Electrical Transport — Two-dimensional conductive metal-organic framework with 2,3,6,7,14,15-triptycenehexathiol (TCHT) ligand: synthesis, structure, electrical conductivity and CO2RR activity

5 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu-TCHT@Maxsorb · Electrode

Electrical conductivity of Cu-TCHT and Cu-BHT loaded on Maxsorb; plotted current versus voltage.

Geometry: Maxsorb composite
Context: composite application sample; comparator Cu-BHT@Maxsorb shown in same figure
Measurement source: S13 · Fig. S6 · Fig. S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-BHT@Maxsorb I-V slope	approximately 1.25 A V-1 from Fig. S6	—	visual estimate from plotted current-voltage line	Figure Axis Approximate	S13 · Fig. S6 · Fig. S6
Cu-TCHT@Maxsorb I-V slope	approximately 1.5 A V-1 from Fig. S6	—	visual estimate from plotted current-voltage line	Figure Axis Approximate	S13 · Fig. S6 · Fig. S6

Cu-TCHT Sample A · Pellet

Compressed pellet, 3 mm-diameter pellet mould, Agilent E5291A SMU/E5260A mainframe; measured at 20 deg C.

Temperature: 293
Atmosphere: air-exposed / measured after air filtration
Geometry: compressed pellet; two-terminal method
Context: pristine Cu-TCHT
Measurement source: 25728 · Synthesis and characterization of Cu-TCHT · Fig. 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Electrical conductivity, Sample A	4.3 x 10-7 S cm-1	4.3e-7 S cm-1	—	Text Rounded Reported	25728 · Synthesis and characterization of Cu-TCHT · Fig. 5

Cu-TCHT Sample B · Pellet

Compressed pellet, measured in Ar-filled glovebox.

Temperature: 293
Atmosphere: Ar glovebox
Geometry: compressed pellet; two-terminal method
Context: pristine Cu-TCHT
Measurement source: 25728 · Synthesis and characterization of Cu-TCHT · Fig. 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Electrical conductivity, Sample BMarked as a best value within this paper	on the order of 10-6 S cm-1	0.000001 S cm-1	order-of-magnitude	Text Approximate	25728 · Synthesis and characterization of Cu-TCHT · Fig. 5

Cu-TCHT Sample C · Pellet

Compressed pellet after vacuum activation at 120 deg C for 24 h; measured in glovebox.

Temperature: 293
Atmosphere: Ar glovebox
Geometry: compressed pellet; two-terminal method
Context: pristine Cu-TCHT activated sample
Measurement source: 25728 · Synthesis and characterization of Cu-TCHT · Fig. 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Electrical conductivity, Sample C	on the order of 10-6 S cm-1	0.000001 S cm-1	order-of-magnitude	Text Approximate	25728 · Synthesis and characterization of Cu-TCHT · Fig. 5

Cu-TCHT Sample D · Pellet

Compressed pellet after one day air exposure.

Temperature: 293
Atmosphere: air-exposed
Geometry: compressed pellet; two-terminal method
Context: pristine Cu-TCHT air-exposed sample
Measurement source: 25728 · Synthesis and characterization of Cu-TCHT · Fig. 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Electrical conductivity, Sample D	10-7 S cm-1	1e-7 S cm-1	order-of-magnitude	Text Approximate	25728 · Synthesis and characterization of Cu-TCHT · Fig. 5