Harmonised techniqueNon-exclusive mapping

Electron paramagnetic resonance

EPR/ESR and related spin-resonance measurements.

118primary papers
183mapped measurements
580linked results
109raw method labels
The harmonised label does not replace the method

Every source method stays verbatim. Subtypes retain distinctions such as ATR versus transmission IR, powder versus single-crystal diffraction, and two- versus four-contact transport.

Measurement-family coverage

The same technique may serve transport, electrochemistry, sensing or another scientific purpose.

Mapped measurements

Filter source method wording, sample context and scientific purpose.

183 measurements

SpectroscopyUnspecified subtype

EPR spin trapping of reactive oxygen species

2026 · Metal–(organic cocrystal) framework with a photothermal effect boosting the photocatalytic degradation of pollutants

Ac@[Ca-NDI] MOCF powder · Powder · DMPO used for superoxide and hydroxyl radicals; TEMP used for singlet oxygen; dark and illuminated conditions.

SpectroscopyUnspecified subtype

EPR spectroscopy

2026 · Microenvironment modulation in heterometallic MOFs for tailoring electron/proton transport and hydrophilicity toward photocatalytic hydrogen production

Ni-Ca dark brown crystals / powder · Powder

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†

Ca-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†

Co-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†

Cu-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†

Mg-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†

Ni-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†

Zn-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.

Electrochemistry ApplicationUnspecified subtype

Solid-state EPR spectroelectrochemistry

2026 · Tunable Charge Transport Properties Through Precise π-Stacking Modulation in Isostructural Porous Molecular Conductors

PMC-3-Br solid-state electrochemical sample · Electrode · X-band EPR SEC at room temperature using Bruker EMXnano; Pt mesh/Pt working electrode; 0.1 M LiBF4/MeCN.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance

2025 · A Cu-based electronically conducting metal–organic framework with π–d conjugation for cathode and anode modification in aqueous zinc-ion batteries

DDA ligand · Powder · Room-temperature EPR of pristine DDA ligand.

SpectroscopyUnspecified subtype

SERS Raman, XPS, EPR and Cu K-edge XAS

2025 · A Low-Symmetry Copper Benzenehexathiol Coordination Polymer with In-Plane Electrical Anisotropy

Cu5BHT crystal domains · Single Crystal · Raman within crystal domains; XPS calibrated to graphitic C1s at 284.6 eV; EPR at 3.4 K; XANES/EXAFS compared with Cu foil, CuO, Cu2O, CuS and Cu2S references.

SpectroscopyUnspecified subtype

XPS and EPR

2025 · Catalysis-Assisted Synthesis of Two-Dimensional Conductive Metal–Organic Framework Films with Controllable Orientation

face-on Cu3(HHTP)2 film on silicon, 60 min · Thin Film · Cu 2p, C 1s, O 1s XPS and EPR spectrum at 77 K

SpectroscopyUnspecified subtype

EPR spectroscopy with DMPO and TEMP spin trapping

2025 · Construction of nanozyme based with mixed valence manganese oxide loaded on defective metal-organic frameworks for sensitive detection of biomarker procalcitonin

MdP nanoparticles · Powder · EPR detection of hydroxyl radical, superoxide/peroxyl radical and singlet oxygen species during MdP/TMB reaction.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field

As-synthesised Cu3(HHTP)2 powder · Powder · EPR spectra recorded at 77 K; ligand-based radicals and Cu2+ square-planar signatures discussed.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field

As-synthesised Cu3(HITP)2 powder · Powder · EPR spectra recorded at 77 K; ligand-based radicals and Cu2+ square-planar signatures discussed.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field

As-synthesised Cu3(THT)2 powder · Powder · EPR spectra recorded at 77 K; ligand-based radicals and Cu2+ square-planar signatures discussed.

Electrochemistry ApplicationUnspecified subtype

Radical scavenging and EPR spectroscopy

2025 · Dual single atomic Fe-Ni sites in N‑doped nanoporous carbon for high-efficiency potassium periodate activation toward pollutant abatement

Fe2Ni1-NC-900 · Powder · TBA, MeOH, EtOH, p-BQ, L-histidine and DMSO scavengers; EPR with DMPO for radicals and TEMP for singlet oxygen.

SpectroscopyUnspecified subtype

FTIR, Raman, XPS, EPR spectroscopy

2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks

Cu-S-HHS solvothermal powder · Powder · KBr FTIR; SERS with silver nanoparticles/APTS glass; XPS Al Kalpha; EPR X-band at 120 K.

SpectroscopyUnspecified subtype

FTIR, Raman, XPS, EPR spectroscopy

2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks

Cu-Se-HHS solvothermal powder · Powder · KBr FTIR; SERS with silver nanoparticles/APTS glass; XPS Al Kalpha; EPR X-band at 120 K.

SpectroscopyUnspecified subtype

FTIR, Raman, XPS, EPR spectroscopy

2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks

Cu-Te-HHS solvothermal powder · Powder · KBr FTIR; SERS with silver nanoparticles/APTS glass; XPS Al Kalpha; EPR X-band at 120 K.

SpectroscopyUnspecified subtype

EPR

2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks

Ni3(HI12)2 activated powder · Powder · EPR spectra at 300 K; powders activated at 60 C under vacuum for 2 h

SpectroscopyUnspecified subtype

EPR

2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks

Ni3(HI18)2 activated powder · Powder · EPR spectra at 300 K; powders activated at 60 C under vacuum for 2 h

SpectroscopyUnspecified subtype

EPR

2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks

Ni3(HITP)2 activated powder · Powder · EPR spectra at 300 K; powders activated at 60 C under vacuum for 2 h

SpectroscopyUnspecified subtype

in situ FT-IR, ex situ EPR and XPS

2025 · In Situ Construction of Amide-Functionalized 2D Conjugated Metal-Organic Frameworks with Multiple Active Sites for High-Performance Potassium-Ion Batteries

Cu-HBB-MOF cathode electrode in CR2025 potassium half-cell · Electrode · Cu-HBB-MOF electrode monitored during charge/discharge

SpectroscopyUnspecified subtype

EPR spectroscopy

2025 · Mechanistic Insight into the Formation and Deposition of Conductive, Layered Metal-Organic Framework Nanocrystals

reduced HHTP powder · Powder · fresh HHTP under nitrogen and aged 5 days exposed to air

SpectroscopyUnspecified subtype

EPR

2025 · Modulating the redox states in a 3D conductive MOF for sweat ascorbic acid monitoring

I2@FeTHQ, 20 C 6 h · Powder · Persistent free radicals in FeTHQ and I2@FeTHQ

Electrochemistry ApplicationUnspecified subtype

ROS probe assays and ESR under ultrasound

2025 · Piezoelectric-mediated two-dimensional copper-based metal–organic framework for synergistic sonodynamic and cuproptosis-driven tumor therapy

CM nanosheets · Nanosheet · DPA, NBT, MB, DPBF and ESR spin-trapping assays under ultrasound; CM concentration typically 60 ug mL^-1; ultrasound 1 MHz, 1 W cm^-2, 60% duty cycle for optical probes.

SpectroscopyUnspecified subtype

EPR

2025 · Radiation-Induced in Situ Construction of 2D Conductive Defect-Rich Metal-Organic Frameworks for High-Performance Supercapacitor

Cu-CAT-Rad · Powder · Powder EPR; ligand-centred monoradical signal

SpectroscopyUnspecified subtype

EPR

2025 · Radiation-Induced in Situ Construction of 2D Conductive Defect-Rich Metal-Organic Frameworks for High-Performance Supercapacitor

Cu-CAT-Sol · Powder · Powder EPR; ligand-centred monoradical signal

SpectroscopyUnspecified subtype

Single-crystal X-band CW-EPR quantitative spin counting

2025 · Screening-Enabled Chemiresistive Moisture Sensing with Tetrathiafulvalene-Based Electrically Conductive Metal–Organic Frameworks

Single crystal of Cd2(TTFTB) for quantitative CW-EPR · Single Crystal · Cd2(TTFTB) and Zn2(TTFTB) single crystals in humid air at room temperature; c axis parallel to static magnetic field.

SpectroscopyUnspecified subtype

X-band CW-EPR with EasySpin fitting

2025 · Screening-Enabled Chemiresistive Moisture Sensing with Tetrathiafulvalene-Based Electrically Conductive Metal–Organic Frameworks

Polycrystalline Zn2(TTFTB) powder/crystals for CW-EPR · Powder · Polycrystalline Zn2(TTFTB), humid air and vacuum, 298 K; CIQTEK EPR200M, 9.6 GHz.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance spectroscopy

2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages

CuPc-O-Cu black powder · Powder · Bruker BioSpin standard cavity; 2-3 mg sample purged with N2 for 2 h and sealed under N2; liquid nitrogen temperature 77 K.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance spectroscopy

2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages

CuPc(OH)8 monomer powder · Powder · Bruker BioSpin standard cavity; 2-3 mg sample purged with N2 for 2 h and sealed under N2; liquid nitrogen temperature 77 K.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance spectroscopy

2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages

CuPc-O-Ni black powder · Powder · Bruker BioSpin standard cavity; 2-3 mg sample purged with N2 for 2 h and sealed under N2; liquid nitrogen temperature 77 K.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance spectroscopy

2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages

CuPc-O-Zn black powder · Powder · Bruker BioSpin standard cavity; 2-3 mg sample purged with N2 for 2 h and sealed under N2; liquid nitrogen temperature 77 K.

SpectroscopyUnspecified subtype

ESR/EPR spectroscopy

2025 · Two-dimensional conductive metal-organic framework with 2,3,6,7,14,15-triptycenehexathiol (TCHT) ligand: synthesis, structure, electrical conductivity and CO2RR activity

Cu-TCHT black powder · Powder · EMX-nano; frequency 9.64 GHz; Q-value 5635.

SpectroscopyUnspecified subtype

FT-IR, Raman, XPS, EPR and TEM-EDS mapping

2025 · Two-Dimensional π-d Conjugated Conductive Metal-Organic Framework with Triple Active Centers as High-Performance Cathodes for Flexible Zinc Batteries

Pristine 2D Cu-TABQ powder · Powder · Powder characterisation of 2D Cu-TABQ; instruments include Raman Bruker Senterra, FTIR Bruker Vertex 70 V, XPS Thermo ESCALAB 250Xi and EPR Bruker EMXplus-6/1.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance spectroscopy.

2025 · Uninterrupted π-d Conjugated Three-Dimensional Conductive Metal-Organic Framework

As-synthesised Ni3HBC greenish-black nanocrystalline powder · Powder · Bruker BioSpin spectrometer at 110 K; X-band 9.4 GHz, microwave power 2.14 mW, modulation frequency 100 kHz, amplitude 4 G.

SpectroscopyUnspecified subtype

solid-state EPR

2024 · 2D Conductive Metal-Organic Frameworks Based on Tetraoxa[8]circulenes as Promising Cathode for Aqueous Zinc Ion Batteries

Cu-TOC black powder / pressed pellet · Powder · EPR spectra collected at 90 K according to SI methods.

SpectroscopyUnspecified subtype

FTIR, EPR, XPS

2024 · A Triptycene-Based Layered/Flower-Like 2D Conductive Metal–Organic Framework with 3D Extension as an Electrode for Efficient Li Storage

Pristine M-DBH powders (M = Ni, Co, Mn) · Powder · FTIR-ATR 400-4000 cm^-1; EPR at room temperature; XPS with Al K alpha radiation.

SpectroscopyUnspecified subtype

Scavenger trapping and EPR spectroscopy

2024 · Bimetallic synergy significantly enhances the photocatalytic performance of lanthanide porphyrin-based MOFs: Efficient photocatalytic oxidation of benzyl alcohol and benzylamine under mild conditions in air

Ni-Nd PMOFs · Powder · Scavenger capture experiment; DMPO captured superoxide; TEMPO captured singlet oxygen; dark versus visible light comparisons.

SpectroscopyUnspecified subtype

XANES and ESR/EPR spectroscopy

2024 · Diamagnetic Carrier-Doping-Induced Continuous Electronic and Magnetic Crossover in One-Dimensional Coordination Polymers

all Cu-doping-ratio powders · Powder · Co and Cu XANES plus solid-state ESR used to assign tetrahedral coordination and Cu1+ oxidation.

SpectroscopyUnspecified subtype

X-band EPR spectroscopy

2024 · Gas-Induced Electrical and Magnetic Modulation of Two-Dimensional Conductive Metal–Organic Framework

gas-exposed Cu3(C6O6)2 EPR tube samples · Powder · 298 K and 77 K; 9.77 GHz; centre field 3500 G; sweep width 3000 G

SpectroscopyUnspecified subtype

S 2p XPS and EPR before/after H2S exposure

2024 · High-Performance H2S Sensors to Detect SF6 Leakage

Co1.8Ni1.2(HITP)2 chemiresistive gas sensor on Au IDE chip · Electrode · Reaction of Co1.8Ni1.2(HITP)2 with H2S; S 2p peaks and free radical signal.

SpectroscopyUnspecified subtype

ESR radical quantification using TEMPO reference

2024 · Naphthalene Diimide-Based Hydrogen-Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applications

ammonia-doped NDI(CPOH)2-SC sensor device · Single Crystal · ammonia-doped NDI(CPOH)2-SC compared with TEMPO

SpectroscopyUnspecified subtype

ESR radical quantification using TEMPO integrated area

2024 · Naphthalene Diimide-Based Hydrogen-Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applications

Device C vacuum-pretreated hydrazine-doped NDI(CPOH)2-SC · Single Crystal · comparison of pristine, hydrazine-doped normal and hydrazine-doped vacuum-treated samples

SpectroscopyUnspecified subtype

PES, LEIPS, UV-vis/NIR absorption, ESR

2024 · Naphthalene Diimide-Based Hydrogen-Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applications

Device B hydrazine-doped NDI(CPOH)2-SC, normal treatment · Single Crystal · comparison of pristine and hydrazine-doped NDI(CPOH)2-SCs; TEMPO used as ESR reference

SpectroscopyUnspecified subtype

X-band electron paramagnetic resonance

2024 · Revealing the effect of cobalt content and ligand exchange in the bimetallic Ni–Co MOF for stable supercapacitors with high energy density

Ni-M/NiCo-M/Co-M powder comparison series · Powder · Around 9 GHz, Bruker EMX PLUS EPR with ER 4122 SHQ resonator

SpectroscopyUnspecified subtype

EDS, XPS, EPR, TGA and post-soaking PXRD stability checks

2024 · Triazacoronene-Based 2D Conductive Metal–Organic Framework for High-Capacity Lithium Storage

as-synthesised Cu-TAC powder · Powder · Elemental composition, Cu valence, paramagnetic signal, thermal decomposition and crystallinity after water/electrolyte immersion.

SpectroscopyUnspecified subtype

Continuous-wave ESR and variable-temperature ESR

2024 · Tunable Charge Transport and Spin Dynamics in Two-Dimensional Conjugated Metal-Organic Frameworks

Ni3(HATI_H)2 black powder · Powder · Powder heated at 150 C under vacuum for 2 h, sealed in quartz ESR tube under He; X-band CW ESR from 10-300 K.

SpectroscopyUnspecified subtype

XAFS/XPS/EPR electronic structure

2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance

Co-DHHBTN powder · Powder · XAFS at metal K edges; XPS with Al Kalpha, pass energy 30 eV; EPR at 150 K, 9.08 GHz X-band.

SpectroscopyUnspecified subtype

XAFS/XPS/EPR electronic structure

2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance

Cu-DHHBTN powder · Powder · XAFS at metal K edges; XPS with Al Kalpha, pass energy 30 eV; EPR at 150 K, 9.08 GHz X-band.

SpectroscopyUnspecified subtype

XAFS/XPS/EPR electronic structure

2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance

Ni-DHHBTN powder · Powder · XAFS at metal K edges; XPS with Al Kalpha, pass energy 30 eV; EPR at 150 K, 9.08 GHz X-band.

SpectroscopyUnspecified subtype

EPR and DC magnetic susceptibility

2023 · A Conductive 2D Conjugated Tetrathia[8]circulene-Based Nickel Metal–Organic Framework for Energy Storage

as-synthesised Ni-TTC black powder · Powder · EPR collected at 90 K; magnetic susceptibility in SQUID-VSM at 1000 Oe

SpectroscopyUnspecified subtype

Electron paramagnetic resonance spectroscopy

2023 · A Triptycene-Based 2D MOF with Vertically Extended Structure for Improving the Electrocatalytic Performance of CO2 to Methane

2D-vc-MOF(Cu) blue-black powder · Powder · EPR with sweep width 1500 G and centre field 3500 G.

SpectroscopyUnspecified subtype

EPR spectroscopy

2023 · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction

c-HBC-12O-Cu black powder · Powder · Room-temperature Bruker A300; sweep width 3000 G, centre field 3300 G, modulation 4 G, microwave 9.85 GHz, power 18.83 mW.

SpectroscopyUnspecified subtype

EPR spectroscopy

2023 · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction

c-HBC-6O-Cu black powder · Powder · Room-temperature Bruker A300; sweep width 3000 G, centre field 3300 G, modulation 4 G, microwave 9.85 GHz, power 18.83 mW.

SpectroscopyUnspecified subtype

EPR spectroscopy

2023 · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction

c-HBC-8O-Cu black powder · Powder · Room-temperature Bruker A300; sweep width 3000 G, centre field 3300 G, modulation 4 G, microwave 9.85 GHz, power 18.83 mW.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2023 · Engineering Band Gap and Photoconduction in Semiconducting Metal Organic Frameworks: Metal Node Effect

Fe-THQ powder · Powder · Bruker EXELSYS E500 at 77 K; old Fe-THQ stored under air compared with fresh sample stored under N2.

Electrochemistry ApplicationUnspecified subtype

Radical scavenger tests and EPR with TEMPO/DMPO

2023 · Enhancing the Photocatalytic Degradation Efficiency of Dyes of Copper-Based Metal-Organic Frameworks through a Dimension-Induced Structural Strategy

Complex 1 powder catalyst used for MB/dye degradation · Powder · TBA, EDTA-2Na and TEMPOL added as scavengers; EPR used to detect h+ and hydroxyl radical related signals

SpectroscopyUnspecified subtype

Electron paramagnetic resonance with DPPH reference

2023 · Exceptionally high charge mobility in phthalocyanine-based poly(benzimidazobenzophenanthroline)-ladder-type two-dimensional conjugated polymers

2DCP-NiPc powder · Powder · Room-temperature and temperature-dependent EPR; spin count per unit cell.

SpectroscopyUnspecified subtype

FTIR, XPS, EPR, DRUV-vis

2023 · Framework Dimensional Control Boosting Charge Storage in Conjugated Coordination Polymers

as-synthesised 1D-CuTABQ powder · Powder · FTIR 400-4000 cm^-1; Al Kalpha XPS; X-band EPR at room temperature; diffuse-reflectance UV-vis

SpectroscopyUnspecified subtype

FTIR, XPS, EPR, DRUV-vis

2023 · Framework Dimensional Control Boosting Charge Storage in Conjugated Coordination Polymers

as-synthesised 2D-CuTABQ powder · Powder · FTIR 400-4000 cm^-1; Al Kalpha XPS; X-band EPR at room temperature; diffuse-reflectance UV-vis

SpectroscopyUnspecified subtype

Electron paramagnetic resonance

2023 · Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness

Cu3(HHTP)2 film on Au/Cr/glass anode deposited at 0.25 V for 45 min · Thin Film · Room-temperature EPR spectrum of Cu3(HHTP)2 film.

SpectroscopyUnspecified subtype

EPR and SQUID magnetisation

2023 · Near IR Bandgap Semiconducting 2D Conjugated Metal-Organic Framework with Rhombic Lattice and High Mobility

Cu2(OHPTP) bulk powder · Powder · EPR on Bruker 500; SQUID magnetometer with 100 Oe and 1 T options; magnetic moment measured at 15 kOe.

SpectroscopyUnspecified subtype

XPS, EPR, Raman and FTIR

2023 · One-Dimensional π-d Conjugated Conductive Metal-Organic Framework with Dual Redox-Active Sites for High-Capacity and Durable Cathodes for Aqueous Zinc Batteries

Cu-BTA-H powder · Powder · Chemical structure and electronic state comparison of Cu-BTA-H/L and Ni-BTA-H; XPS used Escalab 250Xi, Raman excitation 632 nm, FTIR Ruili WQF-510, EPR Bruker EMS nano at room temperature.

SpectroscopyUnspecified subtype

Solid-state electron spin resonance

2023 · Oxidatively Doped Tetrathiafulvalene-Based Metal-Organic Frameworks for High Specific Energy of Supercapatteries

1-ox · Single Crystal · Measured at 110 K for 1 and 1-ox with same parameters; 2/2-ox in missing Figure S14a.

SpectroscopyUnspecified subtype

solid-state electron paramagnetic resonance

2023 · Redox-Active Two-Dimensional Tetrathiafulvalene-Copper Metal-Organic Framework with Boosted Electrochemical Performances for Supercapatteries

Iodine-treated crystals of 1 (1-ox) · Single Crystal · EPR spectra of 1, 1-ox and 1-ox' in the solid state, same parameters; figure caption states 110 K.

SpectroscopyUnspecified subtype

EPR and solid UV-vis-NIR/Tauc analysis

2023 · Stabilizing Redox-Active Hexaazatriphenylene in a 2D Conductive Metal–Organic Framework for Improved Lithium Storage Performance

Cu-HATN powder · Powder · EPR on Bruker EMX-6/1; solid UV-vis-NIR on Shimadzu UV-3600.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance spectroscopy

2023 · Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene

Complex 1 bulk powdered sample · Powder · EPR on Bruker-BioSpin E500; detailed acquisition conditions otherwise not reported

SpectroscopyUnspecified subtype

Electron paramagnetic resonance spectroscopy

2023 · Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene

Complex 2 bulk powdered sample · Powder · EPR on Bruker-BioSpin E500; detailed acquisition conditions otherwise not reported

SpectroscopyUnspecified subtype

Electron paramagnetic resonance spectroscopy

2023 · Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene

Complex 3 bulk powdered sample · Powder · EPR on Bruker-BioSpin E500; detailed acquisition conditions otherwise not reported

SpectroscopyUnspecified subtype

ex situ XPS, EPR and FT-IR during discharge-charge

2022 · A Monocrystalline Coordination Polymer with Multiple Redox Centers as a High-Performance Cathode for Lithium-Ion Batteries

CuCA composite electrode in liquid-electrolyte LIB coin cell · Electrode · Coin cells at 50 mA g-1 with Celgard 2400 and 1.0 M LiTFSI in DME/DOL; electrodes disassembled in Ar glovebox, washed with DME and dried.

SpectroscopyUnspecified subtype

XPS and EPR

2022 · A one-dimensional conductive metal-organic framework with extended π-d conjugated nanoribbon layers

DDA-Cu MOF crystals / bulk precipitate · Powder · Cu 2p XPS; room-temperature EPR

SpectroscopyUnspecified subtype

quantitative solid-state EPR, Bruker EMXmicro X-band

2022 · A stable lanthanum hydroxamate metal-organic framework with radical character and electrical conductivity

La-ONDI-DMF pressed pellet · Pellet · Room-temperature X-band EPR; spin numbers determined by double integration and comparison with ultramarine standard. DMF sample is representative sample key; DMA and Catechol values are also recorded.

SpectroscopyUnspecified subtype

EPR of DMSO-extracted electrolyte

2022 · Atomic Ruthenium-Riveted Metal-Organic Framework with Tunable d-Band Modulates Oxygen Redox for Lithium-Oxygen Batteries

NiRu-HTP nanowire-array electrode on carbon paper · Electrode · electrolytes extracted after discharge/charge; reaction intermediate detection

SpectroscopyUnspecified subtype

EPR spectroelectrochemistry

2022 · Atomically Precise Integration of Multiple Functional Motifs in Catalytic Metal-Organic Frameworks for Highly Efficient Nitrate Electroreduction

As-synthesised In8 red block crystals/powder · Single Crystal · Powdered In8 in 5 mM H2SO4 with 0.5 g L-1 KNO3; selected potentials; room temperature.

SpectroscopyUnspecified subtype

ATR-IR, UV-Vis and EPR

2022 · Conjugated Metal-Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity

CuTOTP-OR family-level sample (variant not individually separated in reported result) · Unknown · ATR-IR of CuTOTP-OR; UV-Vis thin films drop-cast on quartz from 4 mg/mL THF; X-band EPR at 110 K.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR, Bruker A30)

2022 · Construction of sulfur vacancies enriched hollow zinc cobalt bimetallic sulfides for high-performance supercapacitors

Zn0.3Co2.7S4 · Powder · Used to analyse sulphur vacancies; Co3S4 and Zn0.3Co2.7S4 spectra compared in Fig. 2e.

SpectroscopyUnspecified subtype

solid-state electron paramagnetic resonance

2022 · Crystal Structure and Electrochemical and Charge Transfer Properties in Redox-Active Coordination Polymers Based on a Truncated Tetrathiafulvalene Linker

as-synthesised Zn-m-TTFTB red rod-like crystals · Powder · Solid-state EPR spectra of m-H4TTFTB ligand, Zn-m-TTFTB, and Cd-m-TTFTB.

SpectroscopyUnspecified subtype

DC magnetometry and EPR

2022 · Dimensionality Modulates Electrical Conductivity in Compositionally Constant One-, Two-, and Three-Dimensional Frameworks

Ni-1D rods/bricks · Powder · Magnetic susceptibility under 1 kOe from 1.8-300 K; EPR under nitrogen at about 4.5-5 K.

SpectroscopyUnspecified subtype

Chemical inhibition and EPR spectroscopy

2022 · Fe–O–Zr in MOF for effective photo-Fenton Bisphenol A degradation: Boosting mechanism of electronic transmission

FeUiO-1 · Powder · p-BQ, EDTA-2Na, TBA, FFA, MeOH and PO4(3-) scavenging; EPR detection of hydroxyl and superoxide radicals.

SpectroscopyUnspecified subtype

EPR ageing and pseudo-first-order decay fit

2022 · Generation of Environmentally Persistent Free Radicals on Metal-Organic Frameworks

MCP-dosed MIL-100(Al) · Powder · MCP-dosed MIL-100(Al) aged in ambient atmospheric environment from day 10 to day 157.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR)

2022 · Generation of Environmentally Persistent Free Radicals on Metal-Organic Frameworks

MIL-100(Fe) powder · Powder · MIL-100(Fe) and MIL-100(Cr) before and after MCP/CT dosing and 250 C treatment.

SpectroscopyUnspecified subtype

electron paramagnetic resonance with TEMP spin trap

2022 · Highly Effective Generation of Singlet Oxygen by an Imidazole-Linked Robust Photosensitizing Covalent Organic Framework

as-synthesized PyPor-COF powder · Powder · COF powders and trapping agents in EPR tube; xenon lamp excitation; compared dark/light and precursor/commercial photosensitiser controls.

SpectroscopyUnspecified subtype

solid-state quantitative EPR spectroscopy

2022 · Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

iodine-treated Tb-MOF bulk powder · Powder · Freshly prepared and air-exposed iodine-treated powder in 4 mm quartz tube; double integration used for spin quantification.

SpectroscopyUnspecified subtype

solid-state quantitative EPR spectroscopy

2022 · Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

pristine Tb-MOF bulk powder/crystals · Powder · Freshly prepared and air-exposed powdered sample in 4 mm quartz tube; double integration used for spin quantification.

SpectroscopyUnspecified subtype

X-band continuous-wave EPR spectroscopy

2022 · Iron-Based 2D Conductive Metal-Organic Framework Nanostructure with Enhanced Pseudocapacitance

Fe-HHTP powder · Powder · Bruker Elexsys E 500 with SHQE resonator; microwave power 6.325 mW, modulation amplitude 4 G, modulation frequency 100 kHz.

SpectroscopyUnspecified subtype

in situ EPR

2022 · Large π-Conjugated Metal-Organic Frameworks for Infrared-Light-Driven CO2Reduction

TNP-MOF crystals · Single Crystal · 140 K under N2; NIR irradiation λ ≥ 730 nm; TEOA introduced; TNP linker control

SpectroscopyUnspecified subtype

Ex situ S 2p XPS, N 1s XPS, Ni 2p XPS and EPR after H2S exposure

2022 · Large-Area Synthesis of Ultrathin, Flexible, and Transparent Conductive Metal–Organic Framework Thin Films via a Microfluidic-Based Solution Shearing Process

MASS-PRC Ni3(HITP)2 thin film · Thin Film · Thin film and bulk powder exposed to H2S and analysed for adsorbate and linker redox evidence.

SpectroscopyUnspecified subtype

Quantitative EPR

2022 · Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal-organic framework

Acros HHTP batch 2 · Model · X-band EPR at 200 K with DPPH calibration; ligand in 1:1 d6-DMSO/D2O.

SpectroscopyUnspecified subtype

Quantitative EPR

2022 · Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal-organic framework

Purified HHTP plus 0.3 equiv 2,5-dichloro-1,4-benzoquinone · Model · X-band EPR at 200 K with DPPH calibration; ligand in 1:1 d6-DMSO/D2O.

SpectroscopyUnspecified subtype

In situ X-band electron paramagnetic resonance (EPR)

2022 · Redox-Active Ni(II) Nodes Induced Electrochromism in a Two-Dimensional Conductive Metal-Organic Framework

Ni3(HITP)2-362 nm/FTO electrode · Electrode · Sandwich electrochromic device using Ni3(HITP)2 film, ITO-quartz substrate, and 1 M LiClO4/PC; Bruker A300 at 298 K, 16.65 mW, 9.85 GHz, 1 mT/100 kHz.

SpectroscopyUnspecified subtype

Solid-state EPR

2021 · A family of lanthanide metal-organic frameworks based on a redox-active tetrathiafulvalene-dicarboxylate ligand showing slow relaxation of magnetisation and electronic conductivity

2-Dy · Powder · X-band, 9.05 GHz, room temperature; Bruker EMX.

SpectroscopyUnspecified subtype

solid-state electron paramagnetic resonance (EPR)

2021 · A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands

I2-treated sine-MOF powder · Powder · Solid-state EPR recorded at room temperature on Bruker EMX EPR X-band spectrometer.

SpectroscopyUnspecified subtype

solid-state electron paramagnetic resonance (EPR)

2021 · A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands

pristine sine-MOF evacuated powder · Powder · Solid-state EPR recorded at room temperature on Bruker EMX EPR X-band spectrometer.

SpectroscopyUnspecified subtype

Continuous-wave X-band EPR spectroscopy

2021 · An Electrically Conducting Three-Dimensional Iron–Catecholate Porous Framework

Fe-HHTP-MOF black microcrystalline powder · Powder · JEOL JES-FA200; X-band 8.959 GHz; solid under nitrogen in quartz glass EPR tubes at 293, 95, and 7 K.

SpectroscopyUnspecified subtype

solid-state EPR

2021 · Conductive Stimuli-Responsive Coordination Network Linked with Bismuth for Chemiresistive Gas Sensing

NH3-exposed Bi(HHTP) · Powder · Bruker BioSpin spectrometer; about 2 mg material; pristine, NO-exposed, NH3-exposed samples flushed/sealed under N2

SpectroscopyUnspecified subtype

solid-state quantitative ESR/EPR

2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks

Cs-MOF 4 · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.

SpectroscopyUnspecified subtype

solid-state quantitative ESR/EPR

2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks

K-MOF 2 · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.

SpectroscopyUnspecified subtype

solid-state quantitative ESR/EPR

2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks

K-MOF 2-ox · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.

SpectroscopyUnspecified subtype

solid-state quantitative ESR/EPR

2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks

Na-MOF 1-ox · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.

SpectroscopyUnspecified subtype

solid-state quantitative ESR/EPR

2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks

Rb-MOF 3 · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.

SpectroscopyUnspecified subtype

solid-state quantitative ESR/EPR

2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks

Rb-MOF 3-ox · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.

SpectroscopyUnspecified subtype

electron spin resonance spectroscopy

2021 · Photochromism and photomagnetism in three cyano-bridged 3d-4f heterobimetallic viologen frameworks

CoDy after UV-vis irradiation · Single Crystal · X-band ESR before and after irradiation at room temperature

SpectroscopyUnspecified subtype

EPR

2021 · Quinone-Based Conducting Three-Dimensional Metal-Organic Framework as a Cathode Material for Lithium-Ion Batteries

as-prepared (NBu4)2Fe2(DHBQ)3 powder/solid · Powder · Room-temperature X-band EPR spectrum of pristine MOF powder.

SpectroscopyUnspecified subtype

X-band EPR spectroscopy, Bruker EMX at 9.37 GHz; PHI simulations

2021 · Redox Ladder of Ni3 Complexes with Closed-Shell, Mono-, and Diradical Triphenylene Units: Molecular Models for Conductive 2D MOFs

complex 2 dark blue needle-shaped crystals · Single Crystal · Frozen DCM glasses at 4.5 K; perpendicular and parallel modes; variable-temperature EPR for complex 2 from 4.5-45 K.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance, X-band

2021 · Sulfur vacancies enriched Nickel-Cobalt sulfides hollow spheres with high performance for All-Solid-State hybrid supercapacitor

r-NiCo2S4-6 HSs · Powder · EPR spectra at 77 K, 5.00 G modulation amplitude, magnetic field modulation 100 kHz.

SpectroscopyUnspecified subtype

Low-temperature electron paramagnetic resonance (EPR)

2021 · Two-dimensional d-π conjugated metal-organic framework based on hexahydroxytrinaphthylene

as-synthesised Cu3(HHTN)2 dark brown powder · Powder · Samples about 2 mg in EPR tube; Bruker BioSpin spectrometer; liquid nitrogen temperature.

SpectroscopyUnspecified subtype

X-band EPR spectroscopy

2020 · Biporous Cd(II) Coordination Polymer via in Situ Disulfide Bond Formation: Self-Healing and Application to Photosensitive Optoelectronic Device

Bulk/crude material of compound 1 · Powder · Compound 1 in sealed EPR tube under inert gas; irradiated at 360 nm with ISS P110 lamp for 1 h under argon; monitored after air exposure.

SpectroscopyUnspecified subtype

XPS, solid-state EPR, elemental analysis, TGA

2020 · Conjugated Copper–Catecholate Framework Electrodes for Efficient Energy Storage

As-synthesised Cu-DBC powder · Powder · XPS on Thermo ESCALAB 250XI; EPR at room temperature on Bruker a300; EA with vario EL III; TGA 20-800 C under N2 at 10 C min-1.

SpectroscopyUnspecified subtype

XPS/XANES/EXAFS/EPR

2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys

Co3(HITP)2 powder/pellet · Powder · Co oxidation state and coordination

SpectroscopyUnspecified subtype

XPS/XANES/EPR

2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys

Cu3(HITP)2 powder/pellet · Powder · Cu oxidation state and coordination

SpectroscopyUnspecified subtype

XPS/XANES/EPR

2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys

Ni3(HITP)2 powder/pellet · Powder · Ni oxidation state and ligand radical

SpectroscopyUnspecified subtype

EPR spectroscopy

2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design

purified Ni-btt powder · Powder · 77 K EMX X-band (~10 GHz) spectrometer; spin concentration estimated against CuSO4 x 5 H2O standard.

SpectroscopyUnspecified subtype

EPR spectroscopy

2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design

purified Ni-diett powder · Powder · 77 K EMX X-band (~10 GHz) spectrometer; spin concentration estimated against CuSO4 x 5 H2O standard.

SpectroscopyUnspecified subtype

EPR spectroscopy

2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design

purified Ni-ett powder · Powder · 77 K EMX X-band (~10 GHz) spectrometer; spin concentration estimated against CuSO4 x 5 H2O standard.

SpectroscopyUnspecified subtype

EPR spectroscopy and SQUID magnetometry

2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design

purified Ni-ett powder · Powder · First-derivative EPR spectra at 77 K; SQUID M-T curves and M-H hysteresis at 2 K.

SpectroscopyUnspecified subtype

solid-state EPR with quantitative spin integration

2020 · Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-πInteraction and Efficient Charge-Transport Capabilities

Evacuated [Ag2(HATHCN)(CF3SO3)2]n bulk material · Powder · Bruker EMX EPR X-band at room temperature; 70 mg evacuated MOF powder in 4 mm quartz tube; calibrated using DPPH.

SpectroscopyUnspecified subtype

ESR spectroscopy, JEOL JES-FA100

2020 · Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction

purple crystals of 1 · Single Crystal · Compound 2 handled in sealed glass capillary under nitrogen; ESR compared 1 and 2.

SpectroscopyUnspecified subtype

ESR spectroscopy, JEOL JES-FA100

2020 · Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction

black solid 2 from 1 · Powder · Compound 2 in sealed glass capillary prepared in nitrogen-filled glove box.

SpectroscopyUnspecified subtype

EPR spectroscopy

2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks

Network 4 as-synthesised single crystal · Single Crystal · Native network 4, Co material; SI spectrum recorded at 20 K, 9.3179 GHz, 0.2 mW, 0.4 mT modulation.

SpectroscopyUnspecified subtype

room-temperature X-band EPR

2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks

Network 4 iodine-treated powder/crystals for EPR, PXRD, and EDX · Powder · Polycrystalline powder of 4 left in 0.05 M I2 in CHCl3 for 3 h.

SpectroscopyUnspecified subtype

X-band EPR spectroscopy

2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks

Network 5 as-synthesised single crystal · Single Crystal · Native network 5 control compared with iodine-exposed spectra.

SpectroscopyUnspecified subtype

room-temperature X-band EPR

2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks

Network 5 iodine-treated powder/crystals for EPR, PXRD, and EDX · Powder · Polycrystalline powder of 5 left in 0.05 M I2 in CHCl3 for 3 h; microwave power 4 mW, modulation 0.5 mT.

SpectroscopyUnspecified subtype

room-temperature X-band EPR

2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks

Ligand 1 powder exposed to iodine vapour · Powder · Ligand 1 powder exposed to I2 vapour; radical cation EPR signature measured.

SpectroscopyUnspecified subtype

room-temperature X-band EPR

2020 · Isoreticular Linker Substitution in Conductive Metal–Organic Frameworks with Through-Space Transport Pathways

Cd activated bulk microcrystalline powder · Powder · 1 wt% MOF/KBr; Bruker EMX, 9.37 GHz, 0.100 mW

SpectroscopyUnspecified subtype

room-temperature X-band EPR

2020 · Isoreticular Linker Substitution in Conductive Metal–Organic Frameworks with Through-Space Transport Pathways

Mn activated bulk microcrystalline powder · Powder · 1 wt% MOF/KBr; Bruker EMX, 9.37 GHz, 0.100 mW

SpectroscopyUnspecified subtype

room-temperature X-band EPR

2020 · Isoreticular Linker Substitution in Conductive Metal–Organic Frameworks with Through-Space Transport Pathways

Zn activated bulk microcrystalline powder · Powder · 1 wt% MOF/KBr; Bruker EMX, 9.37 GHz, 0.100 mW

SpectroscopyUnspecified subtype

Electron spin resonance (ESR)

2020 · Nanorods of a novel highly conductive 2D metal-organic framework based on perthiolated coronene for thermoelectric conversion

Ni-PTC nanorod dark powder · Powder · JEOL JES-Fa200; solid-state ESR at 10 K.

SpectroscopyUnspecified subtype

Electron spin resonance (ESR)

2020 · Nanorods of a novel highly conductive 2D metal-organic framework based on perthiolated coronene for thermoelectric conversion

Ni-PTC nanorod dark powder · Powder · JEOL JES-Fa200; solid-state ESR at room temperature.

SpectroscopyUnspecified subtype

Temperature-variable EPR, JEOL JES-FA200

2020 · Quantum spin liquid state in a two-dimensional semiconductive metal−organic framework

Activated Cu3(HHTP)2 powder · Powder · Central field 300 mT and scan range 100 mT; spectra from 15 to 300 K shown.

SpectroscopyUnspecified subtype

Temperature-variable EPR, JEOL JES-FA200

2020 · Quantum spin liquid state in a two-dimensional semiconductive metal−organic framework

Activated Zn3(HHTP)2 powder · Powder · Central field 300 mT and scan range 100 mT; spectra from 15 to 300 K shown.

SpectroscopyUnspecified subtype

XPS and EPR

2020 · Solid-solid interface growth of conductive metal-organic framework nanowire arrays and their supercapacitor application

Cu3(HHTP)2 nanowire arrays in situ grown on Cu foil · Electrode · XPS on ThermoFisher Scientific K-Alpha; EPR on Bruker EM/Xplus at room temperature, 9.67 GHz microwave frequency and 20 mW microwave power.

SpectroscopyUnspecified subtype

Raman, XPS and EPR spectroscopy

2020 · Synthesis of a copper 1,3,5-triamino-2,4,6-benzenetriol metal-organic framework

Iodine-doped Cu3(TABTO)2-Ar powder · Powder · Raman on Si/SiO2 under 532 nm excitation; XPS survey/high-resolution; EPR comparison with pristine.

SpectroscopyUnspecified subtype

Solid-state electron paramagnetic resonance (EPR)

2020 · The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands

1, activated pristine dhMOF · Powder · Solid-state EPR of pristine 1; SI: Bruker EMX EPR X-band spectrometer at room temperature

SpectroscopyUnspecified subtype

Solid-state electron paramagnetic resonance (EPR)

2020 · The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands

1a, iodine-treated washed evacuated dhMOF · Powder · Solid-state EPR of iodine-treated 1a; SI: Bruker EMX EPR X-band spectrometer at room temperature

SpectroscopyUnspecified subtype

EPR spin-trapping and radical quenching

2020 · Three-dimensional Co/Ni bimetallic organic frameworks for high-efficient catalytic ozonation of atrazine: Mechanism, effect parameters, and degradation pathways analysis

Co/Ni-MOF brown powder · Powder · DMPO for OH and O2-; TEMP for 1O2; [DMPO] 90 mmol L-1, [TEMP] 63 mmol L-1, O3 8 mg L-1, catalyst 0.5 g L-1; TBA quenching used for OH.

SpectroscopyUnspecified subtype

Electron paramagnetic resonance using Bruker EMX-10/12.

2020 · Tuning Electrical- and Photo-Conductivity by Cation Exchange within a Redox-Active Tetrathiafulvalene-Based Metal–Organic Framework

MV@1 crystals · Single Crystal · 90 K spectra at 9.4451 GHz; variable-temperature 90-270 K; UV exposure 20 min for irradiated sample.

SpectroscopyUnspecified subtype

ESR with DMPO spin trapping

2020 · Tuning Lewis acidity of MIL-88B-Fe with mix-valence coordinatively unsaturated iron centers on ultrathin Ti3C2 nanosheets for efficient photo-Fenton reaction

CUCs-MIL-88B-Fe/Ti3C2 powder · Powder · 10 uL sample containing 10 mg catalyst in water plus 10 uL 50 mM H2O2 and 10 uL 50 mM DMPO; visible light cutoff 420 nm; ambient temperature.

SpectroscopyUnspecified subtype

EPR spectroscopy

2019 · Co 3 O 4 @Cu-Based Conductive Metal–Organic Framework Core–Shell Nanowire Electrocatalysts Enable Efficient Low-Overall-Potential Water Splitting

Co3O4@CuCAT optimal core-shell electrode · Electrode · EPR spectra collected at 77 K to assess oxygen vacancies.

SpectroscopyUnspecified subtype

Room-temperature X-band electron paramagnetic resonance

2019 · Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks

As-synthesised bulk powder of compound 1 · Powder · MOF powders diluted 1 wt% with KBr and measured under nitrogen in septum-sealed quartz tubes.

SpectroscopyUnspecified subtype

Room-temperature X-band electron paramagnetic resonance

2019 · Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks

As-synthesised bulk powder of compound 2 · Powder · MOF powders diluted 1 wt% with KBr and measured under nitrogen in septum-sealed quartz tubes.

SpectroscopyUnspecified subtype

Room-temperature X-band electron paramagnetic resonance

2019 · Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks

As-synthesised bulk powder of compound 3 · Powder · MOF powders diluted 1 wt% with KBr and measured under nitrogen in septum-sealed quartz tubes.

SpectroscopyUnspecified subtype

ESR spectroscopy

2019 · Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers

PMC-1 bulk powder/crystals · Powder · JEOL JES-FA100; measured at room temperature.

SpectroscopyUnspecified subtype

EPR spectroscopy

2019 · Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal-Organic Frameworks

complex 1 frozen methanol:toluene glass · Unknown · Bruker EMX spectrometer, 9.37 GHz; frozen 1:1 methanol:toluene glass; traces at 5, 20, and 50 K; EasySpin simulations.

SpectroscopyUnspecified subtype

EPR spectroscopy

2019 · Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal-Organic Frameworks

complex 2 frozen methanol:toluene glass · Unknown · Bruker EMX spectrometer, 9.37 GHz; frozen 1:1 methanol:toluene glass; 20 K trace fitted with EasySpin.

SpectroscopyUnspecified subtype

continuous-wave solid-state EPR spectroscopy

2018 · Probing charge transfer characteristics in a donor-acceptor metal-organic framework by Raman spectroelectrochemistry and pressure-dependence studies

solid DPNI · Powder · Room-temperature Bruker Elexsys 500 with X-band microwave bridge; referenced against strong pitch.

SpectroscopyUnspecified subtype

X-band EPR spectroscopy; EMX Bruker spectrometer

2017 · Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework

MOF-CoNDI-py-2 purple leaf-like crystals/powder · Single Crystal · Powder sample, 7 K and 25 K, P = 6.533 mW.

SpectroscopyUnspecified subtype

continuous-wave EPR spectroscopy

2017 · Is iron unique in promoting electrical conductivity in MOFs?

pressed pellet of Fe(1,2,3-triazolate)2 · Pellet · About 5 mg Fe(1,2,3-triazolate)2 in toluene, sealed in low-pressure/vac Suprasil tube in N2 glovebox; measured at 77 K, 0.20 mW, 9.423 GHz.

SpectroscopyUnspecified subtype

Solid-state EPR spectroscopy

2017 · Lowering Band Gap of an Electroactive Metal-Organic Framework via Complementary Guest Intercalation

TTF-doped DSNDI-based MOF-74 powder · Powder · EPR spectra of undoped and TTF-doped MOF-74 compared.

SpectroscopyUnspecified subtype

ESR spectroscopy and spin susceptibility

2017 · Multiple-Hydrogen-Bond Approach to Uncommon Pd(III) Oxidation State: A Pd-Br Chain with High Conductivity and Thermal Stability

Polycrystalline compound 3 · Powder · Bruker EMX spectrometer with Oxford ESR 900 gas-flow cryostat; susceptibility calibrated using CuSO4.5H2O standard.

SpectroscopyUnspecified subtype

Q-band EPR spectroscopy

2017 · Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal-Organic Frameworks

compound 1 black shiny microcrystalline solid · Powder · Variable-temperature Q-band EPR spectra.

SpectroscopyUnspecified subtype

Q-band EPR spectroscopy

2017 · Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal-Organic Frameworks

compound 2 black shiny microcrystalline solid · Powder · Variable-temperature Q-band EPR spectra.

SpectroscopyUnspecified subtype

X-band powder ESR spectroscopy

2015 · Topochemical conversion of a dense metal-organic framework from a crystalline insulator to an amorphous semiconductor

Compound 3 vacuum-dried black monolith · Unknown · JEOL JES-TE200 ESR spectrometer, 100 kHz field modulation, room temperature.

SpectroscopyUnspecified subtype

Continuous-wave EPR spectroscopy

2014 · Tunable electrical conductivity in metal-organic framework thin-film devices

TCNQ@Cu3(BTC)2 powder · Powder · Room-temperature EPR for activated Cu3(BTC)2, methanol-treated Cu3(BTC)2 and methanol/TCNQ-treated Cu3(BTC)2; low-temperature X-band triplet EPR in SI

SpectroscopyUnspecified subtype

Electron paramagnetic resonance (EPR) spectroscopy

2012 · High charge mobility in a tetrathiafulvalene-based microporous metal-organic framework

As-synthesised bulk dark maroon powder of compound 1 · Powder · EPR spectra of as-synthesised compound 1 and iodine-oxidised H4TTFTB control; instrument conditions not reported.

SpectroscopyUnspecified subtype

Room-temperature X-band solid-state ESR/EPR spectroscopy

2012 · Synthesis, characterization and solid state electrical properties of 1-D coordination polymer of the type [CuxNi1-x(dadb) ·yH2O]n

Complex 4 powder / pressed pellet · Powder · Powder ESR spectra recorded on Varian E-112; microwave frequency calibrated using TCNE, g = 2.00277; Table 2 reports ESR parameters.

SpectroscopyUnspecified subtype

Solid-state ESR spectroscopy

2012 · Synthesis, characterization, and solid state electrical conductivity of coordination polymers with copper and zinc

Complex 2 compressed pellet · Pellet · Powder ESR at room temperature and liquid nitrogen temperature; TCNE calibration.

SpectroscopyUnspecified subtype

Solid-state ESR spectroscopy

2012 · Synthesis, characterization, and solid state electrical conductivity of coordination polymers with copper and zinc

Complex 4 compressed pellet · Pellet · Powder ESR at room temperature; TCNE calibration.

SpectroscopyUnspecified subtype

Solid-state ESR spectroscopy

2012 · Synthesis, characterization, and solid state electrical conductivity of coordination polymers with copper and zinc

Complex 7 compressed pellet · Pellet · Powder ESR at room temperature; TCNE calibration.

SpectroscopyUnspecified subtype

Solid-state X-band ESR spectroscopy

2009 · Semiconducting neutral microstructures fabricated by coordinative self-assembly of intramolecular charge-transfer tetrathiafulvalene derivatives

TTF-Pb coordination-polymer microwires · Powder · Solid-state ESR spectra recorded at 298 K; g value calibrated by DPPH. Figure 4 compares microwires and spherical particles.

SpectroscopyUnspecified subtype

X-band ESR spectroscopy

1984 · Cofacial Assembly of Metallomacrocycles as an Approach to Controlling Lattice Architecture in Low-Dimensional Molecular Solids. Chemical, Structural, Oxidation-State, Transport, and Optical Properties of the Coordination Polymer [Fe(phthalocyaninato)(μ-pyrazine)]n and the Consequences of Halogen Doping

{[Fe(Pc)(mu-pyz)]I2.60}n · Pellet · Powder ESR of {[Fe(Pc)(pyz)]I2.29}n at room temperature and 77 K; 100 kHz field modulation; DPPH calibration.

Raw method vocabulary

These are the exact source-preserving method strings consolidated by this technique group.

Show 109 reported method labels
Raw method labelMapped measurements
EPR spectroscopy12
Electron paramagnetic resonance (EPR)11
Electron paramagnetic resonance spectroscopy8
EPR7
room-temperature X-band EPR6
solid-state quantitative ESR/EPR6
XPS and EPR3
Room-temperature X-band electron paramagnetic resonance3
Continuous-wave ESR, spin susceptibility fitting and pulsed EPR3
FTIR, Raman, XPS, EPR spectroscopy3
X-band EPR spectroscopy3
Solid-state ESR spectroscopy3
XAFS/XPS/EPR electronic structure3
XPS/XANES/EPR2
solid-state EPR2
Electron spin resonance (ESR)2
Quantitative EPR2
Q-band EPR spectroscopy2
solid-state electron paramagnetic resonance2
Solid-state electron paramagnetic resonance (EPR)2
solid-state electron paramagnetic resonance (EPR)2
Electron paramagnetic resonance2
ESR spectroscopy, JEOL JES-FA1002
EPR ageing and pseudo-first-order decay fit2
Electron paramagnetic resonance (EPR), Bruker E500 X-band2
solid-state quantitative EPR spectroscopy2
ex situ FTIR, O 1s/Cu 2p/P 2p XPS, EPR, ex situ PXRD during cycling2
FTIR, XPS, EPR, DRUV-vis2
Temperature-variable EPR, JEOL JES-FA2002
X-band continuous-wave EPR spectroscopy1
Low-temperature electron paramagnetic resonance (EPR)1
EPR of pristine and iodine-doped Cu3(HHTN)21
Electron paramagnetic resonance (EPR) spectroscopy1
Solid-state EPR spectroelectrochemistry1
ATR-IR, UV-Vis and EPR1
XPS/XANES/EXAFS/EPR1
Electron paramagnetic resonance, Bruker ESP-300E, X band 9.861 GHz1
Raman, XPS and EPR spectroscopy1
Electron paramagnetic resonance spectroscopy.1
XPS, solid-state EPR, elemental analysis, TGA1
solid-state EPR with quantitative spin integration1
Continuous-wave EPR spectroscopy1
EPR and DC magnetic susceptibility1
FT-IR, 1H NMR digestion/suspension, XPS, UV-Vis-NIR DRS, EPR, and TGA1
Ex situ S 2p XPS, N 1s XPS, Ni 2p XPS and EPR after H2S exposure1
EPR and SQUID magnetisation1
Continuous-wave ESR and variable-temperature ESR1
Electron paramagnetic resonance (EPR, Bruker A30)1
Solid-state EPR spectroscopy1
Single-crystal X-band CW-EPR quantitative spin counting1
X-band CW-EPR with EasySpin fitting1
Electron paramagnetic resonance using Bruker EMX-10/12.1
ESR spectroscopy and spin susceptibility1
continuous-wave EPR spectroscopy1
quantitative solid-state EPR, Bruker EMXmicro X-band1
X-band EPR spectroscopy, Bruker EMX at 9.37 GHz; PHI simulations1
Solid-state EPR1
X-band ESR spectroscopy1
ESR spectroscopy1
ESR with DMPO spin trapping1
EPR and solid UV-vis-NIR/Tauc analysis1
ESR/EPR spectroscopy1
EPR spin-trapping and radical quenching1
FT-IR, Raman, XPS, EPR and TEM-EDS mapping1
Electron paramagnetic resonance with DPPH reference1
Room-temperature X-band solid-state ESR/EPR spectroscopy1
X-band EPR before/after irradiation1
X-band electron paramagnetic resonance1
DC magnetometry and EPR1
X-band electron spin resonance spectroscopy with Varian E-4 spectrometers; goniometer orientation dependence; numerical double integration for intensity1
Electron paramagnetic resonance, X-band1
Solid-state electron spin resonance1
X-band EPR and SQUID magnetic susceptibility1
EDS, XPS, EPR, TGA and post-soaking PXRD stability checks1
Electron paramagnetic resonance spectroscopy on EPR-200Plus at X-band frequency1
In situ X-band electron paramagnetic resonance (EPR)1
ex situ XPS, EPR and FT-IR during discharge-charge1
ROS probe assays and ESR under ultrasound1
Temperature-variable continuous-wave X-band EPR, JEOL JES-FA2001
Chemical inhibition and EPR spectroscopy1
EPR spectroelectrochemistry1
EPR spectroscopy and SQUID magnetometry1
EPR spin trapping of reactive oxygen species1
electron spin resonance spectroscopy1
PI membrane permeability assay, DCFH-DA ROS assay, CAT activity assay, SEM bacteria morphology, ESR1
Solid-state X-band ESR spectroscopy1
Radical scavenging and EPR spectroscopy1
EPR of DMSO-extracted electrolyte1
EPR spectroscopy with DMPO and TEMP spin trapping1
in situ FT-IR, ex situ EPR and XPS1
continuous-wave solid-state EPR spectroscopy1
Radical scavenger tests and EPR with TEMPO/DMPO1
XANES and ESR/EPR spectroscopy1
EPR spectroscopy, Varian E-4 X-band spectrometer1
ESR radical quantification using TEMPO reference1
ESR radical quantification using TEMPO integrated area1
PES, LEIPS, UV-vis/NIR absorption, ESR1
Scavenger trapping and EPR spectroscopy1
X-band powder ESR spectroscopy1
SERS Raman, XPS, EPR and Cu K-edge XAS1
electron paramagnetic resonance with TEMP spin trap1
X-band EPR spectroscopy; EMX Bruker spectrometer1
XPS, EPR, Raman and FTIR1
Electron paramagnetic resonance (Bruker EMX Plus-6/1)1
FTIR, EPR, XPS1
in situ EPR1
S 2p XPS and EPR before/after H2S exposure1
EPR with DMPO trapping, LC-MS degradation-product analysis, ECOSAR toxicity estimation1
Continuous-wave X-band EPR spectroscopy1