Measurement evidence
Diffusional Electron Transport Coupled to Thermodynamically Driven Electron Transfers in Redox-Conductive Multivariate Metal-Organic Frameworks · Li J., Kumar A., Ott S. · Journal of the American Chemical Society · 2024 · 12000-12010
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Zn(NDI) thin film on FTO · Thin Film
MOF@FTO working electrode; Ar-saturated DMF with 0.1 M KPF6; scan rates 50 mV s-1 in Figure 2 and 10 mV s-1 for integration in SI.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|
Zn(NDI)0.2(PMDI)0.8 thin film on FTO · Thin Film
MOF@FTO working electrode; Ar-saturated DMF with 0.1 M KPF6; scan rates 50 mV s-1 in Figure 2 and 10 mV s-1 for integration in SI.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NDI-associated integrated charge | 1.68 mC | — | — | Figure Axis Approximate | SI p12 · Figure S12 |
| PMDI-associated integrated charge | 2.58 mC | — | — | Figure Axis Approximate | SI p12 · Figure S12 |
Zn(NDI)0.5(PMDI)0.5 thin film on FTO · Thin Film
MOF@FTO working electrode; Ar-saturated DMF with 0.1 M KPF6; scan rates 50 mV s-1 in Figure 2 and 10 mV s-1 for integration in SI.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NDI/NDI radical anion half-wave potential | -0.91 V vs Ag/AgNO3 | — | — | Text Exact Reported | 12002 · Figure 2c |
| NDI radical anion/NDI dianion half-wave potential | -1.29 V vs Ag/AgNO3 | — | — | Text Exact Reported | 12002 · Figure 2c |
| PMDI/PMDI radical anion half-wave potential | -1.13 V vs Ag/AgNO3 | — | — | Text Exact Reported | 12002 · Figure 2c |
| PMDI radical anion/PMDI dianion half-wave potential | -1.65 V vs Ag/AgNO3 | — | — | Text Exact Reported | 12002 · Figure 2c |
| NDI-associated integrated charge | 2.97 mC | — | — | Figure Axis Approximate | SI p11 · Figure S11 |
| PMDI-associated integrated charge | 8.91 mC | — | — | Figure Axis Approximate | SI p11 · Figure S11 |
Zn(NDI)0.8(PMDI)0.2 thin film on FTO · Thin Film
MOF@FTO working electrode; Ar-saturated DMF with 0.1 M KPF6; scan rates 50 mV s-1 in Figure 2 and 10 mV s-1 for integration in SI.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NDI-associated integrated charge | 819 μC | — | — | Figure Axis Approximate | SI p10 · Figure S10 |
| PMDI-associated integrated charge | 185 μC | — | — | Figure Axis Approximate | SI p10 · Figure S10 |
Zn(PMDI) thin film on FTO · Thin Film
MOF@FTO working electrode; Ar-saturated DMF with 0.1 M KPF6; scan rates 50 mV s-1 in Figure 2 and 10 mV s-1 for integration in SI.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|
Zn(NDI)0.5(PMDI)0.5 thin film on FTO · Thin Film
One-second cathodic potential steps from -0.2 V to selected potentials followed by open circuit to 300 s; UV-vis traces monitored at 471, 418, 713, and 551 nm.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| step-potential response at -1.1 V | only NDI radical anion increases | — | — | Text Qualitative | 12004-12005 · Figure 5 |
| step-potential response at -1.3 V | exclusively NDI radical anion observed despite PMDI reduction being thermodynamically feasible | — | — | Text Qualitative | 12004-12005 · Figure 5 |
| step-potential response at -1.5 V | exclusively NDI radical anion observed despite PMDI reduction being thermodynamically feasible | — | — | Text Qualitative | 12004-12005 · Figure 5 |
| step-potential response at -1.7 V | simultaneous NDI radical anion and PMDI radical anion formation | — | — | Text Qualitative | 12004-12005 · Figure 5 |
| step-potential response at -1.9 V | slow NDI radical anion formation extends for almost 10 s after fast radical formation | — | — | Text Qualitative | 12004-12005 · Figure 5 |