Electrochemistry Application — Mixed Ionic and Electronic Conductivity in a Tetrathiafulvalene-Phosphonate Metal-Organic Framework

3 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Et8TTFTP red powder · Powder

Et8TTFTP measured at different scan rates.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Et8TTFTP first half-wave potential	E1/2(1) = 0.07 V vs Fc/Fc+	—	—	Text Exact Reported	S5 · Synthesis of H8TTFTP · Figure S6
Et8TTFTP second half-wave potential	E1/2(2) = 0.45 V vs Fc/Fc+	—	—	Text Exact Reported	S5 · Synthesis of H8TTFTP · Figure S6

H8TTFTP black solid · Powder

H8TTFTP ligand measured at 0.1, 0.3 and 0.5 V/s with DPV trace.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
H8TTFTP redox features	multiple redox waves between approximately -0.2 and 1.0 V vs Fc/Fc+	—	visual range approximately -0.2 to 1.0 V	Visual Estimate Approximate	S11 · Synthesis of H8TTFTP · Figure S11

TTFTP-La/Nafion glassy-carbon working electrode · Electrode

TTFTP-La MOF on glassy carbon/Nafion electrode at scan rates 0.1, 0.3 and 0.5 V/s.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Approximate TTFTP-La redox-potential region	redox waves approximately 0.35-0.50 V and 1.1-1.25 V vs Fc/Fc+	—	visual ranges approximately 0.35-0.50 and 1.1-1.25 V	Visual Estimate Approximate	S24 · Physicochemical characterization · Figure S24
TTFTP-La redox processes	two reversible redox processes	—	—	Text Exact Reported	65 · main text · Figure S24