Thermoelectric — Flexible conductive metal-organic framework Cu3(HHTP)2 film with high thermoelectric performance for low-grade heat harvesting

8 measurement groups · 35 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Four-probe electrical conductivity with Loresta-GX MCP-T700; lab-made Seebeck setup with Peltier plates

Electrical conductivity Seebeck and thermopower measurements

HP-1 Cu3(HHTP)2/Nylon hot-pressed film · Thin Film

Room-temperature thermoelectric test of HP-1 volume-series film.

Temperature: room temperature
Geometry: Nylon-supported film; Seebeck calculated as S = -DeltaV/DeltaT.
Context: composite hot-pressed film
Measurement source: main p.2,p.4 · 2.5. Characterization; 3. Results and discussion · Figure 4a-b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
power factor calculated from reported S and sigma	calculated as 215^2 x 3.1 x 1e-4 = 14.3 nW m-1 K-2	1.43e-8 W m-1 K-2	—	Calculated From Reported Rounded Reported	main p.4 · 3. Results and discussion · Figure 4a-b
Seebeck coefficient	215 uV/K	0.000215 V K-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4a
electrical conductivity	3.1 mS cm-1	0.31 S m-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4a

Four-probe electrical conductivity with Loresta-GX MCP-T700; lab-made Seebeck setup with Peltier plates

Electrical conductivity Seebeck and thermopower measurements

HP-2 Cu3(HHTP)2/Nylon hot-pressed film · Thin Film

Room-temperature thermoelectric test of HP-2 volume-series film.

Temperature: room temperature
Geometry: Nylon-supported film; Seebeck calculated as S = -DeltaV/DeltaT.
Context: composite hot-pressed film
Measurement source: main p.2,p.4 · 2.5. Characterization; 3. Results and discussion · Figure 4a-b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
power factor calculated from reported S and sigma	calculated as 229^2 x 3.6 x 1e-4 = 18.9 nW m-1 K-2	1.89e-8 W m-1 K-2	—	Calculated From Reported Rounded Reported	main p.4 · 3. Results and discussion · Figure 4a-b
Seebeck coefficient	229 uV/K	0.000229 V K-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4a
electrical conductivity	3.6 mS cm-1	0.36 S m-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4a

Four-probe electrical conductivity with Loresta-GX MCP-T700; lab-made Seebeck setup with Peltier plates

Electrical conductivity Seebeck and thermopower measurements

HP-3 Cu3(HHTP)2/Nylon hot-pressed film at 333 K · Thin Film

Room-temperature thermoelectric test of HP-3, 20 mL film hot pressed at 333 K.

Temperature: room temperature
Geometry: Nylon-supported film; Seebeck calculated as S = -DeltaV/DeltaT.
Context: composite hot-pressed film
Measurement source: main p.4 · 3. Results and discussion · Figure 4a-d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
power factor	27.7 nW m-1 K-2	2.77e-8 W m-1 K-2	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4b
Seebeck coefficientMarked as a best value within this paper	248.3 uV/K	0.0002483 V K-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4a,c
electrical conductivity	4.5 mS cm-1	0.45 S m-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4a,c

Four-probe electrical conductivity with Loresta-GX MCP-T700; lab-made Seebeck setup with Peltier plates

Electrical conductivity Seebeck and thermopower measurements

Optimised Cu3(HHTP)2/Nylon hot-pressed film at 353 K · Thin Film

Room-temperature thermoelectric test of optimised 20 mL film hot pressed at 353 K.

Temperature: room temperature
Geometry: Nylon-supported film; Seebeck calculated as S = -DeltaV/DeltaT.
Context: target composite hot-pressed film
Measurement source: main p.4 · 3. Results and discussion · Figure 4c-d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
power factorMarked as a best value within this paper	31.9 nW m-1 K-2	3.19e-8 W m-1 K-2	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4d
Seebeck coefficient	221.7 uV/K	0.0002217 V K-1	—	Text Exact Reported	main p.1,p.4 · Abstract; 3. Results and discussion · Figure 4c
electrical conductivityMarked as a best value within this paper	6.5 mS cm-1	0.65 S m-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4c
carrier type indicated by Seebeck sign	All samples show positive Seebeck coefficients, indicating p-type characteristics.	—	—	Text Qualitative	main p.4 · 3. Results and discussion · Figure 4

Four-probe electrical conductivity with Loresta-GX MCP-T700; lab-made Seebeck setup with Peltier plates

Electrical conductivity Seebeck and thermopower measurements

Cu3(HHTP)2/Nylon hot-pressed film at 373 K · Thin Film

Room-temperature thermoelectric test of 20 mL film hot pressed at 373 K.

Temperature: room temperature
Geometry: Nylon-supported film; Seebeck calculated as S = -DeltaV/DeltaT.
Context: composite hot-pressed film
Measurement source: main p.4 · 3. Results and discussion · Figure 4c-d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
power factor calculated from reported S and sigma	calculated as 177.3^2 x 3.1 x 1e-4 = 9.75 nW m-1 K-2	9.75e-9 W m-1 K-2	—	Calculated From Reported Rounded Reported	main p.4 · 3. Results and discussion · Figure 4c-d
Seebeck coefficient	177.3 uV/K	0.0001773 V K-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4c
electrical conductivity	3.1 mS cm-1	0.31 S m-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4c

Four-probe electrical conductivity with Loresta-GX MCP-T700; lab-made Seebeck setup with Peltier plates

Electrical conductivity Seebeck and thermopower measurements

HP-4 Cu3(HHTP)2/Nylon hot-pressed film · Thin Film

Room-temperature thermoelectric test of HP-4 volume-series film.

Temperature: room temperature
Geometry: Nylon-supported film; Seebeck calculated as S = -DeltaV/DeltaT.
Context: composite hot-pressed film
Measurement source: main p.4 · 3. Results and discussion · Figure 4a-b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
power factor calculated from reported S and sigma	calculated as 204^2 x 5.0 x 1e-4 = 20.8 nW m-1 K-2	2.08e-8 W m-1 K-2	—	Calculated From Reported Rounded Reported	main p.4 · 3. Results and discussion · Figure 4a-b
Seebeck coefficient	204 uV/K	0.000204 V K-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4a
electrical conductivity	5.0 mS cm-1	0.5 S m-1	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure 4a

ZEM-3 standard four-probe thermoelectric measurement

Electrical conductivity

Cu3(HHTP)2 pellet · Pellet

Temperature-dependent thermoelectric measurement of cold-isostatic Cu3(HHTP)2 pellet, with room-temperature PF reported in main text and plotted SI data read approximately from Fig. S3.

Temperature: approximately 310-363 K
Geometry: Pressed pellet.
Context: pristine pellet control
Measurement source: SI rendered p.3 · Supplementary Information · Figure S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
pellet power factor	15.3 nW m-1 K-2	1.53e-8 W m-1 K-2	—	Text Exact Reported	main p.4 · 3. Results and discussion · Figure S3 referenced
pellet power factor at approximately 310 KMarked as a best value within this paper	~15.0 nW m-1 K-2 at ~310 K	1.5000000000000002e-8 W m-1 K-2	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet power factor at approximately 325 K	~12.5 nW m-1 K-2 at ~325 K	1.2500000000000001e-8 W m-1 K-2	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet power factor at approximately 342 K	~1.0 nW m-1 K-2 at ~342 K	1e-9 W m-1 K-2	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet power factor at approximately 362 K	~1.8 nW m-1 K-2 at ~362 K	1.8000000000000002e-9 W m-1 K-2	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet Seebeck coefficient at approximately 310 K	~118 uV K-1 at ~310 K	0.000118 V K-1	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet Seebeck coefficient at approximately 325 K	~85 uV K-1 at ~325 K	0.00008499999999999999 V K-1	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet Seebeck coefficient at approximately 342 K	~12 uV K-1 at ~342 K	0.000012 V K-1	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet Seebeck coefficient at approximately 362 K	~10 uV K-1 at ~362 K	0.000009999999999999999 V K-1	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet electrical conductivity at approximately 310 K	~12 mS cm-1 at ~310 K	1.2000000000000002 S m-1	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet electrical conductivity at approximately 325 K	~18 mS cm-1 at ~325 K	1.8 S m-1	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet electrical conductivity at approximately 342 K	~40 mS cm-1 at ~342 K	4 S m-1	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3
pellet electrical conductivity at approximately 362 K	~90 mS cm-1 at ~362 K	9 S m-1	—	Figure Axis Approximate	SI rendered p.3 · Supplementary Information · Figure S3

Supplementary Table S1 comparison of conductive MOF-based thermoelectric materials

Optimised Cu3(HHTP)2/Nylon hot-pressed film at 353 K · Thin Film

Current-work Cu3(HHTP)2 hot-pressed film row in SI Table S1; values duplicate/cross-check main-text best film values using S cm-1 and uW m-1 K-2 units.

Temperature: room temperature
Geometry: Nylon-supported hot-pressed film.
Context: target composite hot-pressed film in literature-comparison table
Measurement source: SI rendered p.4 · Supplementary Information · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
power factor from SI Table S1 current-work rowMarked as a best value within this paper	3.2x10-2 uW m-1 K-2	3.2e-8 W m-1 K-2	—	SI Table Rounded Reported	SI rendered p.4 · Supplementary Information · Table S1
Seebeck coefficient from SI Table S1 current-work row	221.7 uV K-1	0.0002217 V K-1	—	SI Table Exact Reported	SI rendered p.4 · Supplementary Information · Table S1
electrical conductivity from SI Table S1 current-work rowMarked as a best value within this paper	6.5x10-3 S cm-1	0.65 S m-1	—	SI Table Exact Reported	SI rendered p.4 · Supplementary Information · Table S1