Electrical Transport — Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness

Measurement evidence

Electrical Transport

Ligand-Oxidation-Based Anodic Synthesis of Oriented Films of Conductive M-Catecholate Metal-Organic Frameworks with Controllable Thickness · Song M., Jia J., Li P. et al. · Journal of the American Chemical Society · 2023 · 25570-25578

1 measurement group · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Four-probe I-V and temperature-dependent conductivity

Electrical conductivity

~100 nm Cu3(HHTP)2 four-probe device on silica · Thin Film

I-V curves recorded under vacuum (~10^-5 mbar) over 100-300 K; conductivity calculated as sigma = (I/V)*(L/Wd).

Temperature: 100-300
Atmosphere: vacuum ~10^-5 mbar
Geometry: Four Au contacts: 40 nm thickness, 9000 um length, 100 um width, 100 um spacing; channel L 100 um, W 9000 um, d 100 nm.
Context: Pristine Cu3(HHTP)2 film device.
Measurement source: SI p.4 · Device fabrication and conductivity measurement · Fig. S25

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
in-plane conductivity near 100 K	~0.0035 S cm-1	—	—	Visual Estimate Approximate	main p.5, article p.25574 · Results and Discussion · Fig. 5c
in-plane conductivity at 300 KMarked as a best value within this paper	0.031 S cm-1	—	—	Text Exact Reported	main p.5, article p.25574 · Results and Discussion · Fig. 5c
Au contact length	9000 um	—	—	Text Exact Reported	main p.5, article p.25574 · Results and Discussion · Fig. 5b; Fig. S25
Au contact spacing	100 um	—	—	Text Exact Reported	main p.5, article p.25574 · Results and Discussion · Fig. 5b; Fig. S25
Au contact thickness	40 nm	—	—	Text Exact Reported	main p.5, article p.25574 · Results and Discussion · Fig. 5b; Fig. S25
Au contact width	100 um	—	—	Text Exact Reported	main p.5, article p.25574 · Results and Discussion · Fig. 5b; Fig. S25
device MOF film thickness	~100 nm	—	—	Text Approximate	main p.5, article p.25574 · Results and Discussion · Fig. 5b; Fig. S25
I-V linearity / ohmic contact	linear current-voltage curves in 100-300 K range	—	—	Text Qualitative	main p.5, article p.25574 · Results and Discussion · Fig. 5b; Fig. S25d
temperature dependence of conductivity	conductivity increased with temperature; semiconducting nature	—	—	Text Qualitative	main p.6, article p.25575 · Results and Discussion · Fig. 5c