Spectroscopy — Diffusional Electron Transport Coupled to Thermodynamically Driven Electron Transfers in Redox-Conductive Multivariate Metal-Organic Frameworks

Measurement evidence

Spectroscopy

Diffusional Electron Transport Coupled to Thermodynamically Driven Electron Transfers in Redox-Conductive Multivariate Metal-Organic Frameworks · Li J., Kumar A., Ott S. · Journal of the American Chemical Society · 2024 · 12000-12010

1 measurement group · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

operando UV-vis spectroelectrochemistry

Zn(NDI)0.5(PMDI)0.5 thin film on FTO · Thin Film

Slow cathodic CV scan at 10 mV s-1 while collecting UV-vis spectra; five redox states identified.

Context
pristine framework thin film on FTO
Measurement source
12002-12003 · Figure 3; Figure 4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NDI dianion marker418 nmText
Exact Reported
12003 · Figure 4
neutral NDI second absorption band379 nmText
Exact Reported
12002 · Figure 3a
NDI radical anion marker471 nmText
Exact Reported
12003 · Figure 4
NDI radical anion additional absorption bands471, 606, 702, and 779 nmText
Exact Reported
12002 · Figure 3a
neutral NDI pi-pi* absorption360 nmText
Exact Reported
12003 · Figure 4
PMDI dianion marker551 nmText
Exact Reported
12003 · Figure 4
PMDI radical anion marker713 nmText
Exact Reported
12003 · Figure 4