cMOF Evidence Base
Porosity — Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness

Measurement evidence

Porosity

Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness · Song M., Jia J., Li P. et al. · Journal of the American Chemical Society · 2023 · 25570-25578

2 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Mercury intrusion porosimetry

Activated Cu3(HHTP)2 film pieces on Au for gas sorption · Thin Film

Cu3(HHTP)2 film measured by MIP for larger pore structures.

Context
Pristine film integrity/porosity check.
Measurement source
main p.5, article p.25574 · Results and Discussion · Fig. S24
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
MIP artefact gap centre 178 um178 um——Caption
Rounded Reported		SI p.27 · Supplementary data · Fig. S24
MIP artefact gap centre 319 um319 um——Caption
Rounded Reported		SI p.27 · Supplementary data · Fig. S24
MIP artefact gap centre 6 um6 um——Caption
Rounded Reported		SI p.27 · Supplementary data · Fig. S24
absence of regular mesoporesabsence of obvious mesopore structures (3-100 nm)——Text
Range		main p.5, article p.25574 · Results and Discussion · Fig. S24

Nitrogen and krypton sorption; BET and NLDFT pore-size analysis

Gas sorption and porosity

Activated Cu3(HHTP)2 film pieces on Au for gas sorption · Thin Film

Activated Au-supported Cu3(HHTP)2 film pieces measured at 77 K; BET fitted over P/P0 = 0.005-0.065.

Temperature
77
Atmosphere
adsorptive gas N2 or Kr
Context
Pristine thick film porosity.
Measurement source
main p.5, article p.25574 · Results and Discussion · Fig. 5a; Fig. S23
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area from krypton sorption409 m2/g——Figure Axis
Rounded Reported		SI p.26 · Supplementary data · Fig. S23d
krypton sorption calculated film mass5.86 mg——Caption
Exact Reported		SI p.26 · Supplementary data · Fig. S23
BET surface area from nitrogen sorptionMarked as a best value within this paper458 m2 g-1——Text
Rounded Reported		main p.5, article p.25574 · Results and Discussion · Fig. 5a; Fig. S23
NLDFT pore size distribution centreMarked as a best value within this paper1.6 nm——Text
Rounded Reported		main p.5, article p.25574 · Results and Discussion · Fig. 5a; Fig. S23
nitrogen sorption calculated film mass43 mg——Caption
Rounded Reported		SI p.26 · Supplementary data · Fig. S23
isotherm typetype I isotherm with steep uptake at low P/P0 < 0.01——Text
Approximate		main p.5, article p.25574 · Results and Discussion · Fig. 5a
sorption activation temperature100 C——Text
Exact Reported		SI p.2 · Characterization and measurements
sorption activation time24 h——Text
Exact Reported		SI p.2 · Characterization and measurements