SpectroscopyUnspecified subtype
2026 · Metal–(organic cocrystal) framework with a photothermal effect boosting the photocatalytic degradation of pollutants
Ac@[Ca-NDI] MOCF powder · Powder · DMPO used for superoxide and hydroxyl radicals; TEMP used for singlet oxygen; dark and illuminated conditions.
SpectroscopyUnspecified subtype
2026 · Microenvironment modulation in heterometallic MOFs for tailoring electron/proton transport and hydrophilicity toward photocatalytic hydrogen production
Ni-Ca dark brown crystals / powder · Powder
SpectroscopyUnspecified subtype
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Ca-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.
SpectroscopyUnspecified subtype
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Co-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.
SpectroscopyUnspecified subtype
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Cu-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.
SpectroscopyUnspecified subtype
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Mg-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.
SpectroscopyUnspecified subtype
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Ni-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.
SpectroscopyUnspecified subtype
2026 · Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters†
Zn-HHTP powder sample · Powder · JEOL JES-FA200 ESR spectrometer.
Electrochemistry ApplicationUnspecified subtype
2026 · Tunable Charge Transport Properties Through Precise π-Stacking Modulation in Isostructural Porous Molecular Conductors
PMC-3-Br solid-state electrochemical sample · Electrode · X-band EPR SEC at room temperature using Bruker EMXnano; Pt mesh/Pt working electrode; 0.1 M LiBF4/MeCN.
SpectroscopyUnspecified subtype
2025 · A Cu-based electronically conducting metal–organic framework with π–d conjugation for cathode and anode modification in aqueous zinc-ion batteries
DDA-Cu powder · Powder · Room-temperature EPR of DDA-Cu.
SpectroscopyUnspecified subtype
2025 · A Cu-based electronically conducting metal–organic framework with π–d conjugation for cathode and anode modification in aqueous zinc-ion batteries
DDA ligand · Powder · Room-temperature EPR of pristine DDA ligand.
SpectroscopyUnspecified subtype
2025 · A Low-Symmetry Copper Benzenehexathiol Coordination Polymer with In-Plane Electrical Anisotropy
Cu5BHT crystal domains · Single Crystal · Raman within crystal domains; XPS calibrated to graphitic C1s at 284.6 eV; EPR at 3.4 K; XANES/EXAFS compared with Cu foil, CuO, Cu2O, CuS and Cu2S references.
SpectroscopyUnspecified subtype
2025 · Catalysis-Assisted Synthesis of Two-Dimensional Conductive Metal–Organic Framework Films with Controllable Orientation
face-on Cu3(HHTP)2 film on silicon, 60 min · Thin Film · Cu 2p, C 1s, O 1s XPS and EPR spectrum at 77 K
SpectroscopyUnspecified subtype
2025 · Construction of nanozyme based with mixed valence manganese oxide loaded on defective metal-organic frameworks for sensitive detection of biomarker procalcitonin
MdP nanoparticles · Powder · EPR detection of hydroxyl radical, superoxide/peroxyl radical and singlet oxygen species during MdP/TMB reaction.
SpectroscopyUnspecified subtype
2025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field
As-synthesised Cu3(HHTP)2 powder · Powder · EPR spectra recorded at 77 K; ligand-based radicals and Cu2+ square-planar signatures discussed.
SpectroscopyUnspecified subtype
2025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field
As-synthesised Cu3(HITP)2 powder · Powder · EPR spectra recorded at 77 K; ligand-based radicals and Cu2+ square-planar signatures discussed.
SpectroscopyUnspecified subtype
2025 · Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field
As-synthesised Cu3(THT)2 powder · Powder · EPR spectra recorded at 77 K; ligand-based radicals and Cu2+ square-planar signatures discussed.
Electrochemistry ApplicationUnspecified subtype
2025 · Dual single atomic Fe-Ni sites in N‑doped nanoporous carbon for high-efficiency potassium periodate activation toward pollutant abatement
Fe2Ni1-NC-900 · Powder · TBA, MeOH, EtOH, p-BQ, L-histidine and DMSO scavengers; EPR with DMPO for radicals and TEMP for singlet oxygen.
SpectroscopyUnspecified subtype
2025 · Electro Fenton degradation of glyphosate by incrassated defect-free conductive Cu metal organic framework
10CAT-1 Film · Electrode · EPR identifies DMPO-*OH; LC-MS after 60 min identifies degradation fragments; ECOSAR estimates LC50 for glyphosate and intermediates.
SpectroscopyUnspecified subtype
2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks
Cu-S-HHS solvothermal powder · Powder · KBr FTIR; SERS with silver nanoparticles/APTS glass; XPS Al Kalpha; EPR X-band at 120 K.
SpectroscopyUnspecified subtype
2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks
Cu-Se-HHS solvothermal powder · Powder · KBr FTIR; SERS with silver nanoparticles/APTS glass; XPS Al Kalpha; EPR X-band at 120 K.
SpectroscopyUnspecified subtype
2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks
Cu-Te-HHS solvothermal powder · Powder · KBr FTIR; SERS with silver nanoparticles/APTS glass; XPS Al Kalpha; EPR X-band at 120 K.
SpectroscopyUnspecified subtype
2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks
Ni3(HI12)2 activated powder · Powder · EPR spectra at 300 K; powders activated at 60 C under vacuum for 2 h
SpectroscopyUnspecified subtype
2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks
Ni3(HI18)2 activated powder · Powder · EPR spectra at 300 K; powders activated at 60 C under vacuum for 2 h
SpectroscopyUnspecified subtype
2025 · Highly Porous, Electrically Conductive Two-Dimensional Nickel–Hexaaminodehydrobenzoannulene Frameworks
Ni3(HITP)2 activated powder · Powder · EPR spectra at 300 K; powders activated at 60 C under vacuum for 2 h
SpectroscopyUnspecified subtype
2025 · In Situ Construction of Amide-Functionalized 2D Conjugated Metal-Organic Frameworks with Multiple Active Sites for High-Performance Potassium-Ion Batteries
Cu-HBB-MOF cathode electrode in CR2025 potassium half-cell · Electrode · Cu-HBB-MOF electrode monitored during charge/discharge
SpectroscopyUnspecified subtype
2025 · Mechanistic Insight into the Formation and Deposition of Conductive, Layered Metal-Organic Framework Nanocrystals
reduced HHTP powder · Powder · fresh HHTP under nitrogen and aged 5 days exposed to air
SpectroscopyUnspecified subtype
2025 · Mixed Ionic and Electronic Conductivity in a Tetrathiafulvalene-Phosphonate Metal-Organic Framework
TTFTP-La MOF bulk dark crystals · Powder · Room-temperature EPR of TTFTP-La and H8TTFTP ligand.
SpectroscopyUnspecified subtype
2025 · Modulating the redox states in a 3D conductive MOF for sweat ascorbic acid monitoring
I2@FeTHQ, 20 C 6 h · Powder · Persistent free radicals in FeTHQ and I2@FeTHQ
Electrochemistry ApplicationUnspecified subtype
2025 · Piezoelectric-mediated two-dimensional copper-based metal–organic framework for synergistic sonodynamic and cuproptosis-driven tumor therapy
CM nanosheets · Nanosheet · DPA, NBT, MB, DPBF and ESR spin-trapping assays under ultrasound; CM concentration typically 60 ug mL^-1; ultrasound 1 MHz, 1 W cm^-2, 60% duty cycle for optical probes.
SpectroscopyUnspecified subtype
2025 · Radiation-Induced in Situ Construction of 2D Conductive Defect-Rich Metal-Organic Frameworks for High-Performance Supercapacitor
Cu-CAT-Rad · Powder · Powder EPR; ligand-centred monoradical signal
SpectroscopyUnspecified subtype
2025 · Radiation-Induced in Situ Construction of 2D Conductive Defect-Rich Metal-Organic Frameworks for High-Performance Supercapacitor
Cu-CAT-Sol · Powder · Powder EPR; ligand-centred monoradical signal
SpectroscopyUnspecified subtype
2025 · Screening-Enabled Chemiresistive Moisture Sensing with Tetrathiafulvalene-Based Electrically Conductive Metal–Organic Frameworks
Single crystal of Cd2(TTFTB) for quantitative CW-EPR · Single Crystal · Cd2(TTFTB) and Zn2(TTFTB) single crystals in humid air at room temperature; c axis parallel to static magnetic field.
SpectroscopyUnspecified subtype
2025 · Screening-Enabled Chemiresistive Moisture Sensing with Tetrathiafulvalene-Based Electrically Conductive Metal–Organic Frameworks
Polycrystalline Zn2(TTFTB) powder/crystals for CW-EPR · Powder · Polycrystalline Zn2(TTFTB), humid air and vacuum, 298 K; CIQTEK EPR200M, 9.6 GHz.
SpectroscopyUnspecified subtype
2025 · Structural Control of Photoconductivity in a Flexible Titanium-Organic Framework
MUV-35-c closed phase · Single Crystal
SpectroscopyUnspecified subtype
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc-O-Cu black powder · Powder · Bruker BioSpin standard cavity; 2-3 mg sample purged with N2 for 2 h and sealed under N2; liquid nitrogen temperature 77 K.
SpectroscopyUnspecified subtype
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc(OH)8 monomer powder · Powder · Bruker BioSpin standard cavity; 2-3 mg sample purged with N2 for 2 h and sealed under N2; liquid nitrogen temperature 77 K.
SpectroscopyUnspecified subtype
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc-O-Ni black powder · Powder · Bruker BioSpin standard cavity; 2-3 mg sample purged with N2 for 2 h and sealed under N2; liquid nitrogen temperature 77 K.
SpectroscopyUnspecified subtype
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc-O-Zn black powder · Powder · Bruker BioSpin standard cavity; 2-3 mg sample purged with N2 for 2 h and sealed under N2; liquid nitrogen temperature 77 K.
SpectroscopyUnspecified subtype
2025 · Two-dimensional conductive metal-organic framework with 2,3,6,7,14,15-triptycenehexathiol (TCHT) ligand: synthesis, structure, electrical conductivity and CO2RR activity
Cu-TCHT black powder · Powder · EMX-nano; frequency 9.64 GHz; Q-value 5635.
SpectroscopyUnspecified subtype
2025 · Two-Dimensional π-d Conjugated Conductive Metal-Organic Framework with Triple Active Centers as High-Performance Cathodes for Flexible Zinc Batteries
Pristine 2D Cu-TABQ powder · Powder · Powder characterisation of 2D Cu-TABQ; instruments include Raman Bruker Senterra, FTIR Bruker Vertex 70 V, XPS Thermo ESCALAB 250Xi and EPR Bruker EMXplus-6/1.
SpectroscopyUnspecified subtype
2025 · Uninterrupted π-d Conjugated Three-Dimensional Conductive Metal-Organic Framework
As-synthesised Ni3HBC greenish-black nanocrystalline powder · Powder · Bruker BioSpin spectrometer at 110 K; X-band 9.4 GHz, microwave power 2.14 mW, modulation frequency 100 kHz, amplitude 4 G.
SpectroscopyUnspecified subtype
2024 · 2D Conductive Metal-Organic Frameworks Based on Tetraoxa[8]circulenes as Promising Cathode for Aqueous Zinc Ion Batteries
Cu-TOC black powder / pressed pellet · Powder · EPR spectra collected at 90 K according to SI methods.
SpectroscopyUnspecified subtype
2024 · A Triptycene-Based Layered/Flower-Like 2D Conductive Metal–Organic Framework with 3D Extension as an Electrode for Efficient Li Storage
Pristine M-DBH powders (M = Ni, Co, Mn) · Powder · FTIR-ATR 400-4000 cm^-1; EPR at room temperature; XPS with Al K alpha radiation.
SpectroscopyUnspecified subtype
2024 · Bimetallic synergy significantly enhances the photocatalytic performance of lanthanide porphyrin-based MOFs: Efficient photocatalytic oxidation of benzyl alcohol and benzylamine under mild conditions in air
Ni-Nd PMOFs · Powder · Scavenger capture experiment; DMPO captured superoxide; TEMPO captured singlet oxygen; dark versus visible light comparisons.
SpectroscopyUnspecified subtype
2024 · Diamagnetic Carrier-Doping-Induced Continuous Electronic and Magnetic Crossover in One-Dimensional Coordination Polymers
all Cu-doping-ratio powders · Powder · Co and Cu XANES plus solid-state ESR used to assign tetrahedral coordination and Cu1+ oxidation.
SpectroscopyUnspecified subtype
2024 · Enhancing Near-Infrared Photothermal Performance by Molecular Aggregation Optimization in Semiconductive Coordination Polymers
compound 2 pure microcrystalline product · Powder · Compound 1 and 2 spectra compared under same conditions.
SpectroscopyUnspecified subtype
2024 · Gas-Induced Electrical and Magnetic Modulation of Two-Dimensional Conductive Metal–Organic Framework
gas-exposed Cu3(C6O6)2 EPR tube samples · Powder · 298 K and 77 K; 9.77 GHz; centre field 3500 G; sweep width 3000 G
SpectroscopyUnspecified subtype
2024 · High-Performance H2S Sensors to Detect SF6 Leakage
Co1.8Ni1.2(HITP)2 chemiresistive gas sensor on Au IDE chip · Electrode · Reaction of Co1.8Ni1.2(HITP)2 with H2S; S 2p peaks and free radical signal.
SpectroscopyUnspecified subtype
2024 · Naphthalene Diimide-Based Hydrogen-Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applications
ammonia-doped NDI(CPOH)2-SC sensor device · Single Crystal · ammonia-doped NDI(CPOH)2-SC compared with TEMPO
SpectroscopyUnspecified subtype
2024 · Naphthalene Diimide-Based Hydrogen-Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applications
Device C vacuum-pretreated hydrazine-doped NDI(CPOH)2-SC · Single Crystal · comparison of pristine, hydrazine-doped normal and hydrazine-doped vacuum-treated samples
SpectroscopyUnspecified subtype
2024 · Naphthalene Diimide-Based Hydrogen-Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applications
Device B hydrazine-doped NDI(CPOH)2-SC, normal treatment · Single Crystal · comparison of pristine and hydrazine-doped NDI(CPOH)2-SCs; TEMPO used as ESR reference
SpectroscopyUnspecified subtype
2024 · Revealing the effect of cobalt content and ligand exchange in the bimetallic Ni–Co MOF for stable supercapacitors with high energy density
Ni-M/NiCo-M/Co-M powder comparison series · Powder · Around 9 GHz, Bruker EMX PLUS EPR with ER 4122 SHQ resonator
SpectroscopyUnspecified subtype
2024 · Triazacoronene-Based 2D Conductive Metal–Organic Framework for High-Capacity Lithium Storage
as-synthesised Cu-TAC powder · Powder · Elemental composition, Cu valence, paramagnetic signal, thermal decomposition and crystallinity after water/electrolyte immersion.
SpectroscopyUnspecified subtype
2024 · Tunable Charge Transport and Spin Dynamics in Two-Dimensional Conjugated Metal-Organic Frameworks
Ni3(HATI_H)2 black powder · Powder · Powder heated at 150 C under vacuum for 2 h, sealed in quartz ESR tube under He; X-band CW ESR from 10-300 K.
SpectroscopyUnspecified subtype
2024 · Tunable Charge Transport and Spin Dynamics in Two-Dimensional Conjugated Metal-Organic Frameworks
Ni3(HATI_iPr)2 black powder · Powder · Powder heated at 150 C under vacuum for 2 h, sealed in quartz ESR tube under He; X-band CW ESR and 9.70 GHz pulsed EPR.
SpectroscopyUnspecified subtype
2024 · Tunable Charge Transport and Spin Dynamics in Two-Dimensional Conjugated Metal-Organic Frameworks
Ni3(HATI_nPr)2 black powder · Powder · Powder heated at 150 C under vacuum for 2 h, sealed in quartz ESR tube under He; X-band CW ESR and 9.70 GHz pulsed EPR.
SpectroscopyUnspecified subtype
2024 · Tunable Charge Transport and Spin Dynamics in Two-Dimensional Conjugated Metal-Organic Frameworks
Ni3(HATI_vPr)2 black powder · Powder · Powder heated at 150 C under vacuum for 2 h, sealed in quartz ESR tube under He; X-band CW ESR and 9.70 GHz pulsed EPR.
SpectroscopyUnspecified subtype
2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance
Co-DHHBTN powder · Powder · XAFS at metal K edges; XPS with Al Kalpha, pass energy 30 eV; EPR at 150 K, 9.08 GHz X-band.
SpectroscopyUnspecified subtype
2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance
Cu-DHHBTN powder · Powder · XAFS at metal K edges; XPS with Al Kalpha, pass energy 30 eV; EPR at 150 K, 9.08 GHz X-band.
SpectroscopyUnspecified subtype
2024 · Two-Dimensional Conjugated Metal–Organic Frameworks with a Ring-in-Ring Topology and High Electrical Conductance
Ni-DHHBTN powder · Powder · XAFS at metal K edges; XPS with Al Kalpha, pass energy 30 eV; EPR at 150 K, 9.08 GHz X-band.
SpectroscopyUnspecified subtype
2023 · A Conductive 2D Conjugated Tetrathia[8]circulene-Based Nickel Metal–Organic Framework for Energy Storage
as-synthesised Ni-TTC black powder · Powder · EPR collected at 90 K; magnetic susceptibility in SQUID-VSM at 1000 Oe
SpectroscopyUnspecified subtype
2023 · A Triptycene-Based 2D MOF with Vertically Extended Structure for Improving the Electrocatalytic Performance of CO2 to Methane
2D-vc-MOF(Cu) blue-black powder · Powder · EPR with sweep width 1500 G and centre field 3500 G.
SpectroscopyUnspecified subtype
2023 · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction
c-HBC-12O-Cu black powder · Powder · Room-temperature Bruker A300; sweep width 3000 G, centre field 3300 G, modulation 4 G, microwave 9.85 GHz, power 18.83 mW.
SpectroscopyUnspecified subtype
2023 · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction
c-HBC-6O-Cu black powder · Powder · Room-temperature Bruker A300; sweep width 3000 G, centre field 3300 G, modulation 4 G, microwave 9.85 GHz, power 18.83 mW.
SpectroscopyUnspecified subtype
2023 · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction
c-HBC-8O-Cu black powder · Powder · Room-temperature Bruker A300; sweep width 3000 G, centre field 3300 G, modulation 4 G, microwave 9.85 GHz, power 18.83 mW.
SpectroscopyUnspecified subtype
2023 · Electrically Conductive π-Intercalated Graphitic Metal-Organic Framework Containing Alternate π-Donor/Acceptor Stacks
iGMOF1 black powder · Powder · Composition and electronic-structure characterisation of iGMOF1, Cu3(HATP)2, HCTP-treated Cu3(HATP)2, and [HATP/HCTP]n array.
SpectroscopyUnspecified subtype
2023 · Engineering Band Gap and Photoconduction in Semiconducting Metal Organic Frameworks: Metal Node Effect
Fe-THQ powder · Powder · Bruker EXELSYS E500 at 77 K; old Fe-THQ stored under air compared with fresh sample stored under N2.
Electrochemistry ApplicationUnspecified subtype
2023 · Enhancing the Photocatalytic Degradation Efficiency of Dyes of Copper-Based Metal-Organic Frameworks through a Dimension-Induced Structural Strategy
Complex 1 powder catalyst used for MB/dye degradation · Powder · TBA, EDTA-2Na and TEMPOL added as scavengers; EPR used to detect h+ and hydroxyl radical related signals
SpectroscopyUnspecified subtype
2023 · Exceptionally high charge mobility in phthalocyanine-based poly(benzimidazobenzophenanthroline)-ladder-type two-dimensional conjugated polymers
2DCP-NiPc powder · Powder · Room-temperature and temperature-dependent EPR; spin count per unit cell.
SpectroscopyUnspecified subtype
2023 · Framework Dimensional Control Boosting Charge Storage in Conjugated Coordination Polymers
1D-CuTABQ composite cathode electrode · Electrode · Electrodes cycled to selected potentials at 0.1 A g^-1, then disassembled in Ar-filled glove box
SpectroscopyUnspecified subtype
2023 · Framework Dimensional Control Boosting Charge Storage in Conjugated Coordination Polymers
as-synthesised 1D-CuTABQ powder · Powder · FTIR 400-4000 cm^-1; Al Kalpha XPS; X-band EPR at room temperature; diffuse-reflectance UV-vis
SpectroscopyUnspecified subtype
2023 · Framework Dimensional Control Boosting Charge Storage in Conjugated Coordination Polymers
2D-CuTABQ composite cathode electrode · Electrode · Electrodes cycled to selected potentials at 0.1 A g^-1, then disassembled in Ar-filled glove box
SpectroscopyUnspecified subtype
2023 · Framework Dimensional Control Boosting Charge Storage in Conjugated Coordination Polymers
as-synthesised 2D-CuTABQ powder · Powder · FTIR 400-4000 cm^-1; Al Kalpha XPS; X-band EPR at room temperature; diffuse-reflectance UV-vis
SpectroscopyUnspecified subtype
2023 · Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness
Cu3(HHTP)2 film on Au/Cr/glass anode deposited at 0.25 V for 45 min · Thin Film · Room-temperature EPR spectrum of Cu3(HHTP)2 film.
SpectroscopyUnspecified subtype
2023 · Near IR Bandgap Semiconducting 2D Conjugated Metal-Organic Framework with Rhombic Lattice and High Mobility
Cu2(OHPTP) bulk powder · Powder · EPR on Bruker 500; SQUID magnetometer with 100 Oe and 1 T options; magnetic moment measured at 15 kOe.
SpectroscopyUnspecified subtype
2023 · One-Dimensional π-d Conjugated Conductive Metal-Organic Framework with Dual Redox-Active Sites for High-Capacity and Durable Cathodes for Aqueous Zinc Batteries
Cu-BTA-H powder · Powder · Chemical structure and electronic state comparison of Cu-BTA-H/L and Ni-BTA-H; XPS used Escalab 250Xi, Raman excitation 632 nm, FTIR Ruili WQF-510, EPR Bruker EMS nano at room temperature.
SpectroscopyUnspecified subtype
2023 · Oxidatively Doped Tetrathiafulvalene-Based Metal-Organic Frameworks for High Specific Energy of Supercapatteries
1-ox · Single Crystal · Measured at 110 K for 1 and 1-ox with same parameters; 2/2-ox in missing Figure S14a.
SpectroscopyUnspecified subtype
2023 · Redox-Active Two-Dimensional Tetrathiafulvalene-Copper Metal-Organic Framework with Boosted Electrochemical Performances for Supercapatteries
Iodine-treated crystals of 1 (1-ox) · Single Crystal · EPR spectra of 1, 1-ox and 1-ox' in the solid state, same parameters; figure caption states 110 K.
Electrochemistry ApplicationUnspecified subtype
2023 · Self-Powered Disinfection Using Triboelectric, Conductive Wires of Metal-Organic Frameworks
Cu-HHTP NW-Cu electrode · Electrode · Mechanism tests after EH2O2E or N2 electroporation-only disinfection; 10 mM PBS pH 7.0; fixed 100 rpm and 1.2 V where stated.
SpectroscopyUnspecified subtype
2023 · Stabilizing Redox-Active Hexaazatriphenylene in a 2D Conductive Metal–Organic Framework for Improved Lithium Storage Performance
Cu-HATN powder · Powder · EPR on Bruker EMX-6/1; solid UV-vis-NIR on Shimadzu UV-3600.
SpectroscopyUnspecified subtype
2023 · Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene
Complex 1 bulk powdered sample · Powder · EPR on Bruker-BioSpin E500; detailed acquisition conditions otherwise not reported
SpectroscopyUnspecified subtype
2023 · Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene
Complex 2 bulk powdered sample · Powder · EPR on Bruker-BioSpin E500; detailed acquisition conditions otherwise not reported
SpectroscopyUnspecified subtype
2023 · Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene
Complex 3 bulk powdered sample · Powder · EPR on Bruker-BioSpin E500; detailed acquisition conditions otherwise not reported
SpectroscopyUnspecified subtype
2022 · A Monocrystalline Coordination Polymer with Multiple Redox Centers as a High-Performance Cathode for Lithium-Ion Batteries
CuCA composite electrode in liquid-electrolyte LIB coin cell · Electrode · Coin cells at 50 mA g-1 with Celgard 2400 and 1.0 M LiTFSI in DME/DOL; electrodes disassembled in Ar glovebox, washed with DME and dried.
SpectroscopyUnspecified subtype
2022 · A one-dimensional conductive metal-organic framework with extended π-d conjugated nanoribbon layers
DDA-Cu MOF crystals / bulk precipitate · Powder · Cu 2p XPS; room-temperature EPR
SpectroscopyUnspecified subtype
2022 · A stable lanthanum hydroxamate metal-organic framework with radical character and electrical conductivity
La-ONDI-DMF pressed pellet · Pellet · Room-temperature X-band EPR; spin numbers determined by double integration and comparison with ultramarine standard. DMF sample is representative sample key; DMA and Catechol values are also recorded.
SpectroscopyUnspecified subtype
2022 · Atomic Ruthenium-Riveted Metal-Organic Framework with Tunable d-Band Modulates Oxygen Redox for Lithium-Oxygen Batteries
NiRu-HTP nanowire-array electrode on carbon paper · Electrode · electrolytes extracted after discharge/charge; reaction intermediate detection
SpectroscopyUnspecified subtype
2022 · Atomically Precise Integration of Multiple Functional Motifs in Catalytic Metal-Organic Frameworks for Highly Efficient Nitrate Electroreduction
As-synthesised In8 red block crystals/powder · Single Crystal · Powdered In8 in 5 mM H2SO4 with 0.5 g L-1 KNO3; selected potentials; room temperature.
SpectroscopyUnspecified subtype
2022 · Conjugated Metal-Organic Macrocycles: Synthesis, Characterization, and Electrical Conductivity
CuTOTP-OR family-level sample (variant not individually separated in reported result) · Unknown · ATR-IR of CuTOTP-OR; UV-Vis thin films drop-cast on quartz from 4 mg/mL THF; X-band EPR at 110 K.
SpectroscopyUnspecified subtype
2022 · Construction of sulfur vacancies enriched hollow zinc cobalt bimetallic sulfides for high-performance supercapacitors
Zn0.3Co2.7S4 · Powder · Used to analyse sulphur vacancies; Co3S4 and Zn0.3Co2.7S4 spectra compared in Fig. 2e.
SpectroscopyUnspecified subtype
2022 · Crystal Structure and Electrochemical and Charge Transfer Properties in Redox-Active Coordination Polymers Based on a Truncated Tetrathiafulvalene Linker
as-synthesised Zn-m-TTFTB red rod-like crystals · Powder · Solid-state EPR spectra of m-H4TTFTB ligand, Zn-m-TTFTB, and Cd-m-TTFTB.
SpectroscopyUnspecified subtype
2022 · Dimensionality Modulates Electrical Conductivity in Compositionally Constant One-, Two-, and Three-Dimensional Frameworks
Ni-1D rods/bricks · Powder · Magnetic susceptibility under 1 kOe from 1.8-300 K; EPR under nitrogen at about 4.5-5 K.
SpectroscopyUnspecified subtype
2022 · Fe–O–Zr in MOF for effective photo-Fenton Bisphenol A degradation: Boosting mechanism of electronic transmission
FeUiO-1 · Powder · p-BQ, EDTA-2Na, TBA, FFA, MeOH and PO4(3-) scavenging; EPR detection of hydroxyl and superoxide radicals.
SpectroscopyUnspecified subtype
2022 · Generation of Environmentally Persistent Free Radicals on Metal-Organic Frameworks
CT-dosed MIL-100(Al) · Powder · CT-dosed MIL-100(Al) aged in ambient atmospheric environment.
SpectroscopyUnspecified subtype
2022 · Generation of Environmentally Persistent Free Radicals on Metal-Organic Frameworks
CT-dosed MIL-100(Al) · Powder · Room-temperature EPR after CT exposure and 250 C thermal treatment.
SpectroscopyUnspecified subtype
2022 · Generation of Environmentally Persistent Free Radicals on Metal-Organic Frameworks
MCP-dosed MIL-100(Al) · Powder · MCP-dosed MIL-100(Al) aged in ambient atmospheric environment from day 10 to day 157.
SpectroscopyUnspecified subtype
2022 · Generation of Environmentally Persistent Free Radicals on Metal-Organic Frameworks
MCP-dosed MIL-100(Al) · Powder · Room-temperature EPR after MCP exposure and 250 C thermal treatment; typical settings 9.85 GHz, 0.1002 mW, 100 kHz modulation.
SpectroscopyUnspecified subtype
2022 · Generation of Environmentally Persistent Free Radicals on Metal-Organic Frameworks
MIL-100(Fe) powder · Powder · MIL-100(Fe) and MIL-100(Cr) before and after MCP/CT dosing and 250 C treatment.
SpectroscopyUnspecified subtype
2022 · Highly Effective Generation of Singlet Oxygen by an Imidazole-Linked Robust Photosensitizing Covalent Organic Framework
as-synthesized PyPor-COF powder · Powder · COF powders and trapping agents in EPR tube; xenon lamp excitation; compared dark/light and precursor/commercial photosensitiser controls.
SpectroscopyUnspecified subtype
2022 · Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand
iodine-treated Tb-MOF bulk powder · Powder · Freshly prepared and air-exposed iodine-treated powder in 4 mm quartz tube; double integration used for spin quantification.
SpectroscopyUnspecified subtype
2022 · Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand
pristine Tb-MOF bulk powder/crystals · Powder · Freshly prepared and air-exposed powdered sample in 4 mm quartz tube; double integration used for spin quantification.
SpectroscopyUnspecified subtype
2022 · Iron-Based 2D Conductive Metal-Organic Framework Nanostructure with Enhanced Pseudocapacitance
Fe-HHTP powder · Powder · Bruker Elexsys E 500 with SHQE resonator; microwave power 6.325 mW, modulation amplitude 4 G, modulation frequency 100 kHz.
SpectroscopyUnspecified subtype
2022 · Large π-Conjugated Metal-Organic Frameworks for Infrared-Light-Driven CO2Reduction
TNP-MOF crystals · Single Crystal · 140 K under N2; NIR irradiation λ ≥ 730 nm; TEOA introduced; TNP linker control
SpectroscopyUnspecified subtype
2022 · Large-Area Synthesis of Ultrathin, Flexible, and Transparent Conductive Metal–Organic Framework Thin Films via a Microfluidic-Based Solution Shearing Process
MASS-PRC Ni3(HITP)2 thin film · Thin Film · Thin film and bulk powder exposed to H2S and analysed for adsorbate and linker redox evidence.
SpectroscopyUnspecified subtype
2022 · Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal-organic framework
Acros HHTP batch 2 · Model · X-band EPR at 200 K with DPPH calibration; ligand in 1:1 d6-DMSO/D2O.
SpectroscopyUnspecified subtype
2022 · Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal-organic framework
Purified HHTP plus 0.3 equiv 2,5-dichloro-1,4-benzoquinone · Model · X-band EPR at 200 K with DPPH calibration; ligand in 1:1 d6-DMSO/D2O.
SpectroscopyUnspecified subtype
2022 · Redox-Active Ni(II) Nodes Induced Electrochromism in a Two-Dimensional Conductive Metal-Organic Framework
Ni3(HITP)2-362 nm/FTO electrode · Electrode · Sandwich electrochromic device using Ni3(HITP)2 film, ITO-quartz substrate, and 1 M LiClO4/PC; Bruker A300 at 298 K, 16.65 mW, 9.85 GHz, 1 mT/100 kHz.
SpectroscopyUnspecified subtype
2021 · A family of lanthanide metal-organic frameworks based on a redox-active tetrathiafulvalene-dicarboxylate ligand showing slow relaxation of magnetisation and electronic conductivity
2-Dy · Powder · X-band, 9.05 GHz, room temperature; Bruker EMX.
SpectroscopyUnspecified subtype
2021 · A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands
I2-treated sine-MOF powder · Powder · Solid-state EPR recorded at room temperature on Bruker EMX EPR X-band spectrometer.
SpectroscopyUnspecified subtype
2021 · A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands
pristine sine-MOF evacuated powder · Powder · Solid-state EPR recorded at room temperature on Bruker EMX EPR X-band spectrometer.
SpectroscopyUnspecified subtype
2021 · An Electrically Conducting Three-Dimensional Iron–Catecholate Porous Framework
Fe-HHTP-MOF black microcrystalline powder · Powder · JEOL JES-FA200; X-band 8.959 GHz; solid under nitrogen in quartz glass EPR tubes at 293, 95, and 7 K.
SpectroscopyUnspecified subtype
2021 · Conductive Stimuli-Responsive Coordination Network Linked with Bismuth for Chemiresistive Gas Sensing
NH3-exposed Bi(HHTP) · Powder · Bruker BioSpin spectrometer; about 2 mg material; pristine, NO-exposed, NH3-exposed samples flushed/sealed under N2
SpectroscopyUnspecified subtype
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
Cs-MOF 4 · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.
SpectroscopyUnspecified subtype
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
K-MOF 2 · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.
SpectroscopyUnspecified subtype
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
K-MOF 2-ox · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.
SpectroscopyUnspecified subtype
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
Na-MOF 1-ox · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.
SpectroscopyUnspecified subtype
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
Rb-MOF 3 · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.
SpectroscopyUnspecified subtype
2021 · Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks
Rb-MOF 3-ox · Powder · Bruker EMX EPR X-band at room temperature; double integration used to quantify unpaired spins.
SpectroscopyUnspecified subtype
2021 · Photochromism and photomagnetism in three cyano-bridged 3d-4f heterobimetallic viologen frameworks
CoDy after UV-vis irradiation · Single Crystal · X-band ESR before and after irradiation at room temperature
SpectroscopyUnspecified subtype
2021 · Quinone-Based Conducting Three-Dimensional Metal-Organic Framework as a Cathode Material for Lithium-Ion Batteries
as-prepared (NBu4)2Fe2(DHBQ)3 powder/solid · Powder · Room-temperature X-band EPR spectrum of pristine MOF powder.
SpectroscopyUnspecified subtype
2021 · Redox Ladder of Ni3 Complexes with Closed-Shell, Mono-, and Diradical Triphenylene Units: Molecular Models for Conductive 2D MOFs
complex 2 dark blue needle-shaped crystals · Single Crystal · Frozen DCM glasses at 4.5 K; perpendicular and parallel modes; variable-temperature EPR for complex 2 from 4.5-45 K.
SpectroscopyUnspecified subtype
2021 · Sulfur vacancies enriched Nickel-Cobalt sulfides hollow spheres with high performance for All-Solid-State hybrid supercapacitor
r-NiCo2S4-6 HSs · Powder · EPR spectra at 77 K, 5.00 G modulation amplitude, magnetic field modulation 100 kHz.
SpectroscopyUnspecified subtype
2021 · Two-dimensional d-π conjugated metal-organic framework based on hexahydroxytrinaphthylene
as-synthesised Cu3(HHTN)2 dark brown powder · Powder · Samples about 2 mg in EPR tube; Bruker BioSpin spectrometer; liquid nitrogen temperature.
SpectroscopyUnspecified subtype
2021 · Two-dimensional d-π conjugated metal-organic framework based on hexahydroxytrinaphthylene
iodine-doped Cu3(HHTN)2 powder · Powder · EPR spectrum compared to pristine Cu3(HHTN)2 broad signal.
SpectroscopyUnspecified subtype
2020 · Biporous Cd(II) Coordination Polymer via in Situ Disulfide Bond Formation: Self-Healing and Application to Photosensitive Optoelectronic Device
Bulk/crude material of compound 1 · Powder · Compound 1 in sealed EPR tube under inert gas; irradiated at 360 nm with ISS P110 lamp for 1 h under argon; monitored after air exposure.
SpectroscopyUnspecified subtype
2020 · Conjugated Copper–Catecholate Framework Electrodes for Efficient Energy Storage
As-synthesised Cu-DBC powder · Powder · XPS on Thermo ESCALAB 250XI; EPR at room temperature on Bruker a300; EA with vario EL III; TGA 20-800 C under N2 at 10 C min-1.
SpectroscopyUnspecified subtype
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
Co3(HITP)2 powder/pellet · Powder · Co oxidation state and coordination
SpectroscopyUnspecified subtype
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
Cu3(HITP)2 powder/pellet · Powder · Cu oxidation state and coordination
SpectroscopyUnspecified subtype
2020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys
Ni3(HITP)2 powder/pellet · Powder · Ni oxidation state and ligand radical
SpectroscopyUnspecified subtype
2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design
purified Ni-btt powder · Powder · 77 K EMX X-band (~10 GHz) spectrometer; spin concentration estimated against CuSO4 x 5 H2O standard.
SpectroscopyUnspecified subtype
2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design
purified Ni-diett powder · Powder · 77 K EMX X-band (~10 GHz) spectrometer; spin concentration estimated against CuSO4 x 5 H2O standard.
SpectroscopyUnspecified subtype
2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design
purified Ni-ett powder · Powder · 77 K EMX X-band (~10 GHz) spectrometer; spin concentration estimated against CuSO4 x 5 H2O standard.
SpectroscopyUnspecified subtype
2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design
purified Ni-ett powder · Powder · First-derivative EPR spectra at 77 K; SQUID M-T curves and M-H hysteresis at 2 K.
SpectroscopyUnspecified subtype
2020 · Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-πInteraction and Efficient Charge-Transport Capabilities
Evacuated [Ag2(HATHCN)(CF3SO3)2]n bulk material · Powder · Bruker EMX EPR X-band at room temperature; 70 mg evacuated MOF powder in 4 mm quartz tube; calibrated using DPPH.
SpectroscopyUnspecified subtype
2020 · Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction
purple crystals of 1 · Single Crystal · Compound 2 handled in sealed glass capillary under nitrogen; ESR compared 1 and 2.
SpectroscopyUnspecified subtype
2020 · Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction
black solid 2 from 1 · Powder · Compound 2 in sealed glass capillary prepared in nitrogen-filled glove box.
SpectroscopyUnspecified subtype
2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks
Network 4 as-synthesised single crystal · Single Crystal · Native network 4, Co material; SI spectrum recorded at 20 K, 9.3179 GHz, 0.2 mW, 0.4 mT modulation.
SpectroscopyUnspecified subtype
2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks
Network 4 iodine-treated powder/crystals for EPR, PXRD, and EDX · Powder · Polycrystalline powder of 4 left in 0.05 M I2 in CHCl3 for 3 h.
SpectroscopyUnspecified subtype
2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks
Network 5 as-synthesised single crystal · Single Crystal · Native network 5 control compared with iodine-exposed spectra.
SpectroscopyUnspecified subtype
2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks
Network 5 iodine-treated powder/crystals for EPR, PXRD, and EDX · Powder · Polycrystalline powder of 5 left in 0.05 M I2 in CHCl3 for 3 h; microwave power 4 mW, modulation 0.5 mT.
SpectroscopyUnspecified subtype
2020 · Interdigitated conducting tetrathiafulvalene-based coordination networks
Ligand 1 powder exposed to iodine vapour · Powder · Ligand 1 powder exposed to I2 vapour; radical cation EPR signature measured.
SpectroscopyUnspecified subtype
2020 · Isoreticular Linker Substitution in Conductive Metal–Organic Frameworks with Through-Space Transport Pathways
Cd activated bulk microcrystalline powder · Powder · 1 wt% MOF/KBr; Bruker EMX, 9.37 GHz, 0.100 mW
SpectroscopyUnspecified subtype
2020 · Isoreticular Linker Substitution in Conductive Metal–Organic Frameworks with Through-Space Transport Pathways
Mn activated bulk microcrystalline powder · Powder · 1 wt% MOF/KBr; Bruker EMX, 9.37 GHz, 0.100 mW
SpectroscopyUnspecified subtype
2020 · Isoreticular Linker Substitution in Conductive Metal–Organic Frameworks with Through-Space Transport Pathways
Zn activated bulk microcrystalline powder · Powder · 1 wt% MOF/KBr; Bruker EMX, 9.37 GHz, 0.100 mW
SpectroscopyUnspecified subtype
2020 · Nanorods of a novel highly conductive 2D metal-organic framework based on perthiolated coronene for thermoelectric conversion
Ni-PTC nanorod dark powder · Powder · JEOL JES-Fa200; solid-state ESR at 10 K.
SpectroscopyUnspecified subtype
2020 · Nanorods of a novel highly conductive 2D metal-organic framework based on perthiolated coronene for thermoelectric conversion
Ni-PTC nanorod dark powder · Powder · JEOL JES-Fa200; solid-state ESR at room temperature.
SpectroscopyUnspecified subtype
2020 · Quantum spin liquid state in a two-dimensional semiconductive metal−organic framework
Activated Cu3(HHTP)2 powder · Powder · Central field 300 mT and scan range 100 mT; spectra from 15 to 300 K shown.
SpectroscopyUnspecified subtype
2020 · Quantum spin liquid state in a two-dimensional semiconductive metal−organic framework
Activated Zn3(HHTP)2 powder · Powder · Central field 300 mT and scan range 100 mT; spectra from 15 to 300 K shown.
SpectroscopyUnspecified subtype
2020 · Solid-solid interface growth of conductive metal-organic framework nanowire arrays and their supercapacitor application
Cu3(HHTP)2 nanowire arrays in situ grown on Cu foil · Electrode · XPS on ThermoFisher Scientific K-Alpha; EPR on Bruker EM/Xplus at room temperature, 9.67 GHz microwave frequency and 20 mW microwave power.
SpectroscopyUnspecified subtype
2020 · Synthesis of a copper 1,3,5-triamino-2,4,6-benzenetriol metal-organic framework
Iodine-doped Cu3(TABTO)2-Ar powder · Powder · Raman on Si/SiO2 under 532 nm excitation; XPS survey/high-resolution; EPR comparison with pristine.
SpectroscopyUnspecified subtype
2020 · The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands
1, activated pristine dhMOF · Powder · Solid-state EPR of pristine 1; SI: Bruker EMX EPR X-band spectrometer at room temperature
SpectroscopyUnspecified subtype
2020 · The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands
1a, iodine-treated washed evacuated dhMOF · Powder · Solid-state EPR of iodine-treated 1a; SI: Bruker EMX EPR X-band spectrometer at room temperature
SpectroscopyUnspecified subtype
2020 · Three-dimensional Co/Ni bimetallic organic frameworks for high-efficient catalytic ozonation of atrazine: Mechanism, effect parameters, and degradation pathways analysis
Co/Ni-MOF brown powder · Powder · DMPO for OH and O2-; TEMP for 1O2; [DMPO] 90 mmol L-1, [TEMP] 63 mmol L-1, O3 8 mg L-1, catalyst 0.5 g L-1; TBA quenching used for OH.
SpectroscopyUnspecified subtype
2020 · Tuning Electrical- and Photo-Conductivity by Cation Exchange within a Redox-Active Tetrathiafulvalene-Based Metal–Organic Framework
MV@1 crystals · Single Crystal · 90 K spectra at 9.4451 GHz; variable-temperature 90-270 K; UV exposure 20 min for irradiated sample.
SpectroscopyUnspecified subtype
2020 · Tuning Lewis acidity of MIL-88B-Fe with mix-valence coordinatively unsaturated iron centers on ultrathin Ti3C2 nanosheets for efficient photo-Fenton reaction
CUCs-MIL-88B-Fe/Ti3C2 powder · Powder · 10 uL sample containing 10 mg catalyst in water plus 10 uL 50 mM H2O2 and 10 uL 50 mM DMPO; visible light cutoff 420 nm; ambient temperature.
SpectroscopyUnspecified subtype
2019 · Co 3 O 4 @Cu-Based Conductive Metal–Organic Framework Core–Shell Nanowire Electrocatalysts Enable Efficient Low-Overall-Potential Water Splitting
Co3O4@CuCAT optimal core-shell electrode · Electrode · EPR spectra collected at 77 K to assess oxygen vacancies.
SpectroscopyUnspecified subtype
2019 · Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks
As-synthesised bulk powder of compound 1 · Powder · MOF powders diluted 1 wt% with KBr and measured under nitrogen in septum-sealed quartz tubes.
SpectroscopyUnspecified subtype
2019 · Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks
As-synthesised bulk powder of compound 2 · Powder · MOF powders diluted 1 wt% with KBr and measured under nitrogen in septum-sealed quartz tubes.
SpectroscopyUnspecified subtype
2019 · Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks
As-synthesised bulk powder of compound 3 · Powder · MOF powders diluted 1 wt% with KBr and measured under nitrogen in septum-sealed quartz tubes.
SpectroscopyUnspecified subtype
2019 · Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers
PMC-1 bulk powder/crystals · Powder · JEOL JES-FA100; measured at room temperature.
SpectroscopyUnspecified subtype
2019 · Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal-Organic Frameworks
complex 1 frozen methanol:toluene glass · Unknown · Bruker EMX spectrometer, 9.37 GHz; frozen 1:1 methanol:toluene glass; traces at 5, 20, and 50 K; EasySpin simulations.
SpectroscopyUnspecified subtype
2019 · Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal-Organic Frameworks
complex 2 frozen methanol:toluene glass · Unknown · Bruker EMX spectrometer, 9.37 GHz; frozen 1:1 methanol:toluene glass; 20 K trace fitted with EasySpin.
SpectroscopyUnspecified subtype
2018 · Nanopore-induced host-guest charge transfer phenomena in a metal-organic framework
Compound 2 Mn-MOF 7TMPDA crystals · Single Crystal · Mn-MOF and guest crystals measured over low-temperature ranges to compare line-width broadening.
SpectroscopyUnspecified subtype
2018 · Probing charge transfer characteristics in a donor-acceptor metal-organic framework by Raman spectroelectrochemistry and pressure-dependence studies
solid DPNI · Powder · Room-temperature Bruker Elexsys 500 with X-band microwave bridge; referenced against strong pitch.
SpectroscopyUnspecified subtype
2017 · Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework
MOF-CoNDI-py-2 purple leaf-like crystals/powder · Single Crystal · Powder sample, 7 K and 25 K, P = 6.533 mW.
SpectroscopyUnspecified subtype
2017 · Is iron unique in promoting electrical conductivity in MOFs?
pressed pellet of Fe(1,2,3-triazolate)2 · Pellet · About 5 mg Fe(1,2,3-triazolate)2 in toluene, sealed in low-pressure/vac Suprasil tube in N2 glovebox; measured at 77 K, 0.20 mW, 9.423 GHz.
SpectroscopyUnspecified subtype
2017 · Lowering Band Gap of an Electroactive Metal-Organic Framework via Complementary Guest Intercalation
TTF-doped DSNDI-based MOF-74 powder · Powder · EPR spectra of undoped and TTF-doped MOF-74 compared.
SpectroscopyUnspecified subtype
2017 · Multiple-Hydrogen-Bond Approach to Uncommon Pd(III) Oxidation State: A Pd-Br Chain with High Conductivity and Thermal Stability
Polycrystalline compound 3 · Powder · Bruker EMX spectrometer with Oxford ESR 900 gas-flow cryostat; susceptibility calibrated using CuSO4.5H2O standard.
SpectroscopyUnspecified subtype
2017 · Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal-Organic Frameworks
compound 1 black shiny microcrystalline solid · Powder · Variable-temperature Q-band EPR spectra.
SpectroscopyUnspecified subtype
2017 · Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal-Organic Frameworks
compound 2 black shiny microcrystalline solid · Powder · Variable-temperature Q-band EPR spectra.
SpectroscopyUnspecified subtype
2017 · Synthesis of ordered carbonaceous frameworks from organic crystals
Ni2-CPDPy873(1) · Powder · EPR at low temperature; magnetic susceptibility 5.0-300 K, 10 kG.
SpectroscopyUnspecified subtype
2015 · Topochemical conversion of a dense metal-organic framework from a crystalline insulator to an amorphous semiconductor
Compound 3 vacuum-dried black monolith · Unknown · JEOL JES-TE200 ESR spectrometer, 100 kHz field modulation, room temperature.
SpectroscopyUnspecified subtype
2014 · Tunable electrical conductivity in metal-organic framework thin-film devices
TCNQ@Cu3(BTC)2 powder · Powder · Room-temperature EPR for activated Cu3(BTC)2, methanol-treated Cu3(BTC)2 and methanol/TCNQ-treated Cu3(BTC)2; low-temperature X-band triplet EPR in SI
SpectroscopyUnspecified subtype
2012 · High charge mobility in a tetrathiafulvalene-based microporous metal-organic framework
As-synthesised bulk dark maroon powder of compound 1 · Powder · EPR spectra of as-synthesised compound 1 and iodine-oxidised H4TTFTB control; instrument conditions not reported.
SpectroscopyUnspecified subtype
2012 · Synthesis, characterization and solid state electrical properties of 1-D coordination polymer of the type [CuxNi1-x(dadb) ·yH2O]n
Complex 4 powder / pressed pellet · Powder · Powder ESR spectra recorded on Varian E-112; microwave frequency calibrated using TCNE, g = 2.00277; Table 2 reports ESR parameters.
SpectroscopyUnspecified subtype
2012 · Synthesis, characterization, and solid state electrical conductivity of coordination polymers with copper and zinc
Complex 2 compressed pellet · Pellet · Powder ESR at room temperature and liquid nitrogen temperature; TCNE calibration.
SpectroscopyUnspecified subtype
2012 · Synthesis, characterization, and solid state electrical conductivity of coordination polymers with copper and zinc
Complex 4 compressed pellet · Pellet · Powder ESR at room temperature; TCNE calibration.
SpectroscopyUnspecified subtype
2012 · Synthesis, characterization, and solid state electrical conductivity of coordination polymers with copper and zinc
Complex 7 compressed pellet · Pellet · Powder ESR at room temperature; TCNE calibration.
SpectroscopyUnspecified subtype
2009 · Semiconducting neutral microstructures fabricated by coordinative self-assembly of intramolecular charge-transfer tetrathiafulvalene derivatives
TTF-Pb coordination-polymer microwires · Powder · Solid-state ESR spectra recorded at 298 K; g value calibrated by DPPH. Figure 4 compares microwires and spherical particles.
SpectroscopyUnspecified subtype
1998 · Solid state electrical conductivity studies on manganese-molybdenum Schiff base polymer
dark yellow manganese-molybdenum Schiff base polymer solid · Powder · Powder form at room temperature
SpectroscopyUnspecified subtype
1986 · Structure, Conductivity, and Magnetic Properties of (Phthalocyaninato)nickel(II) Bromide
single crystals of Ni(pc)Br · Single Crystal · Measurements from 300-90 K with cold N2 gas and down to 5 K with a Heli-tran refrigerator; EPR crystals first shown to be highly conductive.
SpectroscopyUnspecified subtype
1984 · Cofacial Assembly of Metallomacrocycles as an Approach to Controlling Lattice Architecture in Low-Dimensional Molecular Solids. Chemical, Structural, Oxidation-State, Transport, and Optical Properties of the Coordination Polymer [Fe(phthalocyaninato)(μ-pyrazine)]n and the Consequences of Halogen Doping
{[Fe(Pc)(mu-pyz)]I2.60}n · Pellet · Powder ESR of {[Fe(Pc)(pyz)]I2.29}n at room temperature and 77 K; 100 kHz field modulation; DPPH calibration.
No mapped measurement matches these filters.