDiffuse reflectanceNear infrared
2015 · Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework
Microcrystalline/crystalline powder of 1 · Powder · CARY 5000 spectrophotometer; Praying Mantis air-free diffuse reflectance cell; PVDF matrix; Kubelka-Munk F(R) conversion.
Electrochemistry ApplicationUnspecified subtype
2015 · Facile interfacial charge transfer across hole doped cobalt-based MOFs/TiO2 nano-hybrids making MOFs light harvesting active layers in solar cells
Iodine-treated Co-NDC LBL film on amine-functionalised glass · Thin Film · Hole-doped Co-BDC and Co-NDC frameworks; supporting figures cited as Fig. S1 and Fig. S2.
SpectroscopyUnspecified subtype
2015 · Facile interfacial charge transfer across hole doped cobalt-based MOFs/TiO2 nano-hybrids making MOFs light harvesting active layers in solar cells
Iodine-treated Co-NDC LBL film on amine-functionalised glass · Thin Film · Co-BDC and Co-NDC LBL films before and after iodine treatment.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2015 · Highly Polarizable Triiodide Anions (I3-) as Cross-Linkers for Coordination Polymers: Closing the Semiconductive Band Gap
powder sample of compound 1 · Powder · Solid powder finely ground and pressed between two Mylar tapes; sample thickness about 1.0 mm; held against a white background.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2015 · Highly Polarizable Triiodide Anions (I3-) as Cross-Linkers for Coordination Polymers: Closing the Semiconductive Band Gap
powder sample of TCuI · Powder · Powder sample; spectrum b of Figure 3.
SpectroscopyUnspecified subtype
2015 · Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?
Free-base porphyrin ethanol solution control · Unknown
SpectroscopyUnspecified subtype
2015 · Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?
Pd porphyrin ethanol solution control · Unknown
SpectroscopyUnspecified subtype
2015 · Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?
Free-base porphyrin Zn-SURMOF 2 on quartz glass · Thin Film · Agilent Cary 5000 UV-Vis-NIR; films grown on quartz glass; solution controls at 20 uM in ethanol.
SpectroscopyUnspecified subtype
2015 · Synthesis, conductivity, and electromagnetic wave absorption properties of chiral poly Schiff bases and their silver complexes
Complex 1a pressed tablet / dried black powder · Pellet · Series-level UV-vis summary for silver complexes; sample key is representative to keep measurement linked.
SpectroscopyUnspecified subtype
2015 · Synthesis, conductivity, and electromagnetic wave absorption properties of chiral poly Schiff bases and their silver complexes
Polymer 1 pressed tablet / dried gray powder · Pellet · Series-level UV-vis summary for four chiral poly Schiff bases; sample key is representative to keep measurement linked.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2015 · Topochemical conversion of a dense metal-organic framework from a crystalline insulator to an amorphous semiconductor
Compound 3 vacuum-dried black monolith · Unknown · PerkinElmer Lambda 750 with integrating sphere; 2500-220 nm; powders diluted to 10 wt% with dry BaSO4.
SpectroscopyUnspecified subtype
2015 · Tunneling Electrical Connection to the Interior of Metal-Organic Frameworks
AgNC@Rb-CD-MOF from 10 mM AgNO3 · Single Crystal · Blank Rb-CD-MOF crystal compared with same crystal doped using 10 mM AgNO3
SpectroscopyDiffuse reflectance
2014 · Characterization of a copper phosphate triazole metal organic framework material (Cu3PO4(C2N3H 2)2OH) and oxygen evolution studies
As-synthesised Cu3PO4(C2N3H2)2OH blue needle-like crystals · Single Crystal · Diffuse reflectance data recorded with Jasco 650 UV-vis spectrophotometer equipped with integration sphere.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2014 · Dielectric relaxation processes, electronic structure, and band gap engineering of MFU-4-type metal-organic frameworks: Towards a rational design of semiconducting microporous materials
Co-MFU-4 powder heated at 280 C under vacuum · Powder · Room-temperature diffuse reflectance spectra, 300-900 nm, Perkin Elmer lambda 750s spectrometer, Labsphere integrating sphere, Spectralon white standard.
SpectroscopyDiffuse reflectanceTauc / Kubelka-MunkNear infrared
2014 · Dielectric relaxation processes, electronic structure, and band gap engineering of MFU-4-type metal-organic frameworks: Towards a rational design of semiconducting microporous materials
Co-MFU-4 powder heated at 280 C under vacuum · Powder · 850-350 nm under flowing nitrogen; samples kept 90 min at 120 C under N2 before gradual cooling; direct allowed Tauc plots.
SpectroscopyUnspecified subtype
2014 · Pd uptake and H2S sensing by an amphoteric metal-organic framework with a soft core and rigid side arms
BFMOF-1a desolvated/solvent-exchanged crystals · Single Crystal · Emission spectra under 370 nm excitation for BFMOF-1 and BFMOF-1a.
Electrochemistry ApplicationIn situ / operando
2014 · Solvothermal preparation of an electrocatalytic metalloporphyrin MOF thin film and its redox hopping charge-transfer mechanism
CoPIZA/FTO thin film electrode · Electrode · CoPIZA/FTO in 0.1 M LiClO4/DMF; CV before/after CCl4 addition at 100 mV/s; film first reduced to (CoI TCPP)CoPIZA, then CCl4 injected and spectral changes monitored.
Electrochemistry ApplicationUnspecified subtype
2014 · Solvothermal preparation of an electrocatalytic metalloporphyrin MOF thin film and its redox hopping charge-transfer mechanism
CoPIZA/FTO thin film electrode · Electrode · CoPIZA/FTO held at -1.04 V or -1.45 V vs ferrocyanide for 24 h; post-electrolysis SEM and solution spectra assessed film stability.
SpectroscopyUnspecified subtype
2014 · Solvothermal preparation of an electrocatalytic metalloporphyrin MOF thin film and its redox hopping charge-transfer mechanism
CoPIZA/FTO thin film electrode · Electrode · Cary Series UV-vis NIR spectrophotometer; wavelength scanned from 800 to 200 nm, 1.00 nm data interval, 600 nm/min scan rate.
SpectroscopyNear infrared
2014 · Structural, magnetic and electrical properties of one-dimensional tetraamidatodiruthenium compounds
Compound 1 single crystals and microcrystalline powder · Single Crystal · Solid-state diffuse reflectance converted to F(Rinf) by Kubelka-Munk treatment.
SpectroscopyNear infrared
2014 · Structural, magnetic and electrical properties of one-dimensional tetraamidatodiruthenium compounds
Compound 2 crystalline solid / powder · Single Crystal · Solid-state diffuse reflectance converted to F(Rinf) by Kubelka-Munk treatment.
SpectroscopyNear infrared
2014 · Structural, magnetic and electrical properties of one-dimensional tetraamidatodiruthenium compounds
Compound 3 crystalline solid / powder · Single Crystal · Solid-state diffuse reflectance converted to F(Rinf) by Kubelka-Munk treatment.
SpectroscopyNear infrared
2014 · Structural, magnetic and electrical properties of one-dimensional tetraamidatodiruthenium compounds
Compound 4 single crystals and microcrystalline powder · Single Crystal · Solid-state diffuse reflectance converted to F(Rinf) by Kubelka-Munk treatment.
SpectroscopyNear infrared
2014 · Structural, magnetic and electrical properties of one-dimensional tetraamidatodiruthenium compounds
Compound 5 crystalline solid / powder · Single Crystal · Solid-state diffuse reflectance converted to F(Rinf) by Kubelka-Munk treatment.
SpectroscopyNear infrared
2014 · Structural, magnetic and electrical properties of one-dimensional tetraamidatodiruthenium compounds
Compound 6 crystalline solid / powder · Single Crystal · Solid-state diffuse reflectance converted to F(Rinf) by Kubelka-Munk treatment.
SpectroscopyUnspecified subtype
2014 · Tunable electrical conductivity in metal-organic framework thin-film devices
Cu3(BTC)2.xH2O film on borosilicate before and after TCNQ or H4-TCNQ adsorption · Thin Film · Cu3(BTC)2.xH2O films before and after TCNQ or H4-TCNQ adsorption; TCNQ dilute solution reference
Sensing ApplicationUnspecified subtype
2013 · Bi-porous metal-organic framework with hydrophilic and hydrophobic channels: Selective gas sorption and reversible iodine uptake studies
iodine-loaded compound 1' subset nI2 · Pellet · Solution uptake used 3 mL 0.01 M I2 in cyclohexane and 50 mg activated 1' for 1 h; release used 1 mg 1' subset nI2 in 2 mL dry ethanol at room temperature.
SpectroscopyTauc / Kubelka-MunkNear infrared
2013 · Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand
CuII(3,5-Dmpip-dtc)2 in MgO powder · Powder · 0.01 mmol mononuclear CuII(3,5-Dmpip-dtc)2 doped in 80 mg MgO powder; HOMO-LUMO gap estimated from modified Kubelka-Munk plot.
SpectroscopyTauc / Kubelka-MunkNear infrared
2013 · Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand
Complex 1 black single crystals · Single Crystal · 0.01 mmol of 1 doped in 80 mg MgO powder; HOMO-LUMO gap estimated from modified Kubelka-Munk plot.
SpectroscopyNear infrared
2012 · Dye-sensitized solar cells with new one-dimensional halide-bridged Cu(I)-Ni(II) heterometal coordination polymers containing hexamethylene dithiocarbamate ligand
1a/KBr transmission pellet · Pellet · 0.5 umol coordination polymer ground with 50 mg KBr for 5 min and pressed in a 13 mm pellet maker; spectra shown in SI Figure S3.
SpectroscopyNear infrared
2012 · Dye-sensitized solar cells with new one-dimensional halide-bridged Cu(I)-Ni(II) heterometal coordination polymers containing hexamethylene dithiocarbamate ligand
1b/KBr transmission pellet · Pellet · 0.5 umol coordination polymer ground with 50 mg KBr for 5 min and pressed in a 13 mm pellet maker; spectra shown in SI Figure S3.
SpectroscopyNear infrared
2012 · Dye-sensitized solar cells with new one-dimensional halide-bridged Cu(I)-Ni(II) heterometal coordination polymers containing hexamethylene dithiocarbamate ligand
2a/KBr transmission pellet · Pellet · 0.5 umol coordination polymer ground with 50 mg KBr for 5 min and pressed in a 13 mm pellet maker; spectra shown in SI Figure S3.
SpectroscopyNear infrared
2012 · Dye-sensitized solar cells with new one-dimensional halide-bridged Cu(I)-Ni(II) heterometal coordination polymers containing hexamethylene dithiocarbamate ligand
2b/KBr transmission pellet · Pellet · 0.5 umol coordination polymer ground with 50 mg KBr for 5 min and pressed in a 13 mm pellet maker; spectra shown in SI Figure S3.
SpectroscopyTauc / Kubelka-MunkNear infrared
2012 · Dye-sensitized solar cells with new one-dimensional halide-bridged Cu(I)-Ni(II) heterometal coordination polymers containing hexamethylene dithiocarbamate ligand
1a/MgO diffuse-reflectance pellet · Pellet · 0.01 mmol 1a doped in 80 mg MgO powder; U-4100 UV/VIS/NIR spectrophotometer.
SpectroscopyTauc / Kubelka-MunkNear infrared
2012 · Dye-sensitized solar cells with new one-dimensional halide-bridged Cu(I)-Ni(II) heterometal coordination polymers containing hexamethylene dithiocarbamate ligand
1b/MgO diffuse-reflectance pellet · Pellet · 0.01 mmol 1b doped in 80 mg MgO powder; U-4100 UV/VIS/NIR spectrophotometer.
SpectroscopyTauc / Kubelka-MunkNear infrared
2012 · Dye-sensitized solar cells with new one-dimensional halide-bridged Cu(I)-Ni(II) heterometal coordination polymers containing hexamethylene dithiocarbamate ligand
Ni(Hm-dtc)2/MgO diffuse-reflectance pellet · Pellet · 0.01 mmol complex doped in 80 mg MgO powder; U-4100 UV/VIS/NIR spectrophotometer.
SpectroscopyNear infrared
2012 · Stable organic radical stacked by in situ coordination to rare earth cations in MOF materials
La-RPF8 bulk powder/crystals · Powder · Powder absorption spectra recorded from 200 to 900 nm at room temperature and compared with Na2AQDS.
SpectroscopyUnspecified subtype
2012 · Synthesis, characterization and solid state electrical properties of 1-D coordination polymer of the type [CuxNi1-x(dadb) ·yH2O]n
Complex 4 powder / pressed pellet · Powder · UV-visible electronic absorption spectra recorded in solid state as Nujol mulls on UV-1700 PHARMA SPEC.
SpectroscopyUnspecified subtype
2012 · Synthesis, characterization, and solid state electrical conductivity of coordination polymers with copper and zinc
Complex 2 compressed pellet · Pellet · Magnetic susceptibility at room temperature on powdered samples; electronic absorption as Nujol mulls.
SpectroscopyUnspecified subtype
2011 · Synthesis and characterization of a novel kind soluble, conjugated, and fluorescent chelate polymer containing fluorene ring in the backbone: Optical, electrical, and electrochemical properties
poly(3,4-HBA-Cr-FDA) bulk chelate polymer · Powder · Absorption spectra recorded in MeOH at 25 deg C; optical band gaps calculated from absorption edges.
SpectroscopyUnspecified subtype
2010 · 2-Cyano-2-isonitrosoacetamide and its Ag(I) complexes. Silver(I) cyanoximate as a non-electric gas sensor
colourless crystals of compound 1 · Single Crystal · Solutions recorded over 200-1100 nm at 293 K; protonated 1 and anion 1- compared in solvents.
SpectroscopyNear infrared
2010 · Conductivity, doping, and redox chemistry of a microporous dithiolene-based metal-organic framework
Desolvated Cu[Ni(pdt)2] powder · Powder · Diffuse-reflectance spectra for Cu[Ni(pdt)2], I2-doped Cu[Ni(pdt)2], and Cu[Cu(pdt)2].
SpectroscopyUnspecified subtype
2009 · 1-Hydroxybenzotriazole (HOBt) acidity, formation constant with different metals and thermodynamic parameters: Synthesis and characterization of some HOBt metal complexes - Crystal structures of two polymers: [Cu2(H2O)5(OBt)2(μ-OBt)2] · 2H2O · EtOH (1A) and [Cu(μ-OBt)(HOBt)(OBt)(EtOH)] (1B)
[Co(OBt)2(HOBt)2(H2O)2] pressed tablet · Pellet · Supplementary Table IV reports lambda_max values and effective magnetic moment where applicable.
SpectroscopyUnspecified subtype
2009 · 1-Hydroxybenzotriazole (HOBt) acidity, formation constant with different metals and thermodynamic parameters: Synthesis and characterization of some HOBt metal complexes - Crystal structures of two polymers: [Cu2(H2O)5(OBt)2(μ-OBt)2] · 2H2O · EtOH (1A) and [Cu(μ-OBt)(HOBt)(OBt)(EtOH)] (1B)
[Cu(gly)2] . H2O blue control · Powder · Supplementary Table IV reports lambda_max values and effective magnetic moment where applicable.
SpectroscopyUnspecified subtype
2009 · 1-Hydroxybenzotriazole (HOBt) acidity, formation constant with different metals and thermodynamic parameters: Synthesis and characterization of some HOBt metal complexes - Crystal structures of two polymers: [Cu2(H2O)5(OBt)2(μ-OBt)2] · 2H2O · EtOH (1A) and [Cu(μ-OBt)(HOBt)(OBt)(EtOH)] (1B)
[Cu(gly)(OBt)(H2O)] sea-green solid · Powder · Supplementary Table IV reports lambda_max values and effective magnetic moment where applicable.
SpectroscopyUnspecified subtype
2009 · 1-Hydroxybenzotriazole (HOBt) acidity, formation constant with different metals and thermodynamic parameters: Synthesis and characterization of some HOBt metal complexes - Crystal structures of two polymers: [Cu2(H2O)5(OBt)2(μ-OBt)2] · 2H2O · EtOH (1A) and [Cu(μ-OBt)(HOBt)(OBt)(EtOH)] (1B)
[Cu(OBt)2(H2O)2] pressed tablet · Pellet · Supplementary Table IV reports lambda_max values and effective magnetic moment where applicable.
SpectroscopyUnspecified subtype
2009 · 1-Hydroxybenzotriazole (HOBt) acidity, formation constant with different metals and thermodynamic parameters: Synthesis and characterization of some HOBt metal complexes - Crystal structures of two polymers: [Cu2(H2O)5(OBt)2(μ-OBt)2] · 2H2O · EtOH (1A) and [Cu(μ-OBt)(HOBt)(OBt)(EtOH)] (1B)
[Cu(OBt)(H2O)2(Cl)] brown solid · Powder · Supplementary Table IV reports lambda_max values and effective magnetic moment where applicable.
SpectroscopyUnspecified subtype
2009 · 1-Hydroxybenzotriazole (HOBt) acidity, formation constant with different metals and thermodynamic parameters: Synthesis and characterization of some HOBt metal complexes - Crystal structures of two polymers: [Cu2(H2O)5(OBt)2(μ-OBt)2] · 2H2O · EtOH (1A) and [Cu(μ-OBt)(HOBt)(OBt)(EtOH)] (1B)
HOBt solid control · Powder · Supplementary Table IV reports lambda_max values and effective magnetic moment where applicable.
SpectroscopyUnspecified subtype
2009 · 1-Hydroxybenzotriazole (HOBt) acidity, formation constant with different metals and thermodynamic parameters: Synthesis and characterization of some HOBt metal complexes - Crystal structures of two polymers: [Cu2(H2O)5(OBt)2(μ-OBt)2] · 2H2O · EtOH (1A) and [Cu(μ-OBt)(HOBt)(OBt)(EtOH)] (1B)
[Ni(OBt)(Cl)(H2O)2] pressed tablet · Pellet · Supplementary Table IV reports lambda_max values and effective magnetic moment where applicable.
SpectroscopyUnspecified subtype
2009 · Semiconducting neutral microstructures fabricated by coordinative self-assembly of intramolecular charge-transfer tetrathiafulvalene derivatives
compound 1 plus Pb2+ or Zn2+ solution binding samples · Model · Solution UV/Vis Job plots and spectra plus 1H NMR titrations of compound 1 with Pb(ClO4)2 or Zn(ClO4)2; addition of metal salt changed colour from yellow to deep purple.
SpectroscopyUnspecified subtype
2009 · Semiconducting neutral microstructures fabricated by coordinative self-assembly of intramolecular charge-transfer tetrathiafulvalene derivatives
compound 3 plus Pb2+ micro-nest-like structures · Powder · Pb2+ binding to triple-bond compound 3 was compared with compound 1; micro-nest-like structures were observed instead of microwires.
SpectroscopyUnspecified subtype
2009 · Soluble semi-conductive chelate polymers containing Cr(III) in the backbone: Synthesis, characterization, optical, electrochemical, and electrical properties
P-1 as-synthesised polymer · Powder · Perkin Elmer Lambda 25; absorption spectra in methanol at 25 C; optical band gaps calculated from absorption edges
SpectroscopyDiffuse reflectance
2008 · A conducting coordination polymer based on assembled Cu9 cages
compound 1 yellow crystals · Single Crystal · Solid-state UV-vis absorption spectrum measured on compound 1.
OtherUnspecified subtype
2008 · Synthesis and changes of conductivities and thermal stabilities of 4,4′-oxybis [N-(3,4-dihydroxybenzilidene) aniline] chelate polymers
P-3,4-HBA-Cr pristine coordination-polymer solid/pellet · Pellet · 25 °C; DMF/methanol (4/1 v/v) eluent at 0.4 mL/min; calibrated with polystyrene standards.
SpectroscopyUnspecified subtype
2008 · Synthesis and changes of conductivities and thermal stabilities of 4,4′-oxybis [N-(3,4-dihydroxybenzilidene) aniline] chelate polymers
3,4-HBA monomer, pristine pressed pellet/solid · Pellet · Absorption spectra recorded in methanol at 25 °C; optical band gaps calculated from absorption edges in Fig. 4b.
SpectroscopyUnspecified subtype
2008 · Synthesis and changes of conductivities and thermal stabilities of 4,4′-oxybis [N-(3,4-dihydroxybenzilidene) aniline] chelate polymers
P-3,4-HBA-Cr pristine coordination-polymer solid/pellet · Pellet · Absorption spectra recorded in methanol at 25 °C; optical band gaps calculated from absorption edges in Fig. 4b.
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2005 · Semiconductive coordination networks from 2,3,6,7,10,11-hexakis(alkylthio) triphenylenes and bismuth(III) halides: Synthesis, structure-property relations, and solution processing
HMTT.BiCl3 (1) single-crystal structural sample · Single Crystal · Room-temperature solid-state diffuse reflectance; 350-1500 nm; BaSO4 reference; band gap from absorption edge extrapolation
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2005 · Semiconductive coordination networks from 2,3,6,7,10,11-hexakis(alkylthio) triphenylenes and bismuth(III) halides: Synthesis, structure-property relations, and solution processing
HMTT.BiBr3 (2) bulk powder/crystallites · Powder · Room-temperature solid-state diffuse reflectance; band gap from absorption edge extrapolation
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2005 · Semiconductive coordination networks from 2,3,6,7,10,11-hexakis(alkylthio) triphenylenes and bismuth(III) halides: Synthesis, structure-property relations, and solution processing
HMTT.2BiBr3 (3) bulk powder/crystallites · Powder · Room-temperature solid-state diffuse reflectance; band gap from absorption edge extrapolation
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2005 · Semiconductive coordination networks from 2,3,6,7,10,11-hexakis(alkylthio) triphenylenes and bismuth(III) halides: Synthesis, structure-property relations, and solution processing
HETT.2BiBr3 (4) bulk powder/crystallites · Powder · Room-temperature solid-state diffuse reflectance; band gap from absorption edge extrapolation
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2005 · Semiconductive coordination networks from 2,3,6,7,10,11-hexakis(alkylthio) triphenylenes and bismuth(III) halides: Synthesis, structure-property relations, and solution processing
HiPTT.2BiBr3.C7H8 (5) bulk powder/crystallites · Powder · Room-temperature solid-state diffuse reflectance; band gap from absorption edge extrapolation
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2005 · Semiconductive coordination networks from 2,3,6,7,10,11-hexakis(alkylthio) triphenylenes and bismuth(III) halides: Synthesis, structure-property relations, and solution processing
BiBr3 diffuse-reflectance control · Powder · Room-temperature optical absorption spectrum for BiBr3 control
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2005 · Semiconductive coordination networks from 2,3,6,7,10,11-hexakis(alkylthio) triphenylenes and bismuth(III) halides: Synthesis, structure-property relations, and solution processing
BiCl3 diffuse-reflectance control · Powder · Room-temperature optical absorption spectrum for BiCl3 control
SpectroscopyDiffuse reflectanceTauc / Kubelka-Munk
2005 · Semiconductive coordination networks from 2,3,6,7,10,11-hexakis(alkylthio) triphenylenes and bismuth(III) halides: Synthesis, structure-property relations, and solution processing
HMTT organic molecular control · Powder · Room-temperature solid-state diffuse reflectance on organic HMTT control
SpectroscopyUnspecified subtype
2002 · Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers
CoHg(C7H4NS2)4(phen) · Powder · solid product characterization after precipitation
SpectroscopyUnspecified subtype
2002 · Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers
CoHg(C7H4NS2)4(phen)3 · Powder · solid product characterization after precipitation
SpectroscopyUnspecified subtype
2002 · Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers
NiZn(C7H4NS2)4(en) · Powder · solid product characterization after precipitation
SpectroscopyUnspecified subtype
2002 · Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers
NiZn(C7H4NS2)4(en)3 · Powder · solid product characterization after precipitation
SpectroscopyUnspecified subtype
2002 · Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers
NiZn(C7H4NS2)4(phen) · Powder · solid product characterization after precipitation
SpectroscopyUnspecified subtype
2002 · Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers
NiZn(C7H4NS2)4(phen)3 · Powder · solid product characterization after precipitation
SpectroscopyUnspecified subtype
2002 · Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers
NiZn(C7H4NS2)4(py)2 · Powder · solid product characterization after precipitation
SpectroscopyUnspecified subtype
2002 · Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers
all products reported in this paper · Pellet · structure assignment from ligand bands, ring deformation bands, N-H bending, and electronic transitions
SpectroscopyUnspecified subtype
1990 · New coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene
BHPAP ligand crystals · Powder · DMF solution; Unicam SP 800 spectrophotometer.
SpectroscopyUnspecified subtype
1990 · New coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene
Cr-BHPAP polychelate powder · Powder · DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.
SpectroscopyUnspecified subtype
1990 · New coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene
Cu-BHPAP polychelate powder · Powder · DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.
SpectroscopyUnspecified subtype
1990 · New coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene
Fe-BHPAP polychelate powder · Powder · DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.
SpectroscopyUnspecified subtype
1990 · New coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene
Mn-BHPAP polychelate powder · Powder · DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.
SpectroscopyUnspecified subtype
1990 · New coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene
Ni-BHPAP polychelate powder · Powder · DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.
SpectroscopyUnspecified subtype
1990 · New coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene
Ti-BHPAP polychelate powder · Powder · DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.
No mapped measurement matches these filters.