Microscopy Morphology — Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness

6 measurement groups · 22 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu3(HHTP)2 coating on carbon fibres · Electrode

Carbon fibres imaged before and after Cu3(HHTP)2 coating at 0.25 V.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
carbon-fibre coating observation	Cu3(HHTP)2 electrochemical coating observed after 0.25 V deposition	—	—	Caption Qualitative	SI p.16 · Supplementary data · Fig. S12

Cu3(HHTP)2 film on Au/Cr/glass anode deposited at 0.25 V for 45 min · Thin Film

Au anode film after electrochemical reaction at 0.25 V for 45 min.

Context: Pristine Cu3(HHTP)2 target film.
Measurement source: main p.2-3, article pp.25571-25572 · Results and Discussion · Fig. 2a,b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
film area	approximately 2.5 x 2.5 cm2	—	—	Text Approximate	main p.2, article p.25571 · Results and Discussion · Fig. 2a
intergrown crystal-domain size range	80-200 nm	—	—	Text Range	main p.2, article p.25571 · Results and Discussion · Fig. 2b
film thickness	~900 nm	—	—	Text Approximate	main p.2, article p.25571 · Results and Discussion · Fig. 2b

Cu3(HHTP)2 Au-film growth kinetics series · Thin Film

Potentiostatic deposition at 0.25 V for 5 s to 10 h on Au electrodes.

Atmosphere: Nitrogen
Context: Pristine Cu3(HHTP)2 growth kinetics.
Measurement source: main p.5, article p.25574 · Results and Discussion · Fig. 4d-g; Fig. S19

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
10 h crystal-domain size	1540 nm	—	—	Text Rounded Reported	main p.5, article p.25574 · Results and Discussion · Fig. 4g; Fig. S19
10 h film thicknessMarked as a best value within this paper	10.7 um	—	—	Text Rounded Reported	main p.5, article p.25574 · Results and Discussion · Fig. 4g; Fig. S19
1 min crystal size	~47 nm	—	—	Text Approximate	main p.5, article p.25574 · Results and Discussion · Fig. 4g; Fig. S19
1 min continuous-film thickness	~90 nm	—	—	Text Approximate	main p.5, article p.25574 · Results and Discussion · Fig. 4g; Fig. S19
5 s isolated crystal diameter	~28 nm	—	—	Text Approximate	main p.5, article p.25574 · Results and Discussion · Fig. 4g; Fig. S19
5 s isolated crystal height	~30 nm	—	—	Text Approximate	main p.5, article p.25574 · Results and Discussion · Fig. 4g; Fig. S19
steady thickening rateMarked as a best value within this paper	17.4 nm min-1	—	—	Text Rounded Reported	main p.5, article p.25574 · Results and Discussion · Fig. 4g; Fig. S19
orientation preserved during growth	oriented growth preserved throughout whole synthesis	—	—	Text Qualitative	main p.5, article p.25574 · Results and Discussion · Fig. S19u

Cu3(HHTP)2 nanorods grown in Au-coated PCTE membrane · Electrode

Cu3(HHTP)2 growth confined in Au-coated PCTE membrane; released after PCTE dissolution.

Geometry: PCTE template: 200 nm pores, 10 um thickness.
Context: Pristine framework nanorods/template application.
Measurement source: main p.6, article p.25575 · Results and Discussion · Fig. 6; Fig. S26c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
nanorod diameter	~200 nm	—	—	Text Approximate	main p.6, article p.25575 · Results and Discussion · Fig. 6c
nanorod length	10 um	—	—	Text Rounded Reported	main p.6, article p.25575 · Results and Discussion · Fig. 6c
nanorod orientation assignment	oriented nature in PCTE membrane	—	—	Text Qualitative	main p.6, article p.25575 · Results and Discussion · Fig. S26c
PCTE pore diameter	200 nm	—	—	Text Exact Reported	main p.6, article p.25575 · Results and Discussion · Fig. 6
PCTE membrane thickness	10 um	—	—	Text Exact Reported	main p.6, article p.25575 · Results and Discussion · Fig. 6

Patterned Cu3(HHTP)2 films on prepatterned electrodes · Thin Film

Selective growth on conductive regions of prepatterned electrodes.

Context: Pristine film patterning demonstration.
Measurement source: main p.6, article p.25575 · Results and Discussion · Fig. S26a,b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
pattern feature-size range	micrometer to millimeter	—	—	Text Range	main p.6, article p.25575 · Results and Discussion · Fig. S26a,b

Cu3(HHTP)2 Au-film growth kinetics series · Thin Film

Cu3(HHTP)2 films deposited for 15 min at 0.25, 0.30 and 0.35 V.

Atmosphere: Nitrogen
Context: Pristine film growth kinetics.
Measurement source: main p.4-5, article pp.25573-25574 · Results and Discussion · Fig. 4a-c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average crystal domain size at 0.25 V	~150 nm	—	—	Text Approximate	main p.5, article p.25574 · Results and Discussion · Fig. 4a-c
average crystal domain size at 0.30 V	~50 nm	—	—	Text Approximate	main p.5, article p.25574 · Results and Discussion · Fig. 4a-c
average crystal domain size at 0.35 V	~20 nm	—	—	Text Approximate	main p.5, article p.25574 · Results and Discussion · Fig. 4a-c
film formation threshold	no film at potentials less than 0.2 V; intergrown films above 0.25 V	—	—	Text Approximate	main p.4, article p.25573 · Results and Discussion · Fig. 4