Spectroscopy — Flexible conductive metal-organic framework Cu3(HHTP)2 film with high thermoelectric performance for low-grade heat harvesting

Measurement evidence

Spectroscopy

Flexible conductive metal-organic framework Cu3(HHTP)2 film with high thermoelectric performance for low-grade heat harvesting · Wu X., Zheng Q., Sun T. et al. · Journal of Alloys and Compounds · 2025 · 183333

3 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Fourier transform infrared spectroscopy (Nicolet 6700)

Optimised Cu3(HHTP)2/Nylon hot-pressed film at 353 K · Thin Film

FTIR comparison of HHTP ligand, Cu3(HHTP)2 powder and Cu3(HHTP)2/Nylon film.

Context
film compared with pristine powder and linker
Measurement source
main p.3-5 · 3. Results and discussion · Figure 3d
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
C=O vibration peakC=O vibration peak at 1620 cm-1Text
Exact Reported
main p.3 · 3. Results and discussion · Figure 3d
HHTP O-H vibration diminishes after coordinationO-H vibration peak around 3000-3500 cm-1 diminished in Cu3(HHTP)2 powder and film.Text
Qualitative
main p.3 · 3. Results and discussion · Figure 3d

Solid-state UV-vis spectroscopy

Optimised Cu3(HHTP)2/Nylon hot-pressed film at 353 K · Thin Film

UV-vis comparison of Cu3(HHTP)2 powder, Cu3(HHTP)2 film and nylon membrane.

Context
film compared with pristine powder and substrate
Measurement source
main p.3-5 · 3. Results and discussion · Figure 3e
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
characteristic absorption bandaround 330 nmText
Approximate
main p.3 · 3. Results and discussion · Figure 3e

X-ray photoelectron spectroscopy

Cu3(HHTP)2 nanorod powder · Powder

C 1s, Cu 2p and O 1s spectra of Cu3(HHTP)2 powder discussed from Fig. S1.

Context
pristine Cu3(HHTP)2 powder
Measurement source
SI rendered p.2 · Supplementary Information · Figure S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu valence states from XPSCu+ and Cu2+ species coexist in Cu3(HHTP)2 powder.Text
Qualitative
main p.3 · 3. Results and discussion · Figure S1 referenced