Measurement evidence
Mixed Ionic and Electronic Conductivity in a Tetrathiafulvalene-Phosphonate Metal-Organic Framework · Ribeiro C., Tan B., Figueira F. et al. · Journal of the American Chemical Society · 2025 · 63-68
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
TTFTP-La MOF bulk dark crystals · Powder
Room-temperature EPR of TTFTP-La and H8TTFTP ligand.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| EPR g factor | g = 2.006 | — | — | Text Exact Reported | 64 · main text · Figure S16 |
TTFTP-La MOF bulk dark crystals · Powder
Powdered TTFTP-La compared with H8TTFTP ligand.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| OH stretching band range | broad bands around 3000-3300 cm-1 | — | range 3000-3300 cm-1 | Text Range | 64 · main text · Figure S18 |
TTFTP-La MOF bulk dark crystals · Powder
Room-temperature Raman spectrum of TTFTP-La MOF.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Charge-sensitive Raman bands | 1521, 1478 and 1410 cm-1 | — | multiple reported bands | Text Exact Reported | S19 · Raman spectroscopy · Figure S17 |
TTFTP-La MOF bulk dark crystals · Powder
Direct optical band gap obtained from linear fit to absorption onset.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Optical band gap | Eg = 1.58 eV | — | — | Text Exact Reported | 65 · main text · Figure S26 |