Measurement evidence
Structures and electrical conductivities of a series of coordination polymers based on tetrathiafulvalene · Liu J., Zhang D.-H., Wang B. et al. · Journal of Molecular Structure · 2023 · 136119
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Complex 1 bulk powdered sample · Powder
EPR on Bruker-BioSpin E500; detailed acquisition conditions otherwise not reported
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Major EPR signal g factor | g = 2.006 | — | — | Text Exact Reported | 4 · 3.3 Charge transfer studies · Figure S11 |
Complex 2 bulk powdered sample · Powder
EPR on Bruker-BioSpin E500; detailed acquisition conditions otherwise not reported
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Major EPR signal g factor | g = 2.005 | — | — | Text Exact Reported | 4 · 3.3 Charge transfer studies · Figure S11 |
Complex 3 bulk powdered sample · Powder
EPR on Bruker-BioSpin E500; detailed acquisition conditions otherwise not reported
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Major EPR signal g factor | g = 2.010 | — | — | Text Exact Reported | 4 · 3.3 Charge transfer studies · Figure S11 |
| EPR peak-to-trough separation | 415 G | — | — | Text Exact Reported | 4 · 3.3 Charge transfer studies · Figure S11 |
Complex 1 bulk powdered sample · Powder
Room-temperature diffuse reflectance, 200-2500 nm, BaSO4 baseline; Tauc-plot fitting of absorption onset
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Optical band gap from Tauc plot | 1.76 eV | — | — | Text Exact Reported | 4 · 3.4 Electrical conductivity · Fig. 4b |
| IVCT absorption peak | ~5300 cm-1 | — | — | Text Approximate | 4 · 3.3 Charge transfer studies · Fig. 4a |
| NIR absorption shoulder assigned to TTFTB radical cation | ~14100 cm-1 | — | — | Text Approximate | 4 · 3.3 Charge transfer studies · Fig. 4a |
Complex 2 bulk powdered sample · Powder
Room-temperature diffuse reflectance, 200-2500 nm, BaSO4 baseline; Tauc-plot fitting of absorption onset
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Optical band gap from Tauc plot | 1.73 eV | — | — | Text Exact Reported | 4 · 3.4 Electrical conductivity · Fig. 4b |
| IVCT absorption peak | ~5300 cm-1 | — | — | Text Approximate | 4 · 3.3 Charge transfer studies · Fig. 4a |
| NIR absorption shoulder assigned to TTFTB radical cation | ~14100 cm-1 | — | — | Text Approximate | 4 · 3.3 Charge transfer studies · Fig. 4a |
Complex 3 bulk powdered sample · Powder
Room-temperature diffuse reflectance, 200-2500 nm, BaSO4 baseline; Tauc-plot fitting of absorption onset
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Optical band gap from Tauc plotMarked as a best value within this paper | 1.64 eV | — | — | Text Exact Reported | 4 · 3.4 Electrical conductivity · Fig. 4b |
| IVCT absorption peak | ~5300 cm-1 | — | — | Text Approximate | 4 · 3.3 Charge transfer studies · Fig. 4a |
| NIR absorption shoulder assigned to TTFTB radical cation | ~14100 cm-1 | — | — | Text Approximate | 4 · 3.3 Charge transfer studies · Fig. 4a |