Spectroscopy — Two-dimensional conductive metal-organic framework with 2,3,6,7,14,15-triptycenehexathiol (TCHT) ligand: synthesis, structure, electrical conductivity and CO2RR activity

4 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu-TCHT black powder · Powder

EMX-nano; frequency 9.64 GHz; Q-value 5635.

Context: pristine Cu-TCHT powder
Measurement source: 25728 · Synthesis and characterization of Cu-TCHT · Fig. S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EPR g value	g = 2.14	—	—	Text Exact Reported	25728 · Synthesis and characterization of Cu-TCHT · Fig. S5

Cu-TCHT black powder · Powder

Raman on Horiba LabRAM HR Evolution; IR on JASCO FT/IR-4200 at room temperature.

Temperature: room temperature
Context: pristine Cu-TCHT powder compared with TCHT ligand
Measurement source: 25727 · Synthesis and characterization of Cu-TCHT · Fig. 4a,b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
S-H stretching disappearance	2530 cm-1	—	—	Text Rounded Reported	25727 · Synthesis and characterization of Cu-TCHT · Fig. 4a,b
Raman Cu-S stretching appearance	370 cm-1	—	—	Text Rounded Reported	25727 · Synthesis and characterization of Cu-TCHT · Fig. 4a

Cu-TCHT black powder · Powder

High-resolution Cu 2p spectrum of Cu-TCHT.

Context: pristine Cu-TCHT powder
Measurement source: 25728 · Synthesis and characterization of Cu-TCHT · Fig. S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu2+ 2p1/2 binding energy	953.2 eV	—	—	Text Exact Reported	25728 · Synthesis and characterization of Cu-TCHT · Fig. S4
Cu2+ 2p3/2 binding energy	933.4 eV	—	—	Text Exact Reported	25728 · Synthesis and characterization of Cu-TCHT · Fig. S4

Cu-TCHT black powder · Powder

SHIMADZU ESCA-3400; sample fixed to stand with carbon tape; 50 integrations per element.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Oxidation of sulfur XPS area	29.12% area above 165 eV	—	—	SI Table Exact Reported	S11 · Table S3 · Table S3
S-C 2p1/2 binding energy	163.7 eV	—	—	SI Table Exact Reported	S11 · Table S3 · Table S3
S-C 2p3/2 binding energy	161.8 eV	—	—	SI Table Exact Reported	S11 · Table S3 · Table S3
S-Cu 2p1/2 binding energy	164.5 eV	—	—	SI Table Exact Reported	S11 · Table S3 · Table S3
S-Cu 2p3/2 binding energy	162.9 eV	—	—	SI Table Exact Reported	S11 · Table S3 · Table S3