Measurement evidence
Revealing the effect of cobalt content and ligand exchange in the bimetallic Ni–Co MOF for stable supercapacitors with high energy density · Raissa, Wulan Septiani N.L., Wustoni S. et al. · Journal of Power Sources · 2024 · 234423
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Ni-M/NiCo-M/Co-M powder comparison series · Powder
Around 9 GHz, Bruker EMX PLUS EPR with ER 4122 SHQ resonator
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NiCo-M (10:1) EPR intensityMarked as a best value within this paper | most pronounced intensity | — | — | Text Qualitative | p006 · 3.1 · Fig. 2c |
KNiCoPO4 powder · Powder
FTIR 400-2000 cm^-1; Raman used to confirm phosphate vibrations and BTC replacement
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| KNiCoPO4 FTIR asymmetric P-O band | 1024 cm-1 | — | — | Text Rounded Reported | p008 · 3.3 · Fig. 5b |
| KNiCoPO4 FTIR symmetric P-O band | 915 cm-1 | — | — | Text Rounded Reported | p008 · 3.3 · Fig. 5b |
| KNiCoPO4 Raman symmetric P-O band | 930 cm-1 | — | — | Text Rounded Reported | p008 · 3.3 · Fig. 5c |
Ni-M/NiCo-M/Co-M powder comparison series · Powder
ATR-FTIR on JASCO FT/IR-6800; Raman with 532 nm Renishaw inVia confocal microscope
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| MOF FTIR asymmetric COO band | around 1600 cm-1 | — | around | Text Approximate | p005 · 3.1 · Fig. 1d |
| MOF FTIR symmetric COO band | around 1400 cm-1 | — | around | Text Approximate | p005 · 3.1 · Fig. 1d |
| MOF Raman COO bands | approximately 1470 and 1550 cm-1 | — | approximately | Text Approximate | p005 · 3.1 · Fig. 1e |
KNiCoPO4 powder · Powder
Survey and high-resolution Ni 2p, Co 2p, P 2p, O 1s spectra
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| KNiCoPO4 Co2+/Co3+ ratio | 0.5 | — | — | Text Rounded Reported | p009 · 3.3 · Fig. 5f; Table S4 |
| KNiCoPO4 Ni3+/Ni2+ ratio | 0.9 | — | — | Text Rounded Reported | p009 · 3.3 · Fig. 5e; Table S4 |
| KNiCoPO4 XPS Ni/Co ratio | approximately 11 | — | approximately | Text Approximate | p008 · 3.3 · Fig. S8b |
| KNiCoPO4 Ni 2p and Co 2p XPS fitting parameters table | Ni2+ 2p3/2 855.642 eV area 11691.110; Ni3+ 2p3/2 856.952 eV area 10697.740; residual metallic Co 775.426 eV area 9770.768; Co3+ 2p3/2 780.678 eV area 2554.531; Co2+ 2p3/2 782.396 eV area 1286.689. | — | — | SI Table Exact Reported | p011 · Supplementary Information · Table S4 |
Ni-M/NiCo-M/Co-M powder comparison series · Powder
Kratos Axis Supra with monochromatic Al-Kalpha source, hnu = 1486.6 eV
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NiCo-M (10:1) Co2+/Co3+ ratioMarked as a best value within this paper | 1.08 | — | — | Text Rounded Reported | p006 · 3.1 · Fig. S3d |
| NiCo-M (10:1) Ni3+/Ni2+ ratio | 0.71 | — | — | Text Rounded Reported | p006 · 3.1 · Fig. S3d |
| NiCo-M (10:1) XPS Ni/Co atomic ratio | 11.3:1 | — | around | Text Approximate | p005 · 3.1 · Fig. S3a |
| NiCo-M (1:10) XPS Ni/Co atomic ratio | 1:9.5 | — | around | Text Approximate | p005 · 3.1 · Fig. S3a |
| NiCo-M (1:1) XPS Ni/Co atomic ratio | 1.36:1 | — | around | Text Approximate | p005 · 3.1 · Fig. S3a |
| MOF series Ni 2p and Co 2p XPS fitting parameters table | Table S2 reports binding energy, area, and FWHM for Ni2+/Ni3+ and Co2+/Co3+ spin-orbit components across Ni-M, NiCo-M (10:1), NiCo-M (1:1), NiCo-M (1:10), and Co-M. | — | — | SI Table Exact Reported | p005-p006 · Supplementary Information · Table S2 |