cMOF Evidence Base
Spectroscopy — Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness

Measurement evidence

Spectroscopy

Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness · Song M., Jia J., Li P. et al. · Journal of the American Chemical Society · 2023 · 25570-25578

2 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Electron paramagnetic resonance

Electron paramagnetic resonance

Cu3(HHTP)2 film on Au/Cr/glass anode deposited at 0.25 V for 45 min · Thin Film

Room-temperature EPR spectrum of Cu3(HHTP)2 film.

Temperature
room temperature
Context
Pristine film electronic/oxidation-state assignment.
Measurement source
main p.3, article p.25572 · Results and Discussion · Fig. S6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
narrow ligand-radical EPR g-valueg = 2.001——Text
Exact Reported		main p.3, article p.25572 · Results and Discussion · Fig. S6
broad semisymmetric Cu-centred EPR g-valueg = 2.084——Text
Exact Reported		main p.3, article p.25572 · Results and Discussion · Fig. S6

X-ray photoelectron spectroscopy

X-ray photoelectron spectroscopy

Cu3(HHTP)2 film on Au/Cr/glass anode deposited at 0.25 V for 45 min · Thin Film

High-resolution C 1s, O 1s and Cu 2p spectra of electrochemically synthesised Cu3(HHTP)2 film.

Context
Pristine film composition/oxidation-state assignment.
Measurement source
main p.3, article p.25572 · Results and Discussion · Fig. S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
C 1s C=O binding energy288.68 eV——Text
Exact Reported		main p.3, article p.25572 · Results and Discussion · Fig. S5
O 1s C=O binding energy532.98 eV——Text
Exact Reported		main p.3, article p.25572 · Results and Discussion · Fig. S5
C 1s C-O binding energy286.18 eV——Text
Exact Reported		main p.3, article p.25572 · Results and Discussion · Fig. S5
O 1s C-O binding energy531.28 eV——Text
Exact Reported		main p.3, article p.25572 · Results and Discussion · Fig. S5
Cu 2p Cu(I) binding energy932.98 eV——Text
Exact Reported		main p.3, article p.25572 · Results and Discussion · Fig. S5
Cu 2p Cu(II) binding energy934.88 eV——Text
Exact Reported		main p.3, article p.25572 · Results and Discussion · Fig. S5
ligand oxidation-state assignmentpartial oxidation of catecholate to semiquinonate——Text
Qualitative		main p.3, article p.25572 · Results and Discussion · Fig. S5