Electrochemistry Application — Tuning Electrical- and Photo-Conductivity by Cation Exchange within a Redox-Active Tetrathiafulvalene-Based Metal–Organic Framework

3 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Photo-electrochemical photocurrent using CHI 660e workstation in a standard three-electrode cell.

Photoresponse and photoelectrochemistry

Me2NH2@1 microcrystal ITO photoelectrode · Electrode

0.20 mol L-1 Na2SO4 electrolyte; 150 W high pressure xenon lamp white-light irradiation; 50 s irradiation intervals; Pt counter and saturated Ag/AgCl reference.

Temperature: room temperature
Atmosphere: ambient electrolyte
Geometry: MOF/Nafion/ITO working electrode in three-electrode cell
Context: Pristine parent control photoelectrode.
Measurement source: S3 · Characterizations · Figure 4 in main article

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
visible-light photocurrent	0.3 uA	3e-7 A	—	Text Rounded Reported	18766 · Results and Discussion · Figure 4

Photo-electrochemical photocurrent using CHI 660e workstation in a standard three-electrode cell.

Photoresponse and photoelectrochemistry

MV@1 microcrystal ITO photoelectrode · Electrode

0.20 mol L-1 Na2SO4 electrolyte; 150 W high pressure xenon lamp white-light irradiation; 50 s irradiation intervals; Pt counter and saturated Ag/AgCl reference.

Temperature: room temperature
Atmosphere: ambient electrolyte
Geometry: MOF/Nafion/ITO working electrode in three-electrode cell
Context: Guest-loaded MV2+ exchanged framework photoelectrode.
Measurement source: 18766 · Results and Discussion · Figure 4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
visible-light photocurrentMarked as a best value within this paper	8.5 uA	0.0000085 A	—	Text Rounded Reported	18766 · Results and Discussion · Figure 4
photocurrent enhancement versus Me2NH2@1Marked as a best value within this paper	factor of 28	—	—	Text Rounded Reported	18766 · Results and Discussion · Figure 4
irradiation interval	50 s periods	—	—	Caption Exact Reported	18766 · Figure 4 caption · Figure 4

Photo-electrochemical photocurrent using CHI 660e workstation in a standard three-electrode cell.

Photoresponse and photoelectrochemistry

TTF@1 microcrystal ITO photoelectrode · Electrode

0.20 mol L-1 Na2SO4 electrolyte; 150 W high pressure xenon lamp white-light irradiation; 50 s irradiation intervals; Pt counter and saturated Ag/AgCl reference.

Temperature: room temperature
Atmosphere: ambient electrolyte
Geometry: MOF/Nafion/ITO working electrode in three-electrode cell
Context: Guest-loaded TTF*+ exchanged framework photoelectrode.
Measurement source: 18766 · Results and Discussion · Figure 4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
visible-light photocurrent	1.2 uA	0.0000012 A	—	Text Rounded Reported	18766 · Results and Discussion · Figure 4
photocurrent enhancement versus Me2NH2@1	factor of 4	—	—	Text Rounded Reported	18766 · Results and Discussion · Figure 4