Spectroscopy — Tuning Electrical- and Photo-Conductivity by Cation Exchange within a Redox-Active Tetrathiafulvalene-Based Metal–Organic Framework

3 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

MV@1 crystals · Single Crystal

90 K spectra at 9.4451 GHz; variable-temperature 90-270 K; UV exposure 20 min for irradiated sample.

Temperature: 90; variable 90-270
Geometry: Polycrystalline sample
Context: Guest-loaded MV2+ exchanged framework.
Measurement source: 18765 · Results and Discussion · Figure 3; Figures S14-S15

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EPR microwave frequency	9.4451 GHz	—	—	Caption Exact Reported	18765 · Figure 3 · Figure 3
variable-temperature EPR range	90-270 K	—	range	Caption Range	18765 · Figure 3 caption · Figure 3b
TTF@1 broad EPR signal	broad signal at g approximately 2	—	approximately	Text Approximate	18765 · Results and Discussion · Figure 3a
MV@1 EPR intensity increase after 365 nm irradiation	resonance intensities nearly doubled after 365 nm irradiation for 20 min	—	nearly	Text Approximate	18765 · Results and Discussion · Figure 3a

TTF@1 crystals · Single Crystal

Framework decomposed by D2SO4 because MOF is insoluble.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MV@1 cation exchange completeness by 1H NMR	[Me2NH2]+ 2.57 ppm fully replaced by MV2+ peaks at 4.43, 8.73, 8.75, 9.26, 9.28 ppm	—	—	Caption Qualitative	S11 · Figure S9 caption · Figure S9
TTF@1 cation exchange completeness by 1H NMR	[Me2NH2]+ 2.57 ppm fully replaced by TTF*+ 6.66 ppm	—	—	Caption Qualitative	S11 · Figure S9 caption · Figure S9

MV@1 crystals · Single Crystal

Room temperature; PE Lambda 900 UV-vis spectrometer with integrating sphere; BaSO4 reference; 300-2000 nm.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
common absorption edge	ca. 600 nm	—	ca.	Text Approximate	18765 · Results and Discussion · Figure 2
MV@1 low-energy absorption bands	absorption in 600-1000 nm and weak band at 1200 nm	—	range and weak band	Text Range	18765 · Results and Discussion · Figure 2
*TTF@1 weak TTF+ absorption peak**	weak peak at 750 nm	—	weak	Text Approximate	18765 · Results and Discussion · Figure 2